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Introduction

Chemistry is the scientific discipline involved with compounds composed of atoms, i.e. elements, and molecules, i.e. combinations of atoms: their composition, structure, properties, behavior and the changes they undergo during a reaction with other compounds. Chemistry addresses topics such as how atoms and molecules interact via chemical bonds to form new chemical compounds. There are four types of chemical bonds: covalent bonds, in which compounds share one or more electron(s); ionic bonds, in which a compound donates one or more electrons to another compound to produce ions (cations and anions); hydrogen bonds; and Van der Waals force bonds.

In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both basic and applied scientific disciplines at a fundamental level. Examples include plant chemistry (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties of the soil on the moon (astrophysics), how medications work (pharmacology), and how to collect DNA evidence at a crime scene (forensics).

The history of chemistry spans a period from very old times to the present. Since several millennia BC, civilizations were using technologies that would eventually form the basis of the various branches of chemistry. Examples include extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, and making alloys like bronze. Chemistry was preceded by its protoscience, alchemy, which is an intuitive but non-scientific approach to understanding the constituents of matter and their interactions. It was unsuccessful in explaining the nature of matter and its transformations, but, by performing experiments and recording the results, alchemists set the stage for modern chemistry. Chemistry as a body of knowledge distinct from alchemy began to emerge when a clear differentiation was made between them by Robert Boyle in his work The Sceptical Chymist (1661). While both alchemy and chemistry are concerned with matter and its transformations, the crucial difference was given by the scientific method that chemists employed in their work. Chemistry is considered to have become an established science with the work of Antoine Lavoisier, who developed a law of conservation of mass that demanded careful measurement and quantitative observations of chemical phenomena. The history of chemistry is intertwined with the history of thermodynamics, especially through the work of Willard Gibbs.

Featured article

Helium discharge tube shaped like the element's atomic symbol
Helium is a chemical element; its atomic symbol is He. It is a colorless, odorless, tasteless, non-toxic, and nearly inert monatomic that heads the noble gas series in the periodic table. Its atomic number is 2 and its boiling and melting points are the lowest among the elements. It exists only as a gas except in extreme conditions. Extreme conditions are also needed to create the small handful of helium compounds, which are all unstable at standard temperature and pressure. Its most abundant stable isotope is helium-4 and it has a rare stable isotope, helium-3. The behavior of liquid helium-4's two different states—helium I and helium II—is important to researchers studying quantum mechanics (in particular the phenomenon of superfluidity) and those looking at the effects that near absolute zero temperatures have on matter (such as superconductivity).

Helium is the second most abundant element in the known Universe and second lightest element in the periodic table. In the modern Universe almost all new helium is created as a result of the nuclear fusion of hydrogen in stars. On Earth it is created by the radioactive decay of much heavier elements (alpha particles are helium-4 nuclei produced by alpha-decay). After its creation, part of it is trapped with natural gas in concentrations up to 7% by volume. It is extracted from the natural gas by a low temperature separation process called fractional distillation.

In 1868 the French astronomer Pierre Janssen first detected helium as an unknown yellow spectral line signature in light from a solar eclipse. (The word helium comes from ancient Greek ἥλιος which is, surprisingly, cognate with the English sun.) Since then large reserves of helium have been found in the natural gas fields of the United States, which is by far the largest supplier of the gas. Helium is used in cryogenics, in deep-sea breathing systems, to cool superconducting magnets, in helium dating, for inflating balloons, for providing lift in airships and as a protective gas for many industrial uses (such as arc welding and growing silicon wafers). Inhaling a small volume of the gas temporarily changes the quality of one's voice.

Selected image

Ferrofluid
Credit: Gregory Maxwell

This award winning picture of a ferrofluid (in oil) shows the magnetic field near a powerful magnet.

Categories

History and Philosophy of Chemistry

Antoine Lavoisier

Many chemists have an interest in the history of chemistry. Those with philosophical interests will be interested that the philosophy of chemistry has quite recently developed along a path somewhat different from the general philosophy of science.

Other articles that might interest you are:

There is a Wikipedia Project on the History of Science and a portal for the philosophy of science.

Chemistry Resources

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Wikipedia:WikiProject Chemicals/Data is a collection of links and references that are useful for chemistry-related works. This includes free online chemical databases, publications, patents, computer programs, and various tools.

Science is Fun University of Wisconsin–Madison Chemistry Professor Bassam Z. Shakhashiri, shares the fun of science.

unit-conversion.info A good place to figure out what equals what.

General Chemistry Online Clear text and comprehensive coverage of general chemistry topics by Fred Senese, Dept. of Chemistry Frostburg State University

General Chemistry Demonstration at Purdue Video clips (and descriptions) of lecture demonstrations.

Intota Chemistry Experts A large online listing of real-world chemistry expert biographies provides examples of the many areas of expertise and careers in chemistry.

Chemistry Webercises Directory A large listing of chemistry resources maintained by Steven Murov, Emeritus Chemistry Professor Modesto Junior College.

MathMol MathMol (Mathematics and Molecules) is a good starting point for those interested in the field of molecular modeling.

Chemistry Educational Resources and Essential References from Wiley, the world's largest chemistry publisher

ABC-Chemistry A directory of free full-text journals in chemistry, biochemistry and related subjects.

The Element Song A goofy little song about all of the elements.

Selected biography

Louis Pasteur
Louis Pasteur (1822-1895) was a French microbiologist and chemist. He was the first to demonstrate chirality of molecules, using tartaric acid crystals, but this achievement is often overlooked in favor of his more famous work in biology and medicine. He is best known for demonstrating how to prevent milk and wine from going sour, a process which came to be called pasteurization. His experiments confirmed the germ theory of disease, and he created the first vaccine for rabies. He became one of the main founders of bacteriology, the other major figure being Robert Koch. Pasteur also discovered anaerobiosis, whereby some microorganisms can develop and live without air or oxygen.

Techniques used by chemists

Equipment used by chemists

Chemistry in society

Chemistry in industry

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Periodic Table

Group 1 2 3   4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Alkali metals Alkaline earth metals Pnicto­gens Chal­co­gens Halo­gens Noble gases
Period

1

Hydro­gen1H1.008 He­lium2He4.0026
2 Lith­ium3Li6.94 Beryl­lium4Be9.0122 Boron5B10.81 Carbon6C12.011 Nitro­gen7N14.007 Oxy­gen8O15.999 Fluor­ine9F18.998 Neon10Ne20.180
3 So­dium11Na22.990 Magne­sium12Mg24.305 Alumin­ium13Al26.982 Sili­con14Si28.085 Phos­phorus15P30.974 Sulfur16S32.06 Chlor­ine17Cl35.45 Argon18Ar39.948
4 Potas­sium19K39.098 Cal­cium20Ca40.078 Scan­dium21Sc44.956 Tita­nium22Ti47.867 Vana­dium23V50.942 Chrom­ium24Cr51.996 Manga­nese25Mn54.938 Iron26Fe55.845 Cobalt27Co58.933 Nickel28Ni58.693 Copper29Cu63.546 Zinc30Zn65.38 Gallium31Ga69.723 Germa­nium32Ge72.630 Arsenic33As74.922 Sele­nium34Se78.971 Bromine35Br79.904 Kryp­ton36Kr83.798
5 Rubid­ium37Rb85.468 Stront­ium38Sr87.62 Yttrium39Y88.906 Zirco­nium40Zr91.224 Nio­bium41Nb92.906 Molyb­denum42Mo95.95 Tech­netium43Tc​[98] Ruthe­nium44Ru101.07 Rho­dium45Rh102.91 Pallad­ium46Pd106.42 Silver47Ag107.87 Cad­mium48Cd112.41 Indium49In114.82 Tin50Sn118.71 Anti­mony51Sb121.76 Tellur­ium52Te127.60 Iodine53I126.90 Xenon54Xe131.29
6 Cae­sium55Cs132.91 Ba­rium56Ba137.33 Lan­thanum57La138.91 1 asterisk Haf­nium72Hf178.49 Tanta­lum73Ta180.95 Tung­sten74W183.84 Rhe­nium75Re186.21 Os­mium76Os190.23 Iridium77Ir192.22 Plat­inum78Pt195.08 Gold79Au196.97 Mer­cury80Hg200.59 Thallium81Tl204.38 Lead82Pb207.2 Bis­muth83Bi208.98 Polo­nium84Po​[209] Asta­tine85At​[210] Radon86Rn​[222]
7 Fran­cium87Fr​[223] Ra­dium88Ra​[226] Actin­ium89Ac​[227] 1 asterisk Ruther­fordium104Rf​[267] Dub­nium105Db​[268] Sea­borgium106Sg​[269] Bohr­ium107Bh​[270] Has­sium108Hs​[270] Meit­nerium109Mt​[278] Darm­stadtium110Ds​[281] Roent­genium111Rg​[282] Coper­nicium112Cn​[285] Nihon­ium113Nh​[286] Flerov­ium114Fl​[289] Moscov­ium115Mc​[290] Liver­morium116Lv​[293] Tenness­ine117Ts​[294] Oga­nesson118Og​[294]
1 asterisk Cerium58Ce140.12 Praseo­dymium59Pr140.91 Neo­dymium60Nd144.24 Prome­thium61Pm​[145] Sama­rium62Sm150.36 Europ­ium63Eu151.96 Gadolin­ium64Gd157.25 Ter­bium65Tb158.93 Dyspro­sium66Dy162.50 Hol­mium67Ho164.93 Erbium68Er167.26 Thulium69Tm168.93 Ytter­bium70Yb173.05 Lute­tium71Lu174.97  
1 asterisk Thor­ium90Th232.04 Protac­tinium91Pa231.04 Ura­nium92U238.03 Neptu­nium93Np​[237] Pluto­nium94Pu​[244] Ameri­cium95Am​[243] Curium96Cm​[247] Berkel­ium97Bk​[247] Califor­nium98Cf​[251] Einstei­nium99Es​[252] Fer­mium100Fm​[257] Mende­levium101Md​[258] Nobel­ium102No​[259] Lawren­cium103Lr​[266]

Note: Nihonium, moscovium, tennessine, and oganesson have only recently been named.

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Collaboration of the Month

Nuvola apps edu science.png The current Chemistry Article Improvement Drive is Sodium hydroxide.
Every month a different chemistry-related topic, stub or non-existent article may be picked. Please improve the article any way you can.

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  1. ^ Meija, J.; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305. 
  2. ^ IUPAC 2016, Table 2, 3 combined; uncertainty removed.