Americium-241 (241Am) is an isotope of americium. Like all isotopes of americium, it is radioactive, with a half-life of 432.2 years. 241Am is the most common isotope of americium as well as the most prevalent isotope of americium in nuclear waste. It is commonly found in ionization type smoke detectors and is a potential fuel for long-lifetime radioisotope thermoelectric generators (RTGs). Its common parent nuclides are β− from 241Pu, EC from 241Cm and α from 245Bk. 241Am is fissile and the critical mass of a bare sphere is 57.6-75.6 kilograms and a sphere diameter of 19–21 centimeters. Americium-241 has a specific activity of 3.43 Ci/g (curies per gram or 126.9 gigabequerels (GBq) per gram). It is commonly found in the form of americium-241 dioxide (241AmO2). This isotope also has one meta state; 241mAm, with an excitation energy of 2.2 MeV, and a half-life of 1.23 μs. The presence of americium-241 in plutonium is determined by the original concentration of plutonium-241 and the sample age. Because of the low penetration of alpha radiation, americium-241 only poses a health risk when ingested or inhaled. Older samples of plutonium containing plutonium-241 contain a buildup of 241Am. A chemical removal of americium-241 from reworked plutonium (e.g. during reworking of plutonium pits) may be required in some cases.
Small button containing 241AmO2 from a smoke alarm
|Natural abundance||none (synthetic)|
|Parent isotopes||241Pu (β−)|
|Isotope mass||241.056829144 u|
|Excess energy||52.936008 MeV 52,936.008 keV|
|Binding energy||7.543272 MeV 7,543.272 keV|
|Decay mode||Decay energy (MeV)|
|CD (Cluster Decay)||93.923|
|Complete table of nuclides|
Americium-241 has been produced in small quantities in nuclear reactors for decades, and many kilograms of 241Am have been accumulated by now. Nevertheless, since it was first offered for sale in 1962, its price, about US$1,500 per gram of 241Am, remains almost unchanged owing to the very complex separation procedure.
Americium-241 is not synthesized directly from uranium – the most common reactor material – but from the plutonium isotope 239Pu. The latter needs to be produced first, according to the following nuclear process:
The capture of two neutrons by 239Pu (a so-called (n,γ) reaction), followed by a β-decay, results in 241Am:
The plutonium present in spent nuclear fuel contains about 12% of 241Pu. Because it converts to 241Am, 241Pu can be extracted and may be used to generate further 241Am. However, this process is rather slow: half of the original amount of 241Pu decays to 241Am after about 14 years, and the 241Am amount reaches a maximum after 70 years.
The obtained 241Am can be used for generating heavier americium isotopes by further neutron capture inside a nuclear reactor. In a light water reactor (LWR), 79% of 241Am converts to 242Am and 10% to its nuclear isomer 242mAm:
The α-decay energies are 5.486 MeV for 85% of the time (the one which is widely accepted for standard α-decay energy), 5.443 MeV for 13% of the time, and 5.388 MeV for the remaining 2%. The γ-ray energy is 59.5409 keV for the most part, with little amounts of other energies such as 13.9 keV, 17.8 keV and 26.4 keV.
The second most common type of decay that americium-241 undergoes is spontaneous fission, with a branching ratio of 3.6×10−12 and happening 1.2 times a second per gram of 241Am. It is written as such (the asterisk denotes an excited nucleus):
Ionization-type smoke detectorEdit
Americium-241 is the only synthetic isotope to have found its way into the household, where the most common type of smoke detector (the ionization-type) uses 241AmO2 (americium-241 dioxide) as its source of ionizing radiation. This isotope is preferred over 226Ra as 241Am emits 5 times more alpha particles and also emits relatively little harmful gamma radiation. With its half-life of 432.2 years, the americium in a smoke detector decreases and includes about 3% neptunium after 19 years, and about 5% after 32 years. The amount of americium in a typical new smoke detector is 0.29 microgram (about one-third the weight of a grain of sand) with an activity of 1 microcurie/37 kilobequerels (1.0 μCi/37 kBq). Some old industrial smoke detectors (notably from the Pyrotronics Corporation) can contain up to 80 μCi. The amount of 241Am declines slowly as it decays into neptunium-237, a different transuranic element with a much longer half-life (about 2.14 million years). The radiated alpha-particles pass through an ionization chamber, an air-filled space between two electrodes, which allows a small, constant electric current to pass between the capacitor plates due to the radiation ionizing the air space between. Any smoke that enters the chamber blocks/absorbs some of the alpha particles from freely passing through and reduces the ionization and therefore causes a drop in the current. The alarm's circuitry detects this drop in the current and as a result, triggers the piezoelectric buzzer to sound. Compared to the alternative optical smoke detector, the ionization smoke detector is cheaper and can detect particles which are too small to produce significant light scattering. However, it is more prone to false alarms.
The process for making the americium used in the buttons on ionization-type smoke detectors begins with americium dioxide. The AmO2 is thoroughly mixed with gold, shaped into a briquette, and fused by pressure and heat at over 1470 °F (800 °C). A backing of silver and a front covering of gold (or an alloy of gold or palladium) are applied to the briquette and sealed by hot forging. The briquette is then processed through several stages of cold rolling to achieve the desired thickness and levels of radiation emission. The final thickness is about 0.008 inches (0.2 mm), with the gold cover representing about one percent of the thickness. The resulting foil strip, which is about 0.8 inches (20 mm) wide, is cut into sections 39 inches (1 meter) long. The sources are punched out of the foil strip. Each disc, about 0.2 inches (5 mm) in diameter, is mounted in a metal holder, usually made of aluminium. The holder is the housing, which is the majority of what is seen on the button. The thin rim on the holder is rolled over to completely seal the cut edge around the disc.
RTG power generationEdit
As 241Am has a roughly similar half-life to 238Pu (432.2 years vs. 87 years), it has been proposed as an active isotope of radioisotope thermoelectric generators, for use in spacecraft. Even though americium-241 produces less heat and electricity than plutonium-238 (the power yield is 114.7 mW/g for 241Am vs. 390 mW/g for 238Pu) and its radiation poses a greater threat to humans owing to gamma and neutron emission, it has advantages for long duration missions with its significantly longer half-life. The European Space Agency is working on RTGs based on americium-241 for its space probes as a result of the global shortage of plutonium-238 and easy access to americium-241 in Europe from nuclear waste reprocessing.
Its shielding requirements in an RTG are the second lowest of all possible isotopes: only 238Pu requires less. An advantage over 238Pu is that it is produced as nuclear waste and is nearly isotopically pure. Prototype designs of 241Am RTGs expect 2-2.2 We/kg for 5-50 We RTGs design, putting 241Am RTGs at parity with 238Pu RTGs within that power range.
Here americium acts as the alpha source, and beryllium produces neutrons owing to its large cross-section for the (α,n) nuclear reaction:
The most widespread use of 241AmBe neutron sources is a neutron probe – a device used to measure the quantity of water present in soil, as well as moisture/density for quality control in highway construction. 241Am neutron sources are also used in well logging applications, as well as in neutron radiography, tomography and other radiochemical investigations. 
Production of other elementsEdit
Americium-241 is sometimes used as a starting material for the production of other transuranic elements and transactinides – for example, neutron bombardment of 241Am yields 242Am:
From there, 82.7% of 242Am decays to 242Cm and 17.3% to 242Pu:
In the nuclear reactor, 242Am is also up-converted by neutron capture to 243Am and 244Am, which transforms by β-decay to 244Cm:
Irradiation of 241Am by 12C or 22Ne ions yields the isotopes 253Es (einsteinium) or 263Db (dubnium), respectively. Furthermore, the element berkelium (243Bk isotope) had been first intentionally produced and identified by bombarding 241Am with alpha particles, in 1949, by the same Berkeley group, using the same 60-inch cyclotron that had been used for many previous experiments. Similarly, nobelium was produced at the Joint Institute for Nuclear Research, Dubna, Russia, in 1965 in several reactions, one of which included irradiation of 243Am with 15N ions. Besides, one of the synthesis reactions for lawrencium, discovered by scientists at Berkeley and Dubna, included bombardment of 243Am with 18O.
Americium-241 has been used as a portable source of both gamma rays and alpha particles for a number of medical and industrial uses. The 59.5409 keV gamma ray emissions from 241Am in such sources can be used for indirect analysis of materials in radiography and X-ray fluorescence spectroscopy, as well as for quality control in fixed nuclear density gauges and nuclear densometers. For example, this isotope has been employed to gauge glass thickness to help create flat glass. Americium-241 is also suitable for calibration of gamma-ray spectrometers in the low-energy range, since its spectrum consists of nearly a single peak and negligible Compton continuum (at least three orders of magnitude lower intensity).
Americium-241 gamma rays has been used to provide passive diagnosis of thyroid function. This medical application is now obsolete. Americium-241's gamma rays can provide reasonable quality radiographs, with a 10-minute exposure time. 241Am radiographs have only been taken experimentally due to the long exposure time which increases the effective dose to living tissue. Reducing exposure duration reduces the chance of ionization events causing damage to cells and DNA, and is a critical component in the "time, distance, shielding" maxim used in radiation protection.
Americium-241 is a form of americium therefore having the same general hazards. Americium and its isotopes are both extremely toxic and radioactive. Although α-particles can be stopped by a sheet of paper, there are serious health concerns for ingestion of α-emitters. Americium and its isotopes are also very chemically toxic as well, in the form of heavy-metal toxicity. As little as 0.03 μCi (1,110 Bq) is the maximum permissible body burden for 241Am.
Americium-241 is an α-emitter with a weak γ-ray byproduct. Safely handling americium-241 requires knowing and following proper safety precautions, as without them it would be extremely dangerous. Its specific gamma dose constant is 3.14 x 10−1 mR/hr/mCi or 8.48 x10−5 mSv/hr/MBq at 1 meter.
If consumed, americium-241 is excreted within a few days and only 0.05% is absorbed in the blood. From there, roughly 45% of it goes to the liver and 45% to the bones, and the remaining 10% is excreted. The uptake to the liver depends on the individual and increases with age. In the bones, americium is first deposited over cortical and trabecular surfaces and slowly redistributes over the bone with time. The biological half-life of 241Am is 50 years in the bones and 20 years in the liver, whereas in the gonads (testicles and ovaries) it remains permanently; in all these organs, americium promotes formation of cancer cells as a result of its radioactivity.
Americium-241 often enters landfills from discarded smoke detectors. The rules associated with the disposal of smoke detectors are relaxed in most jurisdictions. In the U.S., the "Radioactive Boy Scout" David Hahn was able to concentrate americium-241 from smoke detectors after managing to buy a hundred of them at remainder prices and also stealing a few. There have been a few cases of exposure to americium-241, the worst case being that of Harold McCluskey, who at the age of 64 was exposed to 500 times the occupational standard for americium-241 as a result of an explosion in his lab. McCluskey died at the age of 75, not as a result of exposure, but of a heart disease which he had before the accident.
- http://typhoon.tokai-sc.jaea.go.jp/icnc2003/Proceeding/paper/6.5_022.pdf Archived 2007-07-10 at the Wayback Machine[full citation needed] Dias et al.
- https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html. Missing or empty
|title=(help) (dead link 11 February 2018)
- Greenwood, p. 1262
- Smoke detectors and americium Archived 2008-12-24 at the Wayback Machine, World Nuclear Association, January 2009, Retrieved 28 November 2010
- BREDL Southern Anti-Plutonium Campaign, Blue Ridge Environmental Defense League, Retrieved 28 November 2010
- Sasahara, A.; et al. (2004). "Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO2 and MOX Spent Fuels". Journal of Nuclear Science and Technology. 41 (4): 448–456. doi:10.3327/jnst.41.448. Archived from the original on 2010-11-19. article/200410/000020041004A0333355.php Abstract Archived 2010-11-24 at the Wayback Machine
- "GAMMA RAY SPECTRUM OF AM-241 IN A BACK SCATTERING GEOMETRY USING A HIGH PURITY GERMANIUM DETECTOR" (PDF).
- Audi, Georges; Kondev, Filip G.; Wang, Meng; Huang, Wen Jia; Naimi, Sarah (2017), "The NUBASE2016 evaluation of nuclear properties" (PDF), Chinese Physics C, 41 (3): 030001–1—030001–138, Bibcode:2017ChPhC..41c0001A, doi:10.1088/1674-1137/41/3/030001
- "Smoke Detectors and Americium", Nuclear Issues Briefing Paper, 35, May 2002, archived from the original on 2008-03-03, retrieved 2015-08-26
- Residential Smoke Alarm Performance, Thomas Cleary. Building and Fire Research Laboratory, National Institute of Standards and Technology; UL Smoke and Fire Dynamics Seminar. November 2007
- Bukowski, R. W. et al. (2007) Performance of Home Smoke Alarms Analysis of the Response of Several Available Technologies in Residential Fire Settings, NIST Technical Note 1455-1
- "Smoke detectors and americium-241 fact sheet" (PDF). Canadian Nuclear Society. Retrieved 31 August 2009.
- Gerberding, Julie Louise (2004). "Toxicological Profile For Americium" (PDF; 2.1 MB). United States Department of Health and Human Services/Agency for Toxic Substances and Disease Registry. Archived (PDF) from the original on 6 September 2009. Retrieved 29 August 2009.
- "Smoke Detector".
- Basic elements of static RTGs
- G.L. Kulcinski, NEEP 602 Course Notes (Spring 2000), Nuclear Power in Space, University of Wisconsin Fusion Technology Institute (see last page)
- Dr Major S. Chahal, , UK Space Agency, 9 Feb 2012, retrieved 13 Nov 2014.
- Space agencies tackle waning plutonium stockpiles, Spaceflight now, 9 July 2010
- Nell Greenfield-Boyce, Plutonium Shortage Could Stall Space Exploration, NPR, 28 Sep 2009, retrieved 2 Nov 2010.
- R.M. Ambrosi, et al. , Nuclear and Emerging Technologies for Space (2012), retrieved 23 Nov 2014.
- Binder, Harry H. (1999). Lexikon der chemischen Elemente: das Periodensystem in Fakten, Zahlen und Daten : mit 96 Abbildungen und vielen tabellarischen Zusammenstellungen. ISBN 978-3-7776-0736-8.
- Greenwood, p. 1252
- Nuclear Data Viewer 2.4, NNDC
- "Americium-241 Uses" (PDF). Archived from the original (PDF) on 2015-11-29.
- "Americium Am".
- "AMERICIUM-241 [241Am]".
- Frisch, Franz Crystal Clear, 100 x energy, Bibliographisches Institut AG, Mannheim 1977, ISBN 3-411-01704-X, p. 184
- Ken Silverstein, The Radioactive Boy Scout: When a teenager attempts to build a breeder reactor. Harper's Magazine, November 1998
- "'Radioactive Boy Scout' Charged in Smoke Detector Theft". Fox News. 4 August 2007. Archived from the original on 8 December 2007. Retrieved 28 November 2007.
- "Man dubbed 'Radioactive Boy Scout' pleads guilty". Detroit Free Press. Associated Press. 27 August 2007. Archived from the original on 29 September 2007. Retrieved 27 August 2007.
- "'Radioactive Boy Scout' Sentenced to 90 Days for Stealing Smoke Detectors". Fox News. 4 October 2007. Archived from the original on 2007-11-13. Retrieved 28 November 2007.
- Cary, Annette (25 April 2008). "Doctor remembers Hanford's 'Atomic Man'". Tri-City Herald. Archived from the original on 10 February 2010. Retrieved 17 June 2008.
- AP wire (3 June 2005). "Hanford nuclear workers enter site of worst contamination accident". Archived from the original on 13 October 2007. Retrieved 17 June 2007.