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Kkmurray (talk) 16:47, 25 January 2018 (UTC)Reply

Hello, I am Achala and I am also enrolled in CHEM 4558.Achaladk (talk) 00:31, 23 January 2018 (UTC)Reply

Welcome!

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Hello, OviniW, and welcome to Wikipedia! My name is Ian and I work with the Wiki Education Foundation; I help support students who are editing as part of a class assignment.

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If you have any questions, please don't hesitate to contact me on my talk page. Ian (Wiki Ed) (talk) 15:47, 26 January 2018 (UTC)Reply

Articles list

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The list of possible articles to edit is here: Wikipedia talk:Wiki Ed/Louisiana State University/Chemistry 4558 Mass Spectrometry (Spring 2018). Check for possible conflicts. mke sure that your list is on your talk page so that I can leave comments on your choices. --Kkmurray (talk) 18:02, 13 February 2018 (UTC)Reply

Topics of Interest for CHEM 4558

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1. Time-resolved mass spectrometry

This is an article with stub-class quality. Found to be relevant to CHEM 4558 content.

2. Time of flight

This is an article with start-quality. Found to be relevant to CHEM 4558 content.

3. Reflectron

This is an article with start-class quality. Found to be relevant to CHEM 4558 content.

4. Thermal ionization mass spectrometry

This is an article with start-class quality. Found to be relevant to CHEM 4558 content.

5. Chemical ionization

This is an article with start-class quality. Found to be relevant to CHEM 4558 content.

Selected Topic

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Chemical ionization

Bibliography

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[1] [2] [3] [4] [5]OviniW (talk) 20:33, 13 February 2018 (UTC) [6]Reply

Outline for editing

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The objective of editing the page Chemical ionization (CI) is to increase its quality by addition of several important, but missing concepts on the topic.

1.History
2.Instrumentation for CI
Conditions needed for electron emission and CI
3.Ion generation by reagent gases
Reagent gases that can be used for CI
Chemical reactions for ion formation by isobutane and ammonia
4.Advantages of CI over other ionization techniques
5.Charge Exchange CI
Introduction
Chemical reactions
6.Improving the section Negative Chemical Ionization (NIC)
Two types of Reaction schemes and examples
7.Improving the section Atmospheric Pressure Chemical Ionization (APCI)
MechanismOviniW (talk) 21:56, 13 February 2018 (UTC)Reply

Peer Review

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Below are my suggestions for your article. A. I found a few sources that appear to be primary, I think you should look through them and consider replacing them with secondary sources, if possible.

1. Munson, M.S.B.; Field, F.H. J. Am. Chem. Soc. 1966, 88, 2621-2630. Chemical Ionization Mass Spectrometry. I. General Introduction.
2. Sahba. Ghaderi; P. S. Kulkarni; Edward B. Ledford; Charles L. Wilkins; Michael L. Gross (1981). "Chemical ionization in Fourier transform mass spectrometry". Analytical Chemistry. 53 (3): 428–437. doi:10.1021/ac00226a011.
3. Kontsas, Helena; Kaija Pekari (2003-07-05). "Determination of polychlorinated biphenyls in serum using gas chromatography–mass spectrometry with negative chemical ionization for exposure estimation". Journal of Chromatography B. Elsevier, Ltd. 791 (1–2): 117–125. doi:10.1016/S1570-0232(03)00216-2. Retrieved 2008-06-26.
4. Rivera-Rodríguez, Laura B.; Ricardo Rodríguez-Estrella; James Jackson Ellington; John J. Evans (July 2007). "Quantification of low levels of organochlorine pesticidesnext term using small volumes (≤100 μl) of plasma of wild birds through gas chromatography negative chemical ionization mass spectrometry."Environmental Pollution. Elsevier, Ltd. 148 (2): 654–662. doi:10.1016/j.envpol.2006.11.018. PMID 17240024. Retrieved 2008-06-26.
5. Lacorte, Sylvia; Míriam Guillamon (2008). "Validation of a pressurized solvent extraction and GC–NCI–MSnext term method for the low level determination of 40 polybrominated diphenyl ethers in mothers' milk". Chemosphere. Elsevier, Ltd. 73 (1): 70–75. Bibcode:2008Chmsp..73...70L. doi:10.1016/j.chemosphere.2008.05.021. PMID 18582915.

B. Below are some recommended changes:

1. In the introduction I would include that chemical ionization is a type of soft ionization and that electron ionization is hard ionization. You could then further explain how this accounts for the energy differences between the two ionization techniques.]]
2.In the mechanisms section I would also add that water can be used a reagent gas, I would explain when it can be used as well (In APCI). In addition, A mechanism showing water as the regent gas should be added as there is one for each of the other 3 gases.
3.In the Advantages and disadvantages section, I would include how Chemical ionization can be coupled to HPLC. In addition, the relatively lo cost can be included as an advantage.
4.Applications: An applications section should be added. The biochemical, biological, and medicinal applications should be discussed, as they are mentioned in the introduction, but not further information is given. Any other applications should also be included here.
5.Diagrams: I would add a lead diagram that demonstrates the general idea along with a diagram that demonstrates the decryption in the “principle of Operations section.” A diagram that shows APCI may also be useful.
6.Structure: The introduction should probably better define what chemical ionization is in the first sentence and then it can be stated that it is an area of mass spectrometry.

Dgary0202 (talk) 02:19, 14 March 2018 (UTC)Reply

  1. ^ Munson, M. S. B.; Field, F. H. "Chemical Ionization Mass Spectrometry. I. General Introduction". Journal of the American Chemical Society. 88 (12): 2621–2630. doi:10.1021/ja00964a001.
  2. ^ Hunt, Donald F.; Stafford, George C.; Crow, Frank W.; Russell, John W. "Pulsed positive negative ion chemical ionization mass spectrometry". Analytical Chemistry. 48 (14): 2098–2104. doi:10.1021/ac50008a014.
  3. ^ Harrison, Alex G. (1992). Chemical Ionization Mass Spectrometry, Second Edition. CRC Press. ISBN 9780849342547.
  4. ^ Dougherty, Ralph C. "Negative chemical ionization mass spectrometry". Analytical Chemistry. 53 (4): 625–636. doi:10.1021/ac00227a003.
  5. ^ Hunt, Donald F.; McEwen, Charles N.; Harvey, T. Michael. "Positive and negative chemical ionization mass spectrometry using a Townsend discharge ion source". Analytical Chemistry. 47 (11): 1730–1734. doi:10.1021/ac60361a011.
  6. ^ Dass, Chhabil (2007). Fundamentals of contemporary mass spectrometry ([Online-Ausg.]. ed.). Hoboken, N.J.: Wiley-Interscience. ISBN 9780470118498.