10 gram sample
|Name, symbol||Uranium-238, 238U|
|Half-life||4.468 billion years|
|Parent isotopes||242Pu (α)
|Isotope mass||238.05078826 u|
|Decay mode||Decay energy|
|Alpha decay||4.267 MeV|
Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of U-238's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.
Around 99.284% of natural uranium's mass is uranium-238, which has a half-life of 1.41×1017 seconds (4.468×109 years, or 4.468 billion years). Due to its natural abundance and half-life relative to other radioactive elements, produces ~40% of the radioactive heat produced within the Earth. decay contributes 6 electron anti-neutrinos per decay (1 per beta decay), resulting in a large detectable geoneutrino signal when decays occur within the Earth. The decay of to daughter isotopes is extensively used in radiometric dating, particularly for material older than ~ 1 million years.
Depleted uranium has an even higher concentration of the 238U isotope, and even low-enriched uranium (LEU), while having a higher proportion of the uranium-235 isotope (in comparison to depleted uranium), is still mostly 238U. Reprocessed uranium is also mainly 238U, with about as much uranium-235 as natural uranium, a comparable proportion of uranium-236, and much smaller amounts of other isotopes of uranium such as uranium-234, uranium-233, and uranium-232.
Nuclear energy applicationsEdit
In a fission nuclear reactor, uranium-238 can be used to generate 239Pu, which itself can be used in a nuclear weapon or as a nuclear-reactor fuel supply. In a typical nuclear reactor, up to one-third of the generated power does come from the fission of 239Pu, which is not supplied as a fuel to the reactor, but rather, produced from 238U.
238U is not usable directly as nuclear fuel, though it can produce energy via "fast" fission. In this process, a neutron that has a kinetic energy in excess of 1 MeV can cause the nucleus of 238U to split in two. Depending on design, this process can contribute some one to ten percent of all fission reactions in a reactor, but too few of the about 2.5 neutrons produced in each fission have enough speed to continue a chain reaction.
238U can be used as a source material for creating plutonium-239, which can in turn be used as nuclear fuel. Breeder reactors carry out such a process of transmutation to convert the fertile isotope 238U into fissile Pu-239. It has been estimated that there is anywhere from 10,000 to five billion years worth of 238U for use in these power plants. Breeder technology has been used in several experimental nuclear reactors.
By December 2005, the only breeder reactor producing power was the 600-megawatt BN-600 reactor at the Beloyarsk Nuclear Power Station in Russia. Russia has planned to build another unit, BN-800, at the Beloyarsk nuclear power plant. Also, Japan's Monju breeder reactor is planned to be started, having been shut down since 1995, and both China and India have announced plans to build nuclear breeder reactors. However, after safety and design hazards were uncovered, in 2016 the Japanese government ordered the decommissioning of the Monju reactor which may be completed by 2047.
The breeder reactor as its name implies creates even larger quantities of Pu-239 than the fission nuclear reactor.
The Clean And Environmentally Safe Advanced Reactor (CAESAR), a nuclear reactor concept that would use steam as a moderator to control delayed neutrons, will potentially be able to burn 238U as fuel once the reactor is started with LEU fuel. This design is still in the early stages of development.
238U is also used as a radiation shield – its alpha radiation is easily stopped by the non-radioactive casing of the shielding and the uranium's high atomic weight and high number of electrons are highly effective in absorbing gamma rays and x-rays. It is not as effective as ordinary water for stopping fast neutrons. Both metallic depleted uranium and depleted uranium dioxide are used for radiation shielding. Uranium is about five times better as a gamma ray shield than lead, so a shield with the same effectiveness can be packed into a thinner layer.
The opposite of enriching is downblending. Surplus highly enriched uranium can be downblended with depleted uranium or natural uranium to turn it into low enriched uranium suitable for use in commercial nuclear fuel.
238U from depleted uranium and natural uranium is also used with recycled Pu-239 from nuclear weapons stockpiles for making mixed oxide fuel (MOX), which is now being redirected to become fuel for nuclear reactors. This dilution, also called downblending, means that any nation or group that acquired the finished fuel would have to repeat the very expensive and complex chemical separation of uranium and plutonium process before assembling a weapon.
Most modern nuclear weapons utilize 238U as a "tamper" material (see nuclear weapon design). A tamper which surrounds a fissile core works to reflect neutrons and to add inertia to the compression of the Pu-239 charge. As such, it increases the efficiency of the weapon and reduces the critical mass required. In the case of a thermonuclear weapon 238U can be used to encase the fusion fuel, the high flux of very energetic neutrons from the resulting fusion reaction causes 238U nuclei to split and adds more energy to the "yield" of the weapon. Such weapons are referred to as fission-fusion-fission weapons after the order in which each reaction takes place. An example of such a weapon is Castle Bravo.
The larger portion of the total explosive yield in this design comes from the final fission stage fueled by 238U, producing enormous amounts of radioactive fission products. For example, an estimated 77% of the 10.4-megaton yield of the Ivy Mike thermonuclear test in 1952 came from fast fission of the depleted uranium tamper. Because depleted uranium has no critical mass, it can be added to thermonuclear bombs in almost unlimited quantity. The Soviet Union's test of the "Tsar Bomba" in 1961 produced "only" 50 megatons of explosive power, over 90% of which came from fusion, because the 238U final stage had been replaced with lead. Had 238U been used instead, the yield of the "Tsar Bomba" could have been well-above 100 megatons, and it would have produced nuclear fallout equivalent to one third of the global total that had been produced up to that time.
Radium series (or uranium series)Edit
The decay chain of 238U is commonly called the "radium series" (sometimes "uranium series"). Beginning with naturally occurring uranium-238, this series includes the following elements: astatine, bismuth, lead, polonium, protactinium, radium, radon, thallium, and thorium. All are present, at least transiently, in any uranium-containing sample, whether metal, compound, or mineral. The decay proceeds as:
The mean lifetime of 238U is 1.41×1017 seconds divided by 0.693 (or multiplied by 1.443), i.e. ca. 2×1017 seconds, so 1 mole of 238U emits 3×106 alpha particles per second, producing the same number of thorium-234 (Th-234) atoms. In a closed system an equilibrium would be reached, with all amounts except for lead-206 and 238U in fixed ratios, in slowly decreasing amounts. The amount of Pb-206 will increase accordingly while that of 238U decreases; all steps in the decay chain have this same rate of 3×106 decayed particles per second per mole 238U.
Thorium-234 has a mean lifetime of 3×106 seconds, so there is equilibrium if one mole of 238U contains 9×1012 atoms of thorium-234, which is 1.5×10−11 mole (the ratio of the two half-lives). Similarly, in an equilibrium in a closed system the amount of each decay product, except the end product lead, is proportional to its half-life.
As already touched upon above, when starting with pure 238U, within a human timescale the equilibrium applies for the first three steps in the decay chain only. Thus, for one mole of 238U, 3×106 times per second one alpha and two beta particles and gamma ray are produced, together 6.7 MeV, a rate of 3 µW. Extrapolated over 2×1017 seconds this is 600 gigajoules, the total energy released in the first three steps in the decay chain.
abundance and its decay to daughter isotopes comprises multiple "uranium dating" techniques and is one of the most common radioactive isotopes used in radiometric dating. The most common dating method is uranium-lead dating, which is used to date rocks older than 1 million years old and has provided ages for the oldest rocks on Earth at 4.4 billion years old.
- Mcclain, D. E.; Miller, A. C.; Kalinich, J. F. (December 20, 2007). "Status of Health Concerns about Military Use of Depleted Uranium and Surrogate Metals in Armor-Penetrating Munitions" (pdf). NATO. Retrieved November 14, 2010.
- Arevalo, Ricardo; McDonough, William F.; Luong, Mario. "The K/U ratio of the silicate Earth: Insights into mantle composition, structure and thermal evolution". Earth and Planetary Science Letters. 278 (3–4): 361–369. Bibcode:2009E&PSL.278..361A. doi:10.1016/j.epsl.2008.12.023.
- Araki, T.; Enomoto, S.; Furuno, K.; Gando, Y.; Ichimura, K.; Ikeda, H.; Inoue, K.; Kishimoto, Y.; Koga, M. "Experimental investigation of geologically produced antineutrinos with KamLAND". Nature. 436 (7050): 499–503. Bibcode:2005Natur.436..499A. doi:10.1038/nature03980.
- Nuclear France: Materials and sites. "Uranium from reprocessing".
- World Nuclear Association http://www.world-nuclear.org/information-library/nuclear-fuel-cycle/introduction/physics-of-nuclear-energy.aspx. Retrieved November 17, 2017. Missing or empty
- Facts from Cohen. Formal.stanford.edu (2007-01-26). Retrieved on 2010-10-24.
- Advanced Nuclear Power Reactors | Generation III+ Nuclear Reactors. World-nuclear.org. Retrieved on 2010-10-24.
- Valley, John W.; Reinhard, David A.; Cavosie, Aaron J.; Ushikubo, Takayuki; Lawrence, Daniel F.; Larson, David J.; Kelly, Thomas F.; Snoeyenbos, David R.; Strickland, Ariel (2015-07-01). "Nano- and micro-geochronology in Hadean and Archean zircons by atom-probe tomography and SIMS: New tools for old minerals" (PDF). American Mineralogist. 100 (7): 1355–1377. doi:10.2138/am-2015-5134. ISSN 0003-004X.
- Henderson, Gideon M. "Seawater (234U/238U) during the last 800 thousand years". Earth and Planetary Science Letters. 199 (1-2): 97–110. Bibcode:2002E&PSL.199...97H. doi:10.1016/S0012-821X(02)00556-3. Retrieved 2017-08-09.
- Patterson, Claire (1956-10-01). "Age of meteorites and the earth". Geochimica et Cosmochimica Acta. 10 (4): 230–237. Bibcode:1956GeCoA..10..230P. doi:10.1016/0016-7037(56)90036-9.