Pentalenene oxygenase (EC 1.14.15.32, Formerly EC 1.14.13.133, PtlI) is an enzyme with systematic name pentalenene,NADPH:oxygen 13-oxidoreductase.[1] This enzyme catalyses the following chemical reaction
- pentalenene + 2 NADPH + 2 H+ + 2 O2 pentalen-13-al + 2 NADP+ + 3 H2O (overall reaction)
- (1a) pentalenene + NADPH + H+ + O2 pentalen-13-ol + NADP+ + H2O
- (1b) pentalen-13-ol + NADPH + H+ + O2 pentalen-13-al + NADP+ + 2 H2O
Pentalenene oxygenase is a heme-thiolate protein (P-450).
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