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Mueller is a spelling variant of the German surname Müller ("miller"). In German, the letter "ü" can be replaced with "ue". Notable people with the surname include:
- Armin Mueller-Stahl (born 1930), German actor
- Barbara R. Mueller, an American philatelist
- Bill Mueller (born 1971), American baseball player
- Brooke Mueller (born 1977), American actress
- Caleb Mueller ("Decomposure"), Canadian electronic music mixer, graphic and visual artist
- Christopher Mueller (disambiguation), several people
- Cookie Mueller (1949–1989), American actress
- Earl Mueller (?–1932), American basketball player
- Edward Mueller is the current Chief Executive Officer and Chairman of Qwest Communications.
- Ferdinand von Mueller (von Müller) (1825–1896), German-Australian botanist
- Frederick Henry Mueller (1893–1976), U.S. administrator
- Gene Mueller (born 1942), historian and author
- George Mueller (NASA) (1918–2015), former NASA deputy administrator
- Greg Mueller (born 1971), Canadian poker player
- Gussie Mueller (1890–1965), U.S. jazz clarinetist
- Ivan Mueller, Russian clarinetist
- Jean Mueller, U.S. astronomer
- John Mueller (born 1937), U.S. political scientist
- Jon Mueller (born 1970), American drummer, percussionist, and composer
- Jon Mueller (baseball) (born 1970), American college baseball coach
- Karl Mueller (rock musician) (1963–2005), U.S. rock musician
- Mervyn Mueller (1914–1984), Australian cricketer
- Peter Mueller (hockey player) (born 1988), NHL player for the Florida Panthers
- Peter Mueller (skater) (born 1954), former speed skater and speed skating coach from the United States
- Robert Mueller (born 1944), U.S. lawyer, former Director of the FBI
- Scott Mueller, an author of books concerning personal computers, as well as president of Mueller Technical Research, a research and training firm.
- Wolfgang Philipp Mueller (born 1966), German founder of VDM Publishing
- Ryan Mueller, (born 1991), American football linebacker for San Diego Chargers