An LNG carrier is a tank ship designed for transporting liquefied natural gas (LNG).

LNG Rivers, a Moss-type carrier with a capacity of 135,000 cubic metres (4,770,000 cu ft)

Overview edit

The first oceangoing liquified natural gas tanker in the world was Methane Pioneer, which entered service in 1959 with a carrying capacity of 5,500 cubic metres (190,000 cu ft).[1] LNG carriers of increasing size have been built since then, leading to the fleet of today, where giant Q-Max LNG ships sail worldwide that can each carry up to 266,000 m3 (9,400,000 cu ft).

A boom in U.S. natural gas production was enabled by hydraulic fracturing ("fracking"), creating large growth in natural gas production from 2010.[2] The first U.S. LNG export facility was completed in 2016, with more following.[3] The increasing supply of natural gas in the U.S. and export facilities expanded the demand for LNG carriers, to transport LNG around the world.[4]

The 2022 Russian invasion of Ukraine dramatically increased the demand for LNG shipping worldwide. U.S. shipments to Europe more than doubled in 2022, to 2.7 trillion cubic feet.[5]

History edit

 

The first LNG carrier Methane Pioneer (5,034 DWT) carrying 5,500 cubic metres (190,000 cu ft), classed by Bureau Veritas, left the Calcasieu River on the Louisiana Gulf coast on 25 January 1959. Carrying the world's first ocean cargo of LNG, it sailed to the UK where the cargo was delivered.[1] The success of the specially modified C1-M-AV1-type standard ship Normarti, renamed Methane Pioneer, caused the Gas Council and Conch International Methane Ltd. to order two purpose built LNG carriers to be constructed: Methane Princess and Methane Progress. The ships were fitted with Conch independent aluminum cargo tanks and entered the Algerian LNG trade in 1964. These ships had a capacity of 27,000 cubic metres (950,000 cu ft).

In the late 1960s, opportunity arose to export LNG from Alaska to Japan, and in 1969 that trade with TEPCO and Tokyo Gas was initiated. Two ships, Polar Alaska and Arctic Tokyo, each with a capacity of 71,500 cubic metres (2,520,000 cu ft), were built in Sweden. In the early 1970s, the US government encouraged US shipyards to build LNG carriers, and a total of 16 LNG ships were built. The late 1970s and early 1980s brought the prospect of Arctic LNG ships with a number of projects being studied.

With the increase in cargo capacity to approximately 143,000 cubic metres (5,000,000 cu ft) costing $250 million,[6] new tank designs were developed, from Moss Rosenberg to Technigaz Mark III and Gaztransport No.96.

The size and capacity of LNG carriers has increased significantly,[7] to 170,000 cubic metres (6,000,000 cu ft). A vessel could cost $200 million.[6]

Since 2005, Qatargas has pioneered the development of two new classes of LNG carriers, referred to as Q-Flex and Q-Max. Each ship has a cargo capacity of between 210,000 and 266,000 cubic metres (7,400,000 and 9,400,000 cu ft) and is equipped with a re-liquefaction plant.

Today[when?] we see interest for small scale LNG bunker carriers. Some need to stay below the life rafts of Cruise ships and Ropax vessels. Examples are the Damen LGC 3000[8] and the Seagas.

By 2005 a total of 203 vessels had been built, of which 193 were still in service. At the end of 2016, the global LNG shipping fleet consisted of 439 vessels.[9] In 2017, an estimated 170 vessels are in use at any one time.[10] At the end of 2018, the global fleet was approximately 550 vessels.[11]

In 2021—2022, an LNG shipment from US to Europe could return a profit of $133—200 million. Shipping rates were $100,000 per day[12] even for 5-year contracts, but can vary between $60,000—250,000.[13]

New building edit

 
LNG carrier under construction at DSME shipyard, Okpo-dong
 
Diagram of newbuild LNG vessels delivered every year from 1965 to 2022.[14]

In 2021, 90 new LNG carriers were ordered.[15] By 2022, high demand had shifted deliveries of new orders to 2027.[13]

In November 2018, South Korean ship builders locked in 3 years worth of large-scale LNG carrier contracts - more than 50 orders - with a value of $9 billion. South Korean builders captured 78% of LNG-related ship building contracts in 2018, with 14% going to Japanese builders and 8% going to Chinese builders. The new contracts would boost the global LNG fleet by 10%. Of the global fleet, historically, about two-thirds of the ships have been built by South Koreans, 22% by Japanese, 7% by Chinese, and the rest built by a combination of France, Spain, and the United States. South Korea's success stems from innovation and price point; South Korean builders introduced the first ice-breaker type LNG vessels and South Korean builders have been successful in catering to increased customer preference for Q-max vessels over Moss type.[16]

In 2018, South Korea's Hyundai Mipo Dockyard (HMD) delivered the world's first LNG-fueled bulk carrier. It has the world's largest capacity at 50,000 dwt.[17]

According to SIGTTO data, in 2019 there were 154 LNG carriers on order, and 584 operating LNG carriers. [18]

In 2017, Daewoo Shipbuilding & Marine Engineering delivered the Christophe de Margerie, an icebreaking LNG tanker of 80,200 deadweight tons. Her capacity of 172,600 m3 (6,100,000 cu ft) is the consumption of Sweden for a month.[19] She completed her first revenue voyage from Norway via the Northern Sea Route in the Arctic Ocean to South Korea.[20] The shipyard has fourteen more on order.[21]

In the case of small scale LNG carriers (LNG carriers below 40,000 m3 (1,400,000 cu ft)), the optimal size of a ship is determined by the project for which it is built, taking into consideration volume, destination and vessel characteristics.[22]

List of small scale LNG carrier builders:

Cargo handling edit

 

A typical LNG carrier has four to six tanks located along the center-line of the vessel. Surrounding the tanks is a combination of ballast tanks, cofferdams and voids; in effect, this gives the vessel a double-hull type design.

LNG carriers, like aircraft carriers, are among the most difficult vessels to build, taking as long as 30 months.[23]

Inside each tank there are typically three submerged pumps. There are two main cargo pumps which are used in cargo discharge operations and a much smaller pump which is referred to as the spray pump. The spray pump is used for either pumping out liquid LNG to be used as fuel (via a vaporizer), or for cooling down cargo tanks. It can also be used for "stripping" out the last of the cargo in discharge operations. All of these pumps are contained within what is known as the pump tower which hangs from the top of the tank and runs the entire depth of the tank. The pump tower also contains the tank gauging system and the tank filling line, all of which are located near the bottom of the tank.

In membrane-type vessels there is also an empty pipe with a spring-loaded foot valve that can be opened by weight or pressure. This is the emergency pump tower. In the event both main cargo pumps fail the top can be removed from this pipe and an emergency cargo pump lowered down to the bottom of the pipe. The top is replaced on the column and then the pump is allowed to push down on the foot valve and open it. The cargo can then be pumped out.

All cargo pumps discharge into a common pipe which runs along the deck of the vessel; it branches off to either side of the vessel to the cargo manifolds, which are used for loading or discharging.

All cargo tank vapour spaces are linked via a vapour header which runs parallel to the cargo header. This also has connections to the sides of the ship next to the loading and discharging manifolds.

Typical cargo cycle edit

A typical cargo cycle starts with the tanks in a "gas free" condition, meaning the tanks are full of air, which allows maintenance on the tank and pumps. Cargo cannot be loaded directly into the tank, as the presence of oxygen would create an explosive atmospheric condition within the tank, and the rapid temperature change caused by loading LNG at −162 °C (−260 °F) could damage the tanks.

First, the tank must be 'inerted' to eliminate the risk of explosion. An inert gas plant burns diesel in air to produce a mixture of gases (typically less than 5% O2 and about 13% CO2 plus N2). This is blown into the tanks until the oxygen level is below 4%.

Next, the vessel goes into port to "gas-up" and "cool-down", as one still cannot load directly into the tank: The CO2 will freeze and damage the pumps and the cold shock could damage the tank's pump column.

LNG is brought onto the vessel and taken along the spray line to the main vaporiser, which boils off the liquid into gas. This is then warmed up to roughly 20 °C (68 °F) in the gas heaters and then blown into the tanks to displace the "inert gas". This continues until all the CO2 is removed from the tanks. Initially, the IG (inert gas) is vented to atmosphere. Once the hydrocarbon content reaches 5% (lower flammability range of methane) the inert gas is redirected to shore via a pipeline and manifold connection by the HD (high duty) compressors. The shore terminal then burns this vapour to avoid the dangers of having large amounts of hydrocarbons present which may explode.

Now the vessel is gassed up and warm. The tanks are still at ambient temperature and are full of methane.

The next stage is cool-down. LNG is sprayed into the tanks via spray heads, which vaporises and starts to cool the tank. The excess gas is again blown ashore to be re-liquified or burned at a flare stack. Once the tanks reach about −140 °C (−220 °F) the tanks are ready to bulk load.

Bulk loading starts and liquid LNG is pumped from the storage tanks ashore into the vessel tanks. Displaced gas is blown ashore by the HD compressors. Loading continues until typically 98.5% full is reached (to allow for thermal expansion/contraction of cargo).

The vessel can now proceed to the discharge port. During passage various boil-off management strategies can be used. Boil-off gas can be burned in boilers to provide propulsion, or it can be re-liquefied and returned to the cargo tanks, depending on the design of the vessel.

Once in the discharge port, the cargo is pumped ashore using the cargo pumps. As the tank empties, the vapour space is filled by either gas from ashore or by vaporising some cargo in the cargo vaporiser. Either the vessel can be pumped out as far as possible, with the last being pumped out with spray pumps, or some cargo can be retained on board as a "heel".

It is normal practice to keep onboard 5% to 10%[citation needed] of the cargo after discharge in one tank. This is referred to as the heel and this is used to cool down the remaining tanks that have no heel before loading. This must be done gradually otherwise the tanks will be cold shocked if loaded directly into warm tanks. Cool-down can take roughly 20[24] hours on a Moss vessel (and 10–12 hours on a membrane type vessel), so carrying a heel allows cool-down to be done before the vessel reaches port giving a significant time saving.

If all the cargo is pumped ashore, then on the ballast passage the tanks will warm up to ambient temperature, returning the vessel to a gassed up and warm state. The vessel can then be cooled again for loading.

If the vessel is to return to a gas free state, the tanks must be warmed up by using the gas heaters to circulate warm gas. Once the tanks are warmed up, the inert gas plant is used to remove the methane from the tanks. Once the tanks are methane free, the inert gas plant is switched to dry air production, which is used to remove all the inert gas from the tanks until they have a safe working atmosphere.

Transportation of natural gas both in the form of LNG and by pipeline causes greenhouse gas emissions, but in different ways. With pipelines, most of the emissions stem from the production of steel pipe; with LNG most of the emissions stem from liquefaction. For both pipelines and LNG, propulsion causes additional emissions (pressurization of the pipeline, propulsion of the LNG tanker).[7]

Containment systems edit

 
The inside of a Moss-type LNG carrier

Today there are four containment systems in use for new build vessels. Two of the designs are of the self-supporting type, while the other two are of the membrane type and today the patents are owned by Gaztransport & Technigaz (GTT).

There is a trend towards the use of the two different membrane types instead of the self-supporting storage systems. This is most likely because prismatic membrane tanks utilize the hull shape more efficiently and thus have less void space between the cargo-tanks and ballast tanks. As a result of this, Moss-type design compared to a membrane design of equal capacity will be far more expensive to transit the Suez Canal. However, self-supporting tanks are more robust and have greater resistance to sloshing forces, and will possibly be considered in the future for offshore storage where bad weather will be a significant factor.

Moss tanks (Spherical IMO type B LNG tanks) edit

 
LNG Moss-type tanker, side view

Named after the company that designed them, the Norwegian company Moss Maritime, the Spherical IMO type B LNG tanks are spherical in shape. Most Moss type vessels have four or five tanks.

The outside of the tanks have a thick layer of foam insulation that is either fitted in panels or in more modern designs wound round the tank. Over this insulation is a thin layer of "tinfoil" which allows the insulation to be kept dry with a nitrogen atmosphere. This atmosphere is constantly checked for any methane that would indicate a leak of the tank. Also the outside of the tank is checked at three-month intervals for any cold spots that would indicate breakdown in the insulation.

The tank is supported around its circumference by the equatorial ring, which is supported by a large circular skirt, known as a data-couple that is a unique combination of aluminum and steel, which takes the weight of the tank down to the ship's structure. This skirt allows the tank to expand and contract during cool-down and warm-up operations. During cool-down or warm-up the tank can expand or contract about 60 cm (24 in). Because of this expansion and contraction all piping into the tank comes in the top and is connected to the ship's lines via flexible bellows.

Inside each tank there is a set of spray heads. These heads are mounted around the equatorial ring and are used to spray LNG onto the tank walls to reduce the temperature.

Tanks normally have a working pressure of up to 22 kPa (3.2 psi), but this can be raised for emergency discharge. If both main pumps fail then to remove the cargo, the tank's safety valves are adjusted to lift at 100 kPa (1 bar). Then the filling line which goes to the bottom of the tank is opened along with the filling lines of the other tanks on board. The pressure is then raised in the tank with the defective pumps which pushes the cargo into the other tanks where it can be pumped out.[25]

IHI (Prismatic IMO type B LNG tanks) edit

Designed by Ishikawajima-Harima Heavy Industries, the self-supporting prismatic type B (SPB) tank is currently employed in only two vessels. Type B tanks limit sloshing problems, an improvement over Membrane LNG carrier tanks which may break due to sloshing impact, therefore destroying the ship's hull. This is also of prime relevance for FPSO LNG (or FLNG).

In addition, IMO type B LNG tanks can sustain internal accidental damage due for example to internal equipment releases. This was incorporated into the design following several incidents that occurred inside membrane LNG tanks.[citation needed]

TGZ Mark III edit

 
Interior of a non-spherical, Technigaz Mark III stainless steel membrane, LNG tank

Designed by Technigaz, these tanks are of the membrane type. The membrane consists of stainless steel with 'waffles' to absorb the thermal contraction when the tank is cooled down. The primary barrier, made of corrugated stainless steel of about 1.2 mm (0.047 in) thickness is the one in direct contact with the cargo liquid (or vapour in empty tank condition). This is followed by a primary insulation which in turn is covered by a secondary barrier made of a material called "triplex" which is basically a metal foil sandwiched between glass wool sheets and compressed together. This is again covered by a secondary insulation which in turn is supported by the ship's hull structure from the outside.[26][27]

From the inside of the tank outwards, the layers are:

  • LNG
  • Primary barrier of 1.2 mm thick corrugated/waffled 304L stainless steel
  • Primary insulation (also called the interbarrier space)
  • Secondary barrier within triplex membrane
  • Secondary insulation (also called the insulation space)
  • Ship's hull structure.

GT96 edit

Designed by Gaztransport, the tanks consists of a primary and secondary thin membrane made of the material Invar which has almost no thermal contraction. The insulation is made out of plywood boxes filled with perlite and continuously flushed with nitrogen gas. The integrity of both membranes is permanently monitored by detection of hydrocarbon in the nitrogen. An evolution is proposed by NG2, with the replacement of nitrogen by argon as the flushed inert and insulation gas. Argon has a better insulation power than nitrogen, which could save 10% of boil-off gas.[27][28]

CS1 edit

CS1 stands for Combined System Number One. It was designed by the now merged Gaztransport & Technigaz companies and consists of the best components of both MkIII and No96 systems. The primary barrier is made of invar 0.7 mm (0.028 in), and secondary from Triplex. The primary and secondary insulation consists of polyurethane foam panels.

Three vessels with CS1 technology were built[when?] by one shipyard, but established shipyards have decided to maintain production of the MKIII and NO96.[citation needed]

Reliquefaction and boil-off edit

In order to facilitate transport, natural gas is cooled down to approximately −163 °C (−261 °F) at atmospheric pressure, at which point the gas condenses to a liquid. The tanks on board an LNG carrier effectively function as giant thermoses to keep the liquid gas cold during storage. No insulation is perfect, however, and so the liquid is constantly boiling during the voyage.

According to WGI, on a typical voyage an estimated 0.1–0.25% of the cargo converts to gas each day, depending on the efficiency of the insulation and the roughness of the voyage.[29][30] In a typical 20-day voyage, anywhere from 2–6% of the total volume of LNG originally loaded may be lost.[29]

Normally[according to whom?] an LNG tanker is powered by steam turbines with boilers. These boilers are dual fuel and can run on either methane or oil or a combination of both.

The gas produced in boil off is traditionally diverted to the boilers and used as a fuel for the vessel. Before this gas is used in the boilers, it must be warmed up to roughly 20 °C by using the gas heaters. The gas is either fed into the boiler by tank pressure or it is increased in pressure by the Low Duty[clarification needed] compressors.

What fuel the vessel runs on is dependent on many factors which include the length of the voyage, desire to carry a heel for cooldown, price of oil versus price of LNG, and port demands for cleaner exhaust.

There are three basic modes available:[citation needed]

Minimum boil-off/maximum oil: In this mode tank pressures are kept high to reduce boil off to a minimum and the majority of energy comes from the fuel oil. This maximises the amount of LNG delivered but does allow tank temps to rise due to lack of evaporation. The high cargo temps can cause storage problems and offloading problems.

Maximum boil-off/minimum oil: In this mode the tank pressures are kept low and there is greater boil-off but a large amount of fuel oil is still used. This decreases the amount of LNG delivered but the cargo will be delivered cold which many ports prefer.

100% gas: Tank pressures are kept at a similar level to maximum boil off but as this may not be enough to supply all the boilers needs, additional LNG must be "forced" to vaporize. A small pump in one tank supplies LNG to the forcing vaporizer, where it is warmed and vaporized back into a gas that is usable in the boilers. In this mode no fuel oil is used.

Recent[when?] advances in technology reliquefication plants to be fitted to vessels, allowing the boil off to be reliquefied and returned to the tanks. Because of this, the vessels' operators and builders have been able to contemplate the use of more efficient slow-speed diesel engines (previously most LNG carriers have been steam turbine-powered). Exceptions are the LNG carrier Havfru (built as Venator in 1973), which originally had dual fuel diesel engines, and its sister-ship Century (built as Lucian in 1974), also built with dual fuel gas turbines before being converted to a diesel engine system in 1982.[citation needed]

Vessels using Dual or Tri-Fuel Diesel Electric, respectively DFDE/TFDE, propulsion systems are now in service.[31]

Recently, there has been interest in a return to propulsion by boil-off gas. This is a result of the IMO 2020 anti-pollution regulation that bans the use of marine fuel oil with a sulfur content greater than 0.5% on ships not fitted with flue-gas scrubbing plant. Space constraints and safety issues typically prevent the installation of such equipment on LNG carriers, forcing them to abandon the use of the lower-cost, high-sulfur fuel oil and switch to low-sulfur fuels that cost more and are in shorter supply. In these circumstances, boil-off gas may become a more attractive option.[32]

Spillage risk edit

Compared to oil, there is less public concern over spillage of Liquid Natural Gas (LNG) carrying vessels as the gas would quickly vaporize and become atmospheric methane.[33]

Up to 2004, no significant accidental LNG discharges occurred in close to 80,000 loaded port transits of LNG carriers.[34]

An analysis of several spherical carriers showed that the vessels can withstand a 90-degree side-on collision with another similar LNG carrier at 6.6 kn (50% of normal port speed) with no loss of LNG cargo integrity.[35] This drops to 1.7 kn for a fully loaded 300,000 dwt oil tanker collision into an LNG carrier. The report also notes that such collisions are rare.[34]

HAZID performed a risk assessment of an LNG spill. Taking into account precautions, training, regulations and technology changes over time HAZID calculates that the likelihood of an LNG spill as approximately 1 in 100,000 trips.[34]

In the event that the tank integrity of a LNG transport is compromised, there is a risk that the natural gas contained within could ignite, causing either an explosion or fire.[36]

See also edit

References edit

  1. ^ a b Noble, Peter G. (10 February 2009). "A Short History of LNG Shipping: 1959–2009" (PDF). Society of Naval Architects & Marine Engineers. Retrieved 23 February 2023.
  2. ^ "Where our natural gas comes from - U.S. Energy Information Administration (EIA)". Energy Information Administration. Retrieved 24 February 2023.
  3. ^ "Cheniere loading first LNG export at Louisiana terminal". Archived from the original on 2 September 2016. Retrieved 1 April 2016.
  4. ^ "U.S. Needs 100 LNG Ships, 30 Years". The Maritime Executive. Retrieved 24 February 2023.
  5. ^ Storrow, Benjamin (21 February 2023). "How Russia's war shattered global energy routes". E&E News. Retrieved 24 February 2023.
  6. ^ a b Corkhill, Mike (21 August 2015). "LNG shipping by numbers". Riviera. Archived from the original on 21 April 2022.
  7. ^ a b Ulvestad, Marte; Overland, Indra (2012). "Natural gas and CO2 price variation: Impact on the relative cost-efficiency of LNG and pipelines". International Journal of Environmental Studies. 69 (3): 407–426. doi:10.1080/00207233.2012.677581. PMC 3962073. PMID 24683269.
  8. ^ "Liquefied gas carrier". products.damen.com.
  9. ^ "2017 World LNG Report" (PDF). IGU(International Gas Union). Archived from the original (PDF) on 10 February 2020. Retrieved 9 January 2018.
  10. ^ Gold, Russell (7 June 2017). "Global market for natural gas has finally arrived". The Australian. Retrieved 7 June 2017.
  11. ^ Kravtsova, Ekaterina (15 April 2019). "LNG transport is where the big money is". Cyprus Mail. Retrieved 15 April 2019.
  12. ^ Miller, Greg (13 September 2022). "LNG shipping rates top $100,000/day, oil tanker rates still rising". FreightWaves. Archived from the original on 18 September 2022.
  13. ^ a b Miller, Greg (24 August 2022). "Price of LNG goes stratospheric. Will LNG shipping rates follow?". FreightWaves. Archived from the original on 13 September 2022.
  14. ^ Dmitry, Shafran (23 January 2023). "Maritime Page: "Discover the Top 10 LNG Carrier Operators in the World"". Maritime Page. Retrieved 23 January 2023.
  15. ^ Hine, Lucy (10 January 2022). "It's official: 2021 was a record-breaker for LNG carrier orders | TradeWinds". TradeWinds | Latest shipping and maritime news.
  16. ^ Jane Chung, Yuka Obayashi (19 November 2018). "South Korean shipbuilders' lock on LNG tanker market to hold for years". Reuters. Retrieved 20 November 2018.
  17. ^ "South Korea Builds World's First LNG Bulk Carrier". Port Technology. Retrieved 3 February 2022.
  18. ^ "Global LNG Carrier Fleet". Global LNG Hub. Retrieved 3 February 2022.
  19. ^ "Unique ice-breaking LNG carrier Christophe de Margerie ready to serve Yamal LNG project". Hellenic Shipping News. 31 March 2017. Archived from the original on 24 August 2017. Retrieved 24 August 2017.
  20. ^ McGrath, Matt (24 August 2017). "First tanker crosses northern sea route without ice breaker". BBC. Retrieved 24 August 2017.
  21. ^ "Christophe de Margerie Class Icebreaking LNG Carriers". Ship Technology. Retrieved 24 August 2017.
  22. ^ "Small Scale Carrier Optimal Vessel Size Calculator". Archived from the original on 17 December 2014. Retrieved 24 September 2014.
  23. ^ Aizhu, Chen (12 December 2022). "China shipyards feast on record LNG tanker orders as South Korea builders are full up". Reuters. Retrieved 21 February 2023.
  24. ^ GIIGNL Fourth Edition 2.6.2
  25. ^ "Pressure distribution in the liquid". googletechnews. Archived from the original on 26 December 2022. Retrieved 26 December 2022.
  26. ^ "GTT Mark III Technology". Gaztransport & Technigaz (GTT) via YouTube. 7 November 2013.[dead YouTube link]
  27. ^ a b "Membrane Containment System". North West Shelf Shipping Services Company (NWSSSC) Pty. Limited. 2014. Archived from the original on 29 October 2017. Retrieved 10 August 2016.
  28. ^ "GTT Mark III Technology". Gaztransport & Technigaz (GTT) via YouTube. 7 November 2013.[dead YouTube link]
  29. ^ a b World Gas Intelligence, 30 July 2008
  30. ^ "Term". Wärtsilä Encyclopedia. Archived from the original on 13 August 2019.
  31. ^ Snyder, John. "DFDE LNG carrier for Japanese joint venture". Riviera. Riviera Maritime Media Ltd. Retrieved 2 February 2024.
  32. ^ "Forced boil-off gas: The future of LNG as a fuel for LNG carriers". www.mckinsey.com. McKinsey & Company. 19 July 2019. Retrieved 17 August 2020.
  33. ^ "How Dangerous is LNG?". www.breakingenergy.com. 22 December 2014. Retrieved 30 November 2021.
  34. ^ a b c Pitblado, R. M.; Baik, J.; Hughes, G. J.; Ferro, C.; Shaw, S. J. (2005). "Consequences of liquefied natural gas marine incidents" (PDF). Process Safety Progress. 24 (2): 108–114. Archived from the original (PDF) on 19 February 2018.
  35. ^ Mokhatab, Saeid; Mak, John Y.; Valappil, Jaleel V.; Wood, David A. (15 October 2013). Handbook of Liquefied Natural Gas. Gulf Professional Publishing. ISBN 9780124046450.
  36. ^ "Methane: The other important greenhouse gas". Environmental Defense Fund. Retrieved 15 November 2017.