Bismuth (83Bi) has 41 known isotopes, ranging from 184Bi to 224Bi. Bismuth has no stable isotopes, but does have one very long-lived isotope; thus, the standard atomic weight can be given as 208.98040(1). Although bismuth-209 is now known to be radioactive, it has classically been considered to be a stable isotope because it has a half-life of approximately 2.01×1019 years, which is more than a billion times the age of the universe. Besides 209Bi, the most stable bismuth radioisotopes are 210mBi with a half-life of 3.04 million years, 208Bi with a half-life of 368,000 years and 207Bi, with a half-life of 32.9 years, none of which occurs in nature. All other isotopes have half-lives under 1 year, most under a day. Of naturally occurring radioisotopes, the most stable is radiogenic 210Bi with a half-life of 5.012 days. 210mBi is unusual for being a nuclear isomer with a half-life multiple orders of magnitude longer than that of the ground state.
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Standard atomic weight Ar°(Bi) | ||||||||||||||||||||||||||||||||||||||
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List of isotopes
edit
Nuclide [n 1] |
Historic name |
Z | N | Isotopic mass (Da)[4] [n 2][n 3] |
Half-life[1] [n 4] |
Decay mode[1] [n 5] |
Daughter isotope [n 6] |
Spin and parity[1] [n 7][n 8] |
Isotopic abundance | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy[n 8] | |||||||||||||||||||
184Bi[5] | 83 | 101 | 184.00135(13)# | 6.6(15) ms | α | 180Tl | 3+# | ||||||||||||
184mBi[n 9] | 150(100)# keV | 13(2) ms | α | 180Tl | 10−# | ||||||||||||||
185Bi[6] | 83 | 102 | 184.99760(9)# | 2.8+2.3 −1.0 μs |
p (92%) | 184Pb | (1/2+) | ||||||||||||
α (8%) | 181Tl | ||||||||||||||||||
185mBi | 70(50)# keV | 58(2) μs | IT | 185Bi | (7/2−, 9/2−) | ||||||||||||||
186Bi | 83 | 103 | 185.996623(18) | 14.8(7) ms | α (99.99%) | 182Tl | (3+) | ||||||||||||
β+ (?%) | 186Pb | ||||||||||||||||||
β+, SF (0.011%) | (various) | ||||||||||||||||||
186mBi[n 9] | 170(100)# keV | 9.8(4) ms | α (99.99%) | 182Tl | (10−) | ||||||||||||||
β+ (?%) | 186Pb | ||||||||||||||||||
β+, SF (0.011%) | (various) | ||||||||||||||||||
187Bi | 83 | 104 | 186.993147(11) | 37(2) ms | α | 183Tl | (9/2−) | ||||||||||||
187m1Bi | 108(8) keV | 370(20) μs | α | 183Tl | 1/2+ | ||||||||||||||
187m2Bi | 252(3) keV | 7(5) μs | IT | 187Bi | (13/2+) | ||||||||||||||
188Bi | 83 | 105 | 187.992276(12) | 60(3) ms | α | 184Tl | (3+) | ||||||||||||
β+, SF (0.0014%) | (various) | ||||||||||||||||||
188m1Bi | 66(30) keV | >5 μs | 7+# | ||||||||||||||||
188m2Bi | 153(30) keV | 265(15) ms | α | 184Tl | (10−) | ||||||||||||||
β+, SF (0.0046%) | (various) | ||||||||||||||||||
189Bi | 83 | 106 | 188.989195(22) | 688(5) ms | α | 185Tl | 9/2− | ||||||||||||
189m1Bi | 184(5) keV | 5.0(1) ms | α (83%) | 185Tl | 1/2+ | ||||||||||||||
IT (17%) | 189Bi | ||||||||||||||||||
189m2Bi | 357.6(5) keV | 880(50) ns | IT | 189Bi | 13/2+ | ||||||||||||||
190Bi | 83 | 107 | 189.988625(23) | 6.3(1) s | α (77%) | 186Tl | (3+) | ||||||||||||
β+ (23%) | 190Pb | ||||||||||||||||||
β+, SF (6×10-6%) | (various) | ||||||||||||||||||
190m1Bi | 120(40) keV | 6.2(1) s | α (70%) | 186Tl | 10− | ||||||||||||||
β+ (30%) | 190Pb | ||||||||||||||||||
β+, SF (4×10-6%) | (various) | ||||||||||||||||||
190m2Bi | 121(15) keV | 175(8) ns | IT | 190Bi | (5−) | ||||||||||||||
190m3Bi | 394(40) keV | 1.3(8) μs | IT | 190Bi | (8−) | ||||||||||||||
191Bi | 83 | 108 | 190.985787(8) | 12.4(3) s | α (51%) | 187Tl | 9/2− | ||||||||||||
β+ (49%) | 191Pb | ||||||||||||||||||
191m1Bi | 242(4) keV | 125(8) ms | α (68%) | 187Tl | 1/2+ | ||||||||||||||
IT (?%) | 191Bi | ||||||||||||||||||
β+ (?%) | 191Pb | ||||||||||||||||||
191m2Bi | 429.7(5) keV | 562(10) ns | IT | 191Bi | 13/2+ | ||||||||||||||
191m3Bi | 1875(25)# keV | 400(40) ns | IT | 191Bi | 25/2-# | ||||||||||||||
192Bi | 83 | 109 | 191.98547(3) | 34.6(9) s | β+ (88%) | 192Pb | (3+) | ||||||||||||
α (12%) | 188Tl | ||||||||||||||||||
192mBi | 140(30) keV | 39.6(4) s | β+ (90%) | 192Pb | 10− | ||||||||||||||
α (10%) | 188Tl | ||||||||||||||||||
193Bi | 83 | 110 | 192.982947(8) | 63.6(30) s | β+ (96.5%) | 193Pb | 9/2− | ||||||||||||
α (3.5%) | 189Tl | ||||||||||||||||||
193m1Bi | 305(6) keV | 3.20(14) s | α (84%) | 189Tl | 1/2+ | ||||||||||||||
β+ (16%) | 193Pb | ||||||||||||||||||
193m2Bi | 605.53(18) keV | 153(10) ns | IT | 193Bi | 13/2+ | ||||||||||||||
193m3Bi | 2349.6(6) keV | 85(3) μs | IT | 193Bi | 29/2+ | ||||||||||||||
193m4Bi | 2405.1(7) keV | 3.02(8) μs | IT | 193Bi | (29/2−) | ||||||||||||||
194Bi | 83 | 111 | 193.982799(6) | 95(3) s | β+ (99.54%) | 194Pb | 3+ | ||||||||||||
α (0.46%) | 190Tl | ||||||||||||||||||
194m1Bi | 150(50) keV | 125(2) s | β+ | 194Pb | (6+, 7+) | ||||||||||||||
194m2Bi | 163(4) keV | 115(4) s | β+ (99.80%) | 194Pb | (10−) | ||||||||||||||
α (0.20%) | 190Tl | ||||||||||||||||||
195Bi | 83 | 112 | 194.980649(6) | 183(4) s | β+ (99.97%) | 195Pb | 9/2− | ||||||||||||
α (0.030%) | 191Tl | ||||||||||||||||||
195m1Bi | 399(6) keV | 87(1) s | β+ (67%) | 195Pb | 1/2+ | ||||||||||||||
α (33%) | 191Tl | ||||||||||||||||||
195m2Bi | 2381.0(5) keV | 614(5) ns | IT | 195Bi | (29/2−) | ||||||||||||||
195m3Bi | 2615.9(5) keV | 1.49(1) μs | IT | 195Bi | 29/2+ | ||||||||||||||
196Bi | 83 | 113 | 195.980667(26) | 5.13(20) min | β+ | 196Pb | (3+) | ||||||||||||
α (0.00115%) | 192Tl | ||||||||||||||||||
196m1Bi | 166.4(29) keV | 0.6(5) s | IT | 196Bi | (7+) | ||||||||||||||
196m2Bi | 272(3) keV | 4.00(5) min | β+ (74.2%) | 196Pb | (10−) | ||||||||||||||
IT (25.8%) | 196Bi | ||||||||||||||||||
α (3.8×10−4%) | 196Bi | ||||||||||||||||||
197Bi | 83 | 114 | 196.978865(9) | 9.33(50) min | β+ | 197Pb | 9/2− | ||||||||||||
197m1Bi | 533(12) keV | 5.04(16) min | α (55%) | 193Tl | 1/2+ | ||||||||||||||
β+ (45%) | 197Pb | ||||||||||||||||||
197m2Bi | 2403(12) keV | 263(13) ns | IT | 197Bi | (29/2−) | ||||||||||||||
197m3Bi | 2929.5(5) keV | 209(30) ns | IT | 197Bi | (31/2−) | ||||||||||||||
198Bi | 83 | 115 | 197.979201(30) | 10.3(3) min | β+ | 198Pb | 3+ | ||||||||||||
198m1Bi | 290(40) keV | 11.6(3) min | β+ | 198Pb | 7+ | ||||||||||||||
198m2Bi | 540(40) keV | 7.7(5) s | IT | 198Bi | 10− | ||||||||||||||
199Bi | 83 | 116 | 198.977673(11) | 27(1) min | β+ | 199Pb | 9/2− | ||||||||||||
199m1Bi | 667(3) keV | 24.70(15) min | β+ (>98%) | 199Pb | (1/2+) | ||||||||||||||
IT (<2%) | 199Bi | ||||||||||||||||||
α (0.01%) | 195Tl | ||||||||||||||||||
199m2Bi | 1962(23) keV | 0.10(3) μs | IT | 199Bi | 25/2+# | ||||||||||||||
199m3Bi | 2548(23) keV | 168(13) ns | IT | 199Bi | 29/2−# | ||||||||||||||
200Bi | 83 | 117 | 199.978131(24) | 36.4(5) min | β+ | 200Pb | 7+ | ||||||||||||
200m1Bi[n 9] | 100(70)# keV | 31(2) min | β+ (?%) | 200Pb | (2+) | ||||||||||||||
IT (?%) | 200Bi | ||||||||||||||||||
200m2Bi | 428.20(10) keV | 400(50) ms | IT | 200Bi | (10−) | ||||||||||||||
201Bi | 83 | 118 | 200.976995(13) | 103(3) min | β+ | 201Pb | 9/2− | ||||||||||||
201m1Bi | 846.35(18) keV | 57.5(21) min | β+ | 201Pb | 1/2+ | ||||||||||||||
α (?%) | 197Tl | ||||||||||||||||||
201m2Bi | 1973(23) keV | 118(28) ns | IT | 201Bi | 25/2+# | ||||||||||||||
201m3Bi | 2012(23) keV | 105(75) ns | IT | 201Bi | 27/2+# | ||||||||||||||
201m4Bi | 2781(23) keV | 124(4) ns | IT | 201Bi | 29/2−# | ||||||||||||||
202Bi | 83 | 119 | 201.977723(15) | 1.72(5) h | β+ | 202Pb | 5+ | ||||||||||||
α (<10−5%) | 198Tl | ||||||||||||||||||
202m1Bi | 625(12) keV | 3.04(6) μs | IT | 202Bi | 10−# | ||||||||||||||
202m2Bi | 2617(12) keV | 310(50) ns | IT | 202Bi | (17+) | ||||||||||||||
203Bi | 83 | 120 | 202.976892(14) | 11.76(5) h | β+ | 203Pb | 9/2− | ||||||||||||
203m1Bi | 1098.21(9) keV | 305(5) ms | IT | 203Bi | 1/2+ | ||||||||||||||
203m2Bi | 2041.5(6) keV | 194(30) ns | IT | 203Bi | 25/2+ | ||||||||||||||
204Bi | 83 | 121 | 203.977836(10) | 11.22(10) h | β+ | 204Pb | 6+ | ||||||||||||
204m1Bi | 805.5(3) keV | 13.0(1) ms | IT | 204Bi | 10− | ||||||||||||||
204m2Bi | 2833.4(11) keV | 1.07(3) ms | IT | 204Bi | 17+ | ||||||||||||||
205Bi | 83 | 122 | 204.977385(5) | 14.91(7) d | β+ | 205Pb | 9/2− | ||||||||||||
205m1Bi | 1497.17(9) keV | 7.9(7) μs | IT | 205Bi | 1/2+ | ||||||||||||||
205m2Bi | 2064.7(4) keV | 100(6) ns | IT | 205Bi | 21/2+ | ||||||||||||||
205m3Bi | 2139.0(7) keV | 220(25) ns | IT | 205Bi | 25/2+ | ||||||||||||||
206Bi | 83 | 123 | 205.978499(8) | 6.243(3) d | β+ | 206Pb | 6+ | ||||||||||||
206m1Bi | 59.897(17) keV | 7.7(2) μs | IT | 206Bi | 4+ | ||||||||||||||
206m2Bi | 1044.8(7) keV | 890(10) μs | IT | 206Bi | 10− | ||||||||||||||
206m3Bi | 9233.3(8) keV | 155(15) ns | IT | 206Bi | (28−) | ||||||||||||||
206m4Bi | 10170.5(8) keV | >2 μs | IT | 206Bi | (31+) | ||||||||||||||
207Bi | 83 | 124 | 206.9784706(26) | 31.22(17) y | β+ | 207Pb | 9/2− | ||||||||||||
207mBi | 2101.61(16) keV | 182(6) μs | IT | 207Bi | 21/2+ | ||||||||||||||
208Bi | 83 | 125 | 207.9797421(25) | 3.68(4)×105 y | β+ | 208Pb | 5+ | ||||||||||||
208mBi | 1571.1(4) keV | 2.58(4) ms | IT | 208Bi | 10− | ||||||||||||||
209Bi [n 10][n 11] |
83 | 126 | 208.9803986(15) | 2.01(8)×1019 y [n 12] |
α | 205Tl | 9/2− | 1.0000 | |||||||||||
210Bi | Radium E | 83 | 127 | 209.9841202(15) | 5.012(5) d | β− | 210Po | 1− | Trace[n 13] | ||||||||||
α (1.32×10−4%) | 206Tl | ||||||||||||||||||
210mBi | 271.31(11) keV | 3.04(6)×106 y | α | 206Tl | 9− | ||||||||||||||
211Bi | Actinium C | 83 | 128 | 210.987269(6) | 2.14(2) min | α (99.72%) | 207Tl | 9/2− | Trace[n 14] | ||||||||||
β− (0.276%) | 211Po | ||||||||||||||||||
211mBi | 1257(10) keV | 1.4(3) μs | IT | 211Bi | (25/2−) | ||||||||||||||
212Bi | Thorium C | 83 | 129 | 211.991285(2) | 60.55(6) min | β− (64.05%) | 212Po | 1− | Trace[n 15] | ||||||||||
α (35.94%) | 208Tl | ||||||||||||||||||
β−, α (0.014%) | 208Pb | ||||||||||||||||||
212m1Bi | 250(30) keV | 25.0(2) min | α (67%) | 208Tl | (8−, 9−) | ||||||||||||||
β−, α (30%) | 208Pb | ||||||||||||||||||
β− (3%) | 212Po | ||||||||||||||||||
212m2Bi | 1479(30) keV | 7.0(3) min | β− | 212Po | (18−) | ||||||||||||||
213Bi [n 16][n 17] |
83 | 130 | 212.994384(5) | 45.60(4) min | β− (97.91%) | 213Po | 9/2− | Trace[n 18] | |||||||||||
α (2.09%) | 209Tl | ||||||||||||||||||
213mBi | 1353(21) keV | >168 s | 25/2−# | ||||||||||||||||
214Bi | Radium C | 83 | 131 | 213.998711(12) | 19.9(4) min | β− (99.98%) | 214Po | 1− | Trace[n 13] | ||||||||||
α (0.021%) | 210Tl | ||||||||||||||||||
β−, α (0.003%) | 210Pb | ||||||||||||||||||
214mBi | 539(30) keV | >93 s | 8−# | ||||||||||||||||
215Bi | 83 | 132 | 215.001749(6) | 7.62(13) min | β− | 215Po | (9/2−) | Trace[n 14] | |||||||||||
215mBi | 1367(20)# keV | 36.9(6) s | IT (76.9%) | 215Bi | (25/2−) | ||||||||||||||
β− (23.1%) | 215Po | ||||||||||||||||||
216Bi | 83 | 133 | 216.006306(12) | 2.21(4) min | β− | 216Po | (6−, 7−) | ||||||||||||
216mBi[n 9] | 24(19) keV | 6.6(21) min | β− | 216Po | 3−# | ||||||||||||||
217Bi | 83 | 134 | 217.009372(19) | 98.5(13) s | β− | 217Po | 9/2−# | ||||||||||||
217mBi | 1491(20) keV | 3.0(2) μs | IT | 217Bi | 25/2−# | ||||||||||||||
218Bi | 83 | 135 | 218.014188(29) | 33(1) s | β− | 218Po | 8−# | ||||||||||||
219Bi | 83 | 136 | 219.01752(22)# | 8.7(29) s | β− | 219Po | 9/2−# | ||||||||||||
220Bi | 83 | 137 | 220.02250(32)# | 9.5(57) s | β− | 220Po | 1−# | ||||||||||||
221Bi | 83 | 138 | 221.02598(32)# | 2# s [>300 ns] |
9/2−# | ||||||||||||||
222Bi | 83 | 139 | 222.03108(32)# | 3# s [>300 ns] |
1−# | ||||||||||||||
223Bi | 83 | 140 | 223.03461(43)# | 1# s [>300 ns] |
9/2−# | ||||||||||||||
224Bi | 83 | 141 | 224.03980(43)# | 1# s [>300 ns] |
1−# | ||||||||||||||
This table header & footer: |
- ^ mBi – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ Bold half-life – nearly stable, half-life longer than age of universe.
- ^
Modes of decay:
EC: Electron capture IT: Isomeric transition
p: Proton emission - ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ a b # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^ a b c d Order of ground state and isomer is uncertain.
- ^ Formerly believed to be final decay product of 4n+1 decay chain
- ^ Primordial radioisotope, also some is radiogenic from the extinct nuclide 237Np
- ^ Formerly believed to be the heaviest stable nuclide
- ^ a b Intermediate decay product of 238U
- ^ a b Intermediate decay product of 235U
- ^ Intermediate decay product of 232Th
- ^ Used in medicine such as for cancer treatment.
- ^ A byproduct of thorium reactors via 233U.
- ^ Intermediate decay product of 237Np
Bismuth-213
editBismuth-213 (213Bi) has a half-life of 45 minutes and decays via alpha emission. Commercially, bismuth-213 can be produced by bombarding radium with bremsstrahlung photons from a linear particle accelerator, which populates its progenitor actinium-225. In 1997, an antibody conjugate with 213Bi was used to treat patients with leukemia. This isotope has also been tried in targeted alpha therapy (TAT) program to treat a variety of cancers.[7] Bismuth-213 is also found in the decay chain of uranium-233, which is the fuel bred by thorium reactors.
References
edit- ^ a b c d Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ "Standard Atomic Weights: Bismuth". CIAAW. 2005.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
- ^ Andreyev, A. N.; Ackermann, D.; Heßberger, F. P.; Hofmann, S.; Huyse, M.; Kojouharov, I.; Kindler, B.; Lommel, B.; Münzenberg, G.; Page, R. D.; Vel, K. Van de; Duppen, P. Van; Heyde, K. (1 October 2003). "α-decay spectroscopy of light odd-odd Bi isotopes - II: 186Bi and the new nuclide 184Bi" (PDF). The European Physical Journal A. 18 (1): 55–64. Bibcode:2003EPJA...18...55A. doi:10.1140/epja/i2003-10051-1. ISSN 1434-601X. S2CID 122369569. Retrieved 20 June 2023.
- ^ Doherty, D. T.; Andreyev, A. N.; Seweryniak, D.; Woods, P. J.; Carpenter, M. P.; Auranen, K.; Ayangeakaa, A. D.; Back, B. B.; Bottoni, S.; Canete, L.; Cubiss, J. G.; Harker, J.; Haylett, T.; Huang, T.; Janssens, R. V. F.; Jenkins, D. G.; Kondev, F. G.; Lauritsen, T.; Lederer-Woods, C.; Li, J.; Müller-Gatermann, C.; Potterveld, D.; Reviol, W.; Savard, G.; Stolze, S.; Zhu, S. (12 November 2021). "Solving the Puzzles of the Decay of the Heaviest Known Proton-Emitting Nucleus 185Bi". Physical Review Letters. 127 (20): 202501. Bibcode:2021PhRvL.127t2501D. doi:10.1103/PhysRevLett.127.202501. hdl:20.500.11820/ac1e5604-7bba-4a25-a538-795ca4bdc875. ISSN 0031-9007. PMID 34860042. S2CID 244089059. Retrieved 20 June 2023.
- ^ Imam, S (2001). "Advancements in cancer therapy with alpha-emitters: a review". International Journal of Radiation Oncology, Biology, Physics. 51 (1): 271–278. doi:10.1016/S0360-3016(01)01585-1. PMID 11516878.
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
- "News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.