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User:Graeme Bartlett/selenite chloride

< User:Graeme Bartlett

A selenite chloride is a chemical compound or salt that contains chloride and selenite anions (Cl− and (SeO2-
3). These are mixed anion compounds. Some have third anions, including nitrate (NO−3), molybdate (MoO4), oxalate (C
2O2−
4), selenate (SeO2−
4), silicate (SiO2−
4) and tellurate (TeO2−
4).



Co(HSeO3)Cl·2H2O[1]

Co(HSeO3)Cl·3H2O and Cu(HSeO3)Cl·2H2O[2]

Cu(HSeO3)2MCl2(H2O)4, M(II)=Mn, Co, Ni, Cu, Zn[3]

(Cu(HSeO3)2)·((NH4)Cl)[4]

K[Cu3O](SeO3)2Cl and Na2[Cu7O2](SeO3)4Cl4[5]

ilinskite, Na[Cu5O2](SeO3)2Cl3[6]

Cu3Yb(SeO3)2O2Cl[7]

Co(H2O)2Cl2(H2SeO3)2[8]

BiOCl/SeO2[9]

LnSeO3Cl[10]

γ-BiSeO3Cl[11]

ErSeO3Cl[12]

Guangyuanite, Pb3Cl3(Se4+O3)(OH)[13]

Cs3La11(SeO3)12Cl12[14]

InSeO3Cl[15]

MNd10(SeO3)12Cl8 (M=Ca and Sr)[16]

NdClSeO3 and ErClSeO3[17]

Pb3(SeO3)(SeO2OH)Cl3 and Pb3(SeO3)2Cl2[18]

Pb2Pd(SeO3)2Cl2[19]

Cs7Nd11(SeO3)12Cl16[20]

Sr3(SeO3)(Se2O5)Cl2[21]

Rb2SeOCl4·H2O[22]

NaCu[23]

MBi(SeO3)2(H2O)Cl (M = Co, Ni, Cu)[24]

Pb2MCu(SeO3)4Cl(H2O) Fe Ga[25]

PbCd[26]

PbGa[27]

PHD https://www.researchgate.net/profile/Mishel-Markovski/publication/357402622_CRYSTAL-CHEMICAL_FEATURES_OF_NOVEL_COMPOUNDS_WITH_SELENITE_AND_TELLURITE_ANIONS/links/61cc6525b6b5667157b339b9/CRYSTAL-CHEMICAL-FEATURES-OF-NOVEL-COMPOUNDS-WITH-SELENITE-AND-TELLURITE-ANIONS.pdf

https://dspace.spbu.ru/bitstream/11701/42391/2/VKR.pdf

Mn[28]

Ca[29]

Co[30]

[31]

Naming

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A selenite chloride compound may also be called a chloride oxoselenate(IV) using IUPAC naming for inorganic compounds.

Production

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selenite chlorides can be produced by dissolving the rmetal selenate with hydrochloric acid. Often these have to be crystallised from acidic solution. Trifluoroacetic acid is used as a volatile acid, rather than just hydrochloric acid as that forms part of the crystal and varies through the evaporation process.

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Related to these are the selenite fluorides and selenite bromides by varying the halogenide. Similar compounds by varying the chalcogen also include the sulfite chlorides and tellurite chlorides.

List

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name formula ratio

SeO3:Cl

mw system space group unit cell Å volume density optical references
KCl•2H2SeO3 monoclinic P2/n a=6.2501 b=5.1716 c=12.038 β=103.612° 378.18 2.920 [32]
scandium selenite fluoride ScSeO3F 1:1 triclinic P1 <13 −173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=2
monoclinic P21/m >13 [33]
Li2(Se2O5)(H2O)1.5·CuCl2 monoclinic C2/c a=13.07 b=7.672 c=17.79 β=98.93° Z=24 1763 3.114 [34]
(NH4Cl)[Cu(HSeO3)2] orthorhombic Pnma a=9.001 b=12.132 c=7.281 795.1 [35]
(NaCl)[Cu(HSeO3)2] monoclinic C2/c a=13.929 b=7.242 c=9.014 β=127.260 724 Greenish-blue [36]
(NaCl)[Cu(HSeO3)2] monoclinic P2/c a=6.1754 b=5.3823 c=10.4442 β=100.342° Z=2 567.0 Greenish-blue [36]
(NaCl)[Cu(HSeO3)2] monoclinic P21/c a=11.1204 b=29.0105 c=9.0128 β=93.236° Z=16 2903.0 [36]
(KCl)[Cu(HSeO3)2] monoclinic P2/c a=6.301 b=5.808 c=10.514 β=101.080 377.6 [36][35]
Zn2(SeO3)Cl2 [37]
(RbCl)[Cu(HSeO3)2] orthorhombic Pnma a=9.0905 b=12.2864 c=7.2033 804.53 [36][35]
RbCl·(H2SeO3)2 2:1 triclinic P1 a=5.2240 b=6.3562 c=6.4079 α=72.940° β=89.697° γ=78.066° UV cut off 230 nm; birefringence 0.14 at 589 nm [38]
Rubidiumzincbis(hydrogenselenate(IV))chloride (RbCl)[Zn(HSeO3)2] monoclinic P12/c1 a=6.479 b=6.110 c=10.741 β=103.61° Z=2 413.3 white [36][39]
Cd4(SeO3)2Cl4(H2O) [37]
Cd4(SeO3)2OCl2 [37]
Cd5(SeO3)4Cl2(H2O) monoclinic P21 a=8.5930 b=17.760 c=10.5872 β=90.078° SHG 0.6×KD [37]
CdCu2(SeO3)2Cl2 monoclinic I2/a a ​= ​7.8057 b ​= ​9.6036 c ​= ​10.7817 β ​= ​102.362° Z ​= ​4 [40]
CsCl•H2SeO3 monoclinic P21/c a=7.9391 b=9.6574 c=7.8275 β=109.440° 565.93 3.490 [32]
(CsCl)[Cu(HSeO3)2] orthorhombic Pnma a=9.103 b=12.639 c=7.1621 843.7 [36][35]
Pb2TiOF(SeO3)2Cl [37]
CdPb8(SeO3)4Cl4Br6 Pnnn a=9.613 b=12.170 c=12.911 [41]
α-BiSeO3Cl orthorhombic P212121 a=6.353 b=7.978 c=8.651 Z=4 [42]
β-BiSeO3Cl monoclinic Cc a=22.7052 b=76.785 c=16.0550 β=135.000° Z=192 19792 5.470 colourless plates [43]
Bi6(SeO3)4Cl10 monoclinic P21/c a=21.460 b=8.4012 c=15.337 β=110.639° Z=4 2587.7 5.432 colourless needles [43]
BaBi(SeO3)2Cl orthorhombic Cmc21 a = 5.2804 b = 20.0535 c = 6.9070 Z = 4 731.39 SHG 16×KDP [44]
PbBi10(SeO3)12Cl8 orthorhombic Ccca a=15.819 b=17.871 c=15.857 Z=4 4483 6.079 colourless plates [43]
Pb2Bi(SeO3)2Cl3 2:3 monoclinic C2 a=13.2270 b=5.6002 c=7.7021, β=115.070° SHG 13.5×KDP; band gap 3.45 eV [45]

References

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  1. ^ Johnston, Magnus G.; Harrison, William T. A. (2003-04-15). "Cobalt hydrogen selenite chloride dihydrate, Co(HSeO 3 )Cl·2H 2 O". Acta Crystallographica Section e Structure Reports Online. 59 (4): i62–i64. Bibcode:2003AcCrE..59I..62J. doi:10.1107/S1600536803006378. ISSN 1600-5368.
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