User:Ccustodi/Grignard reaction/Bibliography

You will be compiling your bibliography and creating an outline of the changes you will make in this sandbox.

Bibliography

As you gather the sources for your Wikipedia contribution, think about the following:

Is the source from a reliable publication?
- Reliable publications include established newspapers, academic journals and books, textbooks, and other published sources with reputations for accuracy and fact-checking.
- Unreliable sources include blog posts and other self-published works, press releases, and social media posts.
Is the source verifiable?
- In order for a source to be considered verifiable, other editors should be able to consult the source.
Is the source independent of the subject?
- Is the source connected in any way to the subject? This is especially important when writing biographies or about organizations.
- For example, if you were writing a biography, sources like the person's webpage or personal blog would not be considered independent.
Is the source primary or secondary?
- Primary sources include first-hand accounts, autobiographies, and other original content.
- Wikipedia allows limited use of primary sources, but typically only for straightforward, descriptive statements of facts, and only if they are published and verifiable without requiring specialized knowledge.
- Secondary sources should be the main basis for a biography on Wikipedia.
If you're working on a topic related to medicine or psychology, ensure that your sources follow these special guidelines.
If you're creating a new article, consider the following:
- Ensure that your topic meets Wikipedia's notability guidelines.
- In order for a topic to meet the notability requirement, you must be able to identify 2-3 sources that are reliable, verifiable, and independent of the subject you're writing about.
- Finding sufficient sources to establish notability can be especially hard when writing about people or organizations.
- Sources that are not independent of the subject might be useful additions, but don't count towards the notability requirement.
- Wikipedia has developed special guidelines for writing about living persons. Please follow these carefully.
- Wikipedia has a series of guidelines for writing about different categories of people, such as academics and artists. If you're trying to create a new entry about a living person, please look at these carefully.

If you're not sure whether a source is reliable, ask a librarian! If you have questions about Wikipedia's sourcing rules, you can use the Get Help button below to contact your Wikipedia Expert.

Get Help

Bibliography

Edit this section to compile the bibliography for your Wikipedia assignment. Add the name and/or notes about what each source covers, then use the "Cite" button to generate the citation for that source

^[1]
- This article outlines how different solvents affect the Grignard reaction.

^[2]
- This source covers how cerium (III) chloride affects the chemoselectivity of Grignard reactions.
^[3]
- This article discusses the benefits of the Knochel method to form Grignard reagents.

Examples:

Luke, Learie. 2007. Identity and secession in the Caribbean: Tobago versus Trinidad, 1889–1980 Kingston, Jamaica: University of the West Indies Press.
- This is a book published by a university press, so it should be a reliable source. It also covers the topic in some depth, so it's helpful in establishing notability.
Galeano, Gloria; Bernal, Rodrigo (2013-11-08). "Sabinaria , a new genus of palms (Cryosophileae, Coryphoideae, Arecaceae) from the Colombia-Panama border". Phytotaxa.
- This is a peer-reviewed scientific journal, so it should be a reliable source. It covers the topic in some depth, so it's helpful in establishing notability.
Baker, William J.; Dransfield, John (2016). "Beyond Genera Palmarum: progress and prospects in palm systematics". Botanical Journal of the Linnean Society.
- This is a peer-reviewed scientific journal, so it should be a reliable source for a specific fact. Since it only dedicates a few sentences to the topic, it can't be used to establish notability.

References

^ Kadam, Asha; Nguyen, Mylinh; Kopach, Michael; Richardson, Paul; Gallou, Fabrice; Wan, Zhao-Kui; Zhang, Wei (2013). "Comparative performance evaluation and systematic screening of solvents in a range of Grignard reactions". Green Chemistry. 15 (7): 1880–1888. doi:10.1039/C3GC40702K.
^ Imamoto, Tsuneo; Takiyama, Nobuyuki; Nakamura, Kimikazu (1985-01-01). "Cerium chloride-promoted nucleophilic addition of grignard reagents to ketones an efficient method for the synthesis of tertiary alcohols". Tetrahedron Letters. 26 (39): 4763–4766. doi:10.1016/S0040-4039(00)94945-1. ISSN 0040-4039.
^ Ziegler, Dorothée S.; Wei, Baosheng; Knochel, Paul (2019-02-21). "Improving the Halogen–Magnesium Exchange by using New Turbo‐Grignard Reagents". Chemistry – A European Journal. 25 (11): 2695–2703. doi:10.1002/chem.201803904. ISSN 0947-6539.

Outline of proposed changes

Click on the edit button to draft your outline.

Source 1 listed above discusses how different solvents affect the Grignard reaction, and in some cases, can improve the chemoselectivity of the Grignard reaction. This will contribute to our discussion of reagents which increase the chemoselectivity of the Grignard reaction.

Source 2 listed above discusses the affect of cerium chloride on the chemoselectivity of the Grignard reaction. This article will contribute to our discussion on how cerium based reagents contribute to the Grignard reaction's chemoselectivity.

Source 3 listed above elaborates on the function of the Knochel Grignard. This will be a valuable source for our discussion on the Knochel Grignard in the section on chemoselectivity we will be adding.

We plan on improving our selected article by adding:

How using Lewis Acids (e.g. Cerium) can influence where a Grignard reagent will react when multiple positions are possible.
How Grignards and other organometallics need to be in anhydrous conditions with no acidic protons to avoid self-quenching.
Knochel Grignards, and chemoselective formation of Grignards.

Additionally, we will be making the following changes:

We have already been using Brogan methods to make the existing article more concise and technical.
We have also been adding citations for uncited assertions within the article.
The article seems to be structured well, but more subtopics can be added based on the three topics listed in Question 3.
- Anhydrous conditions
- Subtopic on chemoselectivity
The article has an adequate number of images, but more specific examples or images can be added for the subtopics we will add. These images could help to explain the mechanism and uses of the additional chemoselective reagents to the Grignard reaction or the anhydrous conditions used for grignard reactions.

Now that you have compiled a bibliography, it's time to plan out how you'll improve your assigned article.

In this section, write up a concise outline of how the sources you've identified will add relevant information to your chosen article. Be sure to discuss what content gap your additions tackle and how these additions will improve the article's quality.

Consider other changes you'll make to the article, including possible deletions of irrelevant, outdated, or incorrect information, restructuring of the article to improve its readability or any other change you plan on making. This is your chance to really think about how your proposed additions will improve your chosen article and to vet your sources even further.

Note: This is not a draft. This is an outline/plan where you can think about how the sources you've identified will fill in a content gap.

Get Help

[1] Kadam, Asha; Nguyen, Mylinh; Kopach, Michael; Richardson, Paul; Gallou, Fabrice; Wan, Zhao-Kui; Zhang, Wei (2013). "Comparative performance evaluation and systematic screening of solvents in a range of Grignard reactions". Green Chemistry. 15 (7): 1880–1888. doi:10.1039/C3GC40702K.

[2] Imamoto, Tsuneo; Takiyama, Nobuyuki; Nakamura, Kimikazu (1985-01-01). "Cerium chloride-promoted nucleophilic addition of grignard reagents to ketones an efficient method for the synthesis of tertiary alcohols". Tetrahedron Letters. 26 (39): 4763–4766. doi:10.1016/S0040-4039(00)94945-1. ISSN 0040-4039.

[3] Ziegler, Dorothée S.; Wei, Baosheng; Knochel, Paul (2019-02-21). "Improving the Halogen–Magnesium Exchange by using New Turbo‐Grignard Reagents". Chemistry – A European Journal. 25 (11): 2695–2703. doi:10.1002/chem.201803904. ISSN 0947-6539.

[1]

[2]

[3]