Tin(IV) iodate is an inorganic compound with the chemical formula Sn(IO3)4. It was first obtained in 2020 through the hydrothermal reaction of tin(II) oxide and iodic acid in water at 220 °C. [1] It is a colorless columnar crystal, crystallized in the triclinic P1 space group.[1] It has an indirect band gap (experimental 4.0 eV; calculated 2.75 eV).[2]
| Identifiers | |
|---|---|
| Properties | |
| Sn(IO3)4 | |
| Molar mass | 818.29 |
| Appearance | colourless columnal crystals |
| Density | 5.107 g·cm-3（23 °C）[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References edit
- ^ a b Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.
- ^ Liang, Akun; Rodriguez-Hernandez, Placida; Muñoz, Alfonso; Rahman, Saqib; Segura, Alfredo; Errandonea, Daniel (2021). "Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons". Inorganic Chemistry Frontiers. 8 (22): 4780–4790. doi:10.1039/D1QI00870F. ISSN 2052-1553.
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