Naturally occurring terbium (65Tb) is composed of one stable isotope, 159Tb. Thirty-seven radioisotopes have been characterized, with the most stable being 158Tb with a half-life of 180 years, 157Tb with a half-life of 71 years, and 160Tb with a half-life of 72.3 days. All of the remaining radioactive isotopes have half-lives that are less than 6.907 days, and the majority of these have half-lives that are less than 24 seconds. This element also has 27 meta states, with the most stable being 156m1Tb (t1/2 = 24.4 hours), 154m2Tb (t1/2 = 22.7 hours) and 154m1Tb (t1/2 = 9.4 hours).
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Standard atomic weight Ar°(Tb) | ||||||||||||||||||||||||||||
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The primary decay mode before the most abundant stable isotope, 159Tb, is electron capture, and the primary mode behind is beta decay. The primary decay products before 159Tb are element Gd (gadolinium) isotopes, and the primary products after 159Tb are element Dy (dysprosium) isotopes.
List of isotopes
edit
Nuclide [n 1] |
Z | N | Isotopic mass (Da)[4] [n 2][n 3] |
Half-life[1] [n 4] |
Decay mode[1] [n 5] |
Daughter isotope [n 6][n 7] |
Spin and parity[1] [n 8][n 4] |
Isotopic abundance | |||||||||||
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Excitation energy[n 4] | |||||||||||||||||||
135Tb | 65 | 70 | 134.96452(43)# | 1.01(28) ms | p | 134Gd | (7/2−) | ||||||||||||
139Tb | 65 | 74 | 138.94833(32)# | 1.6(2) s | β+ | 139Gd | 5/2−# | ||||||||||||
140Tb | 65 | 75 | 139.94581(86) | 2.29(15) s | β+ (99.74%) | 140Gd | (7+) | ||||||||||||
EC (<3%) | 140Gd | ||||||||||||||||||
β+, p (0.26%) | 139Eu | ||||||||||||||||||
141Tb | 65 | 76 | 140.94145(11) | 3.5(2) s | β+ | 141Gd | (5/2−) | ||||||||||||
141mTb[n 9][n 10] | 0(200)# keV | 7.9(6) s | β+ | 141Gd | 11/2−# | ||||||||||||||
142Tb | 65 | 77 | 141.93928(75) | 597(17) ms | β+ (96.8%) | 142Gd | 1+ | ||||||||||||
EC (3.2%) | 142Gd | ||||||||||||||||||
β+, p (0.0022%) | 141Eu | ||||||||||||||||||
142m1Tb | 279.7(4) keV | 303(17) ms | IT | 142Tb | 5− | ||||||||||||||
142m2Tb | 652.1(6) keV | 26(1) μs | IT | 142Tb | 8+ | ||||||||||||||
143Tb | 65 | 78 | 142.935137(55) | 12(1) s | β+ | 143Gd | (11/2−) | ||||||||||||
143mTb[n 9] | 0(100)# keV | 17(4) s | 5/2+# | ||||||||||||||||
144Tb | 65 | 79 | 143.933045(30) | ~1 s | β+ | 144Gd | 1+ | ||||||||||||
144m1Tb | 396.9(5) keV | 4.25(15) s | IT (66%) | 144Tb | 6− | ||||||||||||||
β+ (34%) | 144Gd | ||||||||||||||||||
144m2Tb | 476.2(5) keV | 2.8(3) μs | IT | 144Tb | (8−) | ||||||||||||||
144m3Tb | 517.1(5) keV | 670(60) ns | IT | 144Tb | (9+) | ||||||||||||||
144m4Tb | 544.5(6) keV | <300 ns | IT | 144Tb | (10+) | ||||||||||||||
145Tb | 65 | 80 | 144.92872(12) | 30.9(6) s | β+ | 145Gd | (11/2−) | ||||||||||||
145mTb[n 9] | 860(230) keV | (3/2+) | |||||||||||||||||
146Tb | 65 | 81 | 145.927253(48) | 8(4) s | β+ | 146Gd | 1+ | ||||||||||||
146m1Tb[n 9] | 150(100)# keV | 24.1(5) s | β+ | 146Gd | 5− | ||||||||||||||
146m2Tb | 930(100)# keV | 1.18(2) ms | IT | 146Tb | 10+ | ||||||||||||||
147Tb | 65 | 82 | 146.9240546(87) | 1.64(3) h | β+ | 147Gd | (1/2+) | ||||||||||||
147mTb | 50.6(9) keV | 1.87(5) min | β+ | 147Gd | (11/2−) | ||||||||||||||
148Tb | 65 | 83 | 147.924275(13) | 60(1) min | β+ | 148Gd | 2− | ||||||||||||
148m1Tb | 90.1(3) keV | 2.20(5) min | β+ | 148Gd | (9)+ | ||||||||||||||
148m2Tb | 8618.6(10) keV | 1.310(7) μs | IT | 148Tb | (27+) | ||||||||||||||
149Tb | 65 | 84 | 148.9232538(39) | 4.118(25) h | β+ (83.3%) | 149Gd | 1/2+ | ||||||||||||
α (16.7%) | 145Eu | ||||||||||||||||||
149mTb | 35.78(13) keV | 4.16(4) min | β+ (99.98%) | 149Gd | 11/2− | ||||||||||||||
α (0.022%) | 145Eu | ||||||||||||||||||
150Tb | 65 | 85 | 149.9236648(79) | 3.48(16) h | β+ | 150Gd | (2)− | ||||||||||||
150mTb | 461(27) keV | 5.8(2) min | β+ | 150Gd | 9+ | ||||||||||||||
151Tb | 65 | 86 | 150.9231090(44) | 17.609(1) h | β+ (99.99%) | 151Gd | 1/2+ | ||||||||||||
α (.0095%) | 147Eu | ||||||||||||||||||
151mTb | 99.53(5) keV | 25(3) s | IT (93.4%) | 151Tb | 11/2− | ||||||||||||||
β+ (6.6%) | 151Gd | ||||||||||||||||||
152Tb | 65 | 87 | 151.924082(43) | 17.8784(95) h[5] | EC (83%)[5] | 152Gd | 2− | ||||||||||||
β+ (17%)[5] | |||||||||||||||||||
152m1Tb | 342.15(16) keV | 960(10) ns | IT | 152Tb | 5− | ||||||||||||||
152m2Tb | 501.74(19) keV | 4.2(1) min | IT (78.9%) | 152Tb | 8+ | ||||||||||||||
β+ (21.1%) | 152Gd | ||||||||||||||||||
153Tb | 65 | 88 | 152.9234417(42) | 2.34(1) d | β+ | 153Gd | 5/2+ | ||||||||||||
153mTb | 163.175(5) keV | 186(4) μs | IT | 153Tb | 11/2− | ||||||||||||||
154Tb | 65 | 89 | 153.924684(49) | 9.994(39) h | β+ | 154Gd | 3− | ||||||||||||
154m1Tb[n 9] | 130(50)# keV | 21.5(4) h | β+ | 154Gd | 0− | ||||||||||||||
154m2Tb[n 9] | 200(150)# keV | 22.7(5) h | β+ | 154Gd | 7− | ||||||||||||||
154m3Tb | 405(150)# keV | 513(42) ns | IT | 154Tb | |||||||||||||||
155Tb | 65 | 90 | 154.923510(11) | 5.32(6) d | EC | 155Gd | 3/2+ | ||||||||||||
156Tb | 65 | 91 | 155.9247542(40) | 5.35(10) d | β+ | 156Gd | 3− | ||||||||||||
156m1Tb | 88.4(2) keV | 5.3(2) h | IT | 156Tb | (0+) | ||||||||||||||
156m2Tb | 100(50)# keV | 24.4(10) h | IT | 156Tb | (7−) | ||||||||||||||
157Tb | 65 | 92 | 156.9240319(11) | 71(7) y | EC | 157Gd | 3/2+ | ||||||||||||
158Tb | 65 | 93 | 157.9254199(14) | 180(11) y | β+ (83.4%) | 158Gd | 3− | ||||||||||||
β− (16.6%) | 158Dy | ||||||||||||||||||
158m1Tb | 110.3(12) keV | 10.70(17) s | IT | 158Tb | 0− | ||||||||||||||
158m2Tb | 388.39(11) keV | 0.40(4) ms | IT | 158Tb | 7− | ||||||||||||||
159Tb[n 11] | 65 | 94 | 158.9253537(12) | Stable | 3/2+ | 1.0000 | |||||||||||||
160Tb | 65 | 95 | 159.9271746(12) | 72.3(2) d | β− | 160Dy | 3− | ||||||||||||
161Tb[n 11] | 65 | 96 | 160.9275768(13) | 6.948(5) d | β− | 161Dy | 3/2+ | ||||||||||||
162Tb | 65 | 97 | 161.9292754(22) | 7.60(15) min | β− | 162Dy | (1−) | ||||||||||||
162mTb | 286(3) keV | 10# min | 4−# | ||||||||||||||||
163Tb | 65 | 98 | 162.9306536(44) | 19.5(3) min | β− | 163Dy | 3/2+ | ||||||||||||
164Tb | 65 | 99 | 163.9333276(20) | 3.0(1) min | β− | 164Dy | (5+) | ||||||||||||
164mTb | 145(12) keV | 2# min | 2+# | ||||||||||||||||
165Tb | 65 | 100 | 164.9349552(17) | 2.11(10) min | β− | 165Dy | (3/2+) | ||||||||||||
165mTb | 207(5) keV | 0.81(8) μs | IT | 165Tb | (7/2−) | ||||||||||||||
166Tb | 65 | 101 | 165.9379397(16) | 27.1(15) s | β− | 166Dy | (1−) | ||||||||||||
166mTb | 159.0(15) keV | 3.5(4) μs | IT | 166Tb | 4−# | ||||||||||||||
167Tb | 65 | 102 | 166.9400070(21) | 18.9(16) s | β− | 167Dy | (3/2+) | ||||||||||||
167mTb | 200(6) keV | 1.2(1) μs | IT | 167Tb | (7/2−) | ||||||||||||||
168Tb | 65 | 103 | 167.9433371(45) | 9.4(4) s | β− | 168Dy | (4−) | ||||||||||||
168mTb | 211(1) keV | 0.71(3) μs | IT | 168Tb | (6+) | ||||||||||||||
169Tb | 65 | 104 | 168.94581(32)# | 5.13(32) s | β− | 169Dy | 3/2+# | ||||||||||||
170Tb | 65 | 105 | 169.94986(32)# | 960(78) ms | β− | 170Dy | 2−# | ||||||||||||
171Tb | 65 | 106 | 170.95301(43)# | 1.23(10) s | β− | 171Dy | 3/2+# | ||||||||||||
172Tb | 65 | 107 | 171.95739(54)# | 760(190) ms | β− | 172Dy | 6+# | ||||||||||||
173Tb | 65 | 108 | 172.96081(54)# | 400# ms [>550 ns] |
3/2+# | ||||||||||||||
174Tb | 65 | 109 | 173.96568(54)# | 240# ms [>550 ns] |
2−# | ||||||||||||||
This table header & footer: |
- ^ mTb – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ a b c # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^
Modes of decay:
EC: Electron capture IT: Isomeric transition
p: Proton emission - ^ Bold italics symbol as daughter – Daughter product is nearly stable.
- ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ a b c d e f Order of ground state and isomer is uncertain.
- ^ Discovery of this isotope is disputed.
- ^ a b Fission product
References
edit- ^ a b c d Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ "Standard Atomic Weights: Terbium". CIAAW. 2021.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
- ^ a b c Collins, S.M.; Köster, U.; Robinson, A.P.; Ivanov, P.; Cocolios, T.E.; Russell, B.; Fenwick, A.J.; Bernerd, C.; Stegemann, S.; Johnston, K.; Gerami, A.M.; Chrysalidis, K.; Mohamud, H.; Ramirez, N.; Bhaisare, A.; Mewburn-Crook, J.; Cullen, D.M.; Pietras, B.; Pells, S.; Dockx, K.; Stucki, N.; Regan, P.H. (2023). "Determination of the Terbium-152 half-life from mass-separated samples from CERN-ISOLDE and assessment of the radionuclide purity". Applied Radiation and Isotopes. 202. Elsevier BV: 111044. doi:10.1016/j.apradiso.2023.111044. ISSN 0969-8043. PMID 37797447.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
- "News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.