Talk:Corey–Winter olefin synthesis

Latest comment: 1 year ago by Kgandrews in topic Alternative mechanism diagram

Mechanism diagram

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The diagram in the mechanism section, File:Corey-Winter_olefination_mechanism_v1.svg, looks wrong to me. After the departure of the neutral molecule SP(OMe)3, a carbene should remain, but a carbanion is shown. The text above mentions a carbene. If a carbanion is actually formed, it must have a counter cation somewhere. --Ben (talk) 16:59, 29 June 2012 (UTC)Reply

Alternative mechanism diagram

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The second mechanism is also incorrectly depicted - the arrow from the carbanion to the phosphorus should be reversed, with the lone pair ":" on the phosphorus. Kgandrews (talk) 06:39, 13 June 2023 (UTC)Reply