# Scattering amplitude

In quantum physics, the scattering amplitude is the probability amplitude of the outgoing spherical wave relative to the incoming plane wave in a stationary-state scattering process.

The latter is described by the wavefunction

$\psi (\mathbf {r} )=e^{ikz}+f(\theta ){\frac {e^{ikr}}{r}}\;,$ where $\mathbf {r} \equiv (x,y,z)$ is the position vector; $r\equiv |\mathbf {r} |$ ; $e^{ikz}$ is the incoming plane wave with the wavenumber k along the z axis; $e^{ikr}/r$ is the outgoing spherical wave; θ is the scattering angle; and $f(\theta )$ is the scattering amplitude. The dimension of the scattering amplitude is length.

The scattering amplitude is a probability amplitude; the differential cross-section as a function of scattering angle is given as its modulus squared,

${\frac {d\sigma }{d\Omega }}=|f(\theta )|^{2}\;.$ ## Partial wave expansion

In the partial wave expansion the scattering amplitude is represented as a sum over the partial waves,

$f=\sum _{\ell =0}^{\infty }(2\ell +1)f_{\ell }P_{\ell }(\cos \theta )$ ,

where f is the partial scattering amplitude and P are the Legendre polynomials.

The partial amplitude can be expressed via the partial wave S-matrix element S ($=e^{2i\delta _{\ell }}$ ) and the scattering phase shift δ as

$f_{\ell }={\frac {S_{\ell }-1}{2ik}}={\frac {e^{2i\delta _{\ell }}-1}{2ik}}={\frac {e^{i\delta _{\ell }}\sin \delta _{\ell }}{k}}={\frac {1}{k\cot \delta _{\ell }-ik}}\;.$

Then the differential cross section is given by

${\frac {d\sigma }{d\Omega }}=|f(\theta )|^{2}={\frac {1}{k^{2}}}\left|\sum _{\ell =0}^{\infty }(2\ell +1)e^{i\delta _{\ell }}\sin \delta _{\ell }P_{\ell }(\cos \theta )\right|^{2}$ ,

and the total elastic cross section becomes

$\sigma =2\pi \int _{0}^{\pi }{\frac {d\sigma }{d\Omega }}\sin \theta \,d\theta ={\frac {4\pi }{k}}\operatorname {Im} f(0)$ ,

where Im f(0) is the imaginary part of f(0).

## X-rays

The scattering length for X-rays is the Thomson scattering length or classical electron radius, r0.

## Neutrons

The nuclear neutron scattering process involves the coherent neutron scattering length, often described by b.

## Quantum mechanical formalism

A quantum mechanical approach is given by the S matrix formalism.

## Measurement

The scattering amplitude can be determined by the scattering length in the low-energy regime.