Pympe was the son an heir of Sir William Pympe, MP, who died in 1375, when Reynold was around four years old.
His wife, whose first name was unrecorded, was the daughter of Sir Ralph Freningham of Farningham and West Barming, Kent. She was the sister of the MP, John Freningham. They had two sons, the eldest of whom predeceased him, leaving a child. Pympe was succeeded by the young grandchild, who also died young, and so the Pympe's Court and Nettlestead estates passed to Pympe's younger brother John.
- "PYMPE, Reynold (c.1371-1426), of Nettlestead and Pympe's Court in East Farleigh, Kent". History of Parliament online. Retrieved 18 June 2013.
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