Indium (49In) consists of two primordial nuclides, with the most common (~ 95.7%) nuclide (115In) being measurably though weakly radioactive. Its spin-forbidden decay has a half-life of 4.41×1014 years, much longer than the currently accepted age of the Universe.
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Standard atomic weight Ar°(In) | ||||||||||||||||||||||||||
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The stable isotope 113In is only 4.3% of naturally occurring indium. Among elements with a known stable isotope, only tellurium and rhenium similarly occur with a stable isotope in lower abundance than the long-lived radioactive isotope. Other than 115In, the longest-lived radioisotope is 111In, with a half-life of 2.8047 days. All other radioisotopes have half-lives less than a day. This element also has 47 isomers, the longest-lived being 114m1In, with a half-life of 49.51 days. All other meta-states have half-lives less than a day, most less than an hour, and many measured in milliseconds or less.
Indium-111 is used medically in nuclear imaging, as a radiotracer nuclide tag for gamma camera localization of protein radiopharmaceuticals, such as In-111-labeled octreotide, which binds to receptors on certain endocrine tumors (Octreoscan).[4] Indium-111 is also used in indium white blood cell scans, which use nuclear medical techniques to search for hidden infections.
Several proton-rich isotopes of indium (including indium-99) have been used to measure the mass of the doubly-magic isotope tin-100.[5][6]
List of isotopes
edit
Nuclide [n 1] |
Z | N | Isotopic mass (Da) [n 2][n 3] |
Half-life [n 4] |
Decay mode [n 5] |
Daughter isotope [n 6][n 7] |
Spin and parity [n 8][n 4] |
Natural abundance (mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy[n 4] | Normal proportion | Range of variation | |||||||||||||||||
96In | 49 | 47 | 95.95911(54)# | 1# ms [>400 ns] |
β+? | 96Cd | 9/2+# | ||||||||||||
p? | 95Cd | ||||||||||||||||||
97In | 49 | 48 | 96.94913(43)# | 36(6) ms | β+ (97.7%) | 97Cd | 9/2+# | ||||||||||||
β+, p (2.3%) | 96Ag | ||||||||||||||||||
p? | 96Cd | ||||||||||||||||||
97mIn | 400(100)# keV | 0.12(7) ms | p? | 96Cd | 1/2−# | ||||||||||||||
98In | 49 | 49 | 97.94213(33)# | 30(1) ms | β+ (>99.87%) | 98Cd | (0+) | ||||||||||||
β+, p (<0.13%) | 97Ag | ||||||||||||||||||
98mIn[n 9] | 820(730) keV | 890(20) ms | β+ (56%) | 98Cd | (9+) | ||||||||||||||
β+, p (44%) | 97Ag | ||||||||||||||||||
99In | 49 | 50 | 98.93411(32)# | 3.11(6) s | β+ (99.71%) | 99Cd | 9/2+# | ||||||||||||
β+, p (0.29%) | 98Ag | ||||||||||||||||||
100In | 49 | 51 | 99.9311019(24) | 5.62(6) s | β+ (98.34%) | 100Cd | 6+# | ||||||||||||
β+, p (1.66%) | 99Ag | ||||||||||||||||||
101In | 49 | 52 | 100.926414(13) | 15.1(11) s | β+ (>98.3%) | 101Cd | (9/2+) | ||||||||||||
β+, p (<1.7%) | 100Ag | ||||||||||||||||||
101mIn | 640(40) keV | 10# s | β+? | 101Cd | 1/2−# | ||||||||||||||
IT? | 101In | ||||||||||||||||||
102In | 49 | 53 | 101.9241059(49) | 23.3(1) s | β+ (99.99%) | 102Cd | (6+) | ||||||||||||
β+, p (0.0093%) | 101Ag | ||||||||||||||||||
103In | 49 | 54 | 102.9198788(96) | 60(1) s | β+ | 103Cd | (9/2+) | ||||||||||||
103mIn | 631.7(1) keV | 34(2) s | β+ (67%) | 103Cd | (1/2−) | ||||||||||||||
IT (33%) | 103In | ||||||||||||||||||
104In | 49 | 55 | 103.9182145(62) | 1.80(3) min | β+ | 104Cd | (5+) | ||||||||||||
104mIn | 93.48(10) keV | 15.7(5) s | IT (80%) | 104In | (3+) | ||||||||||||||
β+ (20%) | 104Cd | ||||||||||||||||||
105In | 49 | 56 | 104.914502(11) | 5.07(7) min | β+ | 105Cd | 9/2+ | ||||||||||||
105mIn | 674.09(25) keV | 48(6) s | IT | 105In | (1/2)− | ||||||||||||||
β+? | 105Cd | ||||||||||||||||||
106In | 49 | 57 | 105.9134636(13) | 6.2(1) min | β+ | 106Cd | 7+ | ||||||||||||
106mIn | 28.6(3) keV | 5.2(1) min | β+ | 106Cd | (2)+ | ||||||||||||||
107In | 49 | 58 | 106.910287(10) | 32.4(3) min | β+ | 107Cd | 9/2+ | ||||||||||||
107mIn | 678.5(3) keV | 50.4(6) s | IT | 107In | 1/2− | ||||||||||||||
108In | 49 | 59 | 107.9096937(93) | 58.0(12) min | β+ | 108Cd | 7+ | ||||||||||||
108mIn | 29.75(5) keV | 39.6(7) min | β+ | 108Cd | 2+ | ||||||||||||||
109In | 49 | 60 | 108.9071497(43) | 4.159(10) h | β+ | 109Cd | 9/2+ | ||||||||||||
109m1In | 649.79(10) keV | 1.34(6) min | IT | 109In | 1/2− | ||||||||||||||
109m2In | 2101.86(11) keV | 210.0(9) ms | IT | 109In | 19/2+ | ||||||||||||||
110In | 49 | 61 | 109.907171(12) | 4.92(8) h | β+ | 110Cd | 7+ | ||||||||||||
110mIn | 62.08(4) keV | 69.1(5) min | β+ | 110Cd | 2+ | ||||||||||||||
111In[n 10] | 49 | 62 | 110.9051072(37) | 2.8048(1) d | EC | 111Cd | 9/2+ | ||||||||||||
111mIn | 536.99(7) keV | 7.7(2) min | IT | 111In | 1/2− | ||||||||||||||
112In | 49 | 63 | 111.9055387(46) | 14.88(15) min | β+ (62%) | 112Cd | 1+ | ||||||||||||
β− (38%) | 112Sn | ||||||||||||||||||
112m1In | 156.592(25) keV | 20.67(8) min | IT | 112In | 4+ | ||||||||||||||
112m2In | 350.80(5) keV | 690(50) ns | IT | 112In | (7)+ | ||||||||||||||
112m3In | 613.82(6) keV | 2.81(3) μs | IT | 112In | 8− | ||||||||||||||
113In[n 11] | 49 | 64 | 112.90406045(20) | Stable | 9/2+ | 0.04281(52) | |||||||||||||
113mIn | 391.699(3) keV | 1.6579(4) h | IT | 113In | 1/2− | ||||||||||||||
114In | 49 | 65 | 113.90491641(32) | 71.9(1) s | β− (99.50%) | 114Sn | 1+ | ||||||||||||
β+ (0.50%) | 114Cd | ||||||||||||||||||
114m1In | 190.2682(8) keV | 49.51(1) d | IT (96.75%) | 114In | 5+ | ||||||||||||||
β+ (3.25%) | 114Cd | ||||||||||||||||||
114m2In | 501.948(3) keV | 43.1(6) ms | IT (96.75%) | 114m1In | 8− | ||||||||||||||
β+ (3.25%) | 114Cd | ||||||||||||||||||
115In[n 11][n 12] | 49 | 66 | 114.903878772(12) | 4.41(25)×1014 a | β− | 115Sn | 9/2+ | 0.95.719(52) | |||||||||||
115mIn | 336.244(17) keV | 4.486(4) h | IT (95.0%) | 115In | 1/2− | ||||||||||||||
β− (5.0%) | 115Sn | ||||||||||||||||||
116In | 49 | 67 | 115.90525999(24) | 14.10(3) s | β− (99.98%) | 116Sn | 1+ | ||||||||||||
EC (0.0237%) | 116Cd | ||||||||||||||||||
116m1In | 127.267(6) keV | 54.29(17) min | β− | 116Sn | 5+ | ||||||||||||||
116m2In | 289.660(6) keV | 2.18(4) s | IT | 116m1In | 8− | ||||||||||||||
117In | 49 | 68 | 116.9045157(52) | 43.2(3) min | β− | 117Sn | 9/2+ | ||||||||||||
117mIn | 315.303(11) keV | 116.2(3) min | β− (52.9%) | 117Sn | 1/2− | ||||||||||||||
IT (47.1%) | 117In | ||||||||||||||||||
118In | 49 | 69 | 117.9063567(83) | 5.0(5) s | β− | 118Sn | 1+ | ||||||||||||
118m1In[n 9] | 100(50)# keV | 4.364(7) min | β− | 118Sn | 5+ | ||||||||||||||
118m2In | 240(50)# keV | 8.5(3) s | IT (98.6%) | 118m1In | 8− | ||||||||||||||
β− (1.4%) | 118Sn | ||||||||||||||||||
119In | 49 | 70 | 118.9058516(78) | 2.4(1) min | β− | 119Sn | 9/2+ | ||||||||||||
119m1In | 311.37(3) keV | 18.0(3) min | β− (97.4%) | 119Sn | 1/2− | ||||||||||||||
IT (2.6%) | 119In | ||||||||||||||||||
119m2In | 654.27(7) keV | 130(15) ns | IT | 119In | (3/2)+ | ||||||||||||||
119m3In | 2656.9(18) keV | 265(10) ns | IT | 119In | (25/2+) | ||||||||||||||
120In | 49 | 71 | 119.907967(43) | 3.08(8) s | β− | 120Sn | 1+ | ||||||||||||
120m1In[n 9] | 50(60)# keV | 46.2(8) s | β− | 120Sn | 5+ | ||||||||||||||
120m2In[n 9] | 300(200)# keV | 47.3(5) s | β− | 120Sn | 8− | ||||||||||||||
121In | 49 | 72 | 120.907853(29) | 23.1(6) s | β− | 121Sn | 9/2+ | ||||||||||||
121m1In | 313.68(7) keV | 3.88(10) min | β− (98.8%) | 121Sn | 1/2− | ||||||||||||||
IT (1.2%) | 121In | ||||||||||||||||||
121m2In | 2550(100)# keV | 7.3(2) μs | IT | 121In | (25/2+) | ||||||||||||||
122In | 49 | 73 | 121.910282(54) | 1.5(3) s | β− | 122Sn | 1+ | ||||||||||||
122m1In[n 9] | 40(60)# keV | 10.3(6) s | β− | 122Sn | 5+ | ||||||||||||||
122m2In | 290(140) keV | 10.8(4) s | β− | 122Sn | 8− | ||||||||||||||
123In | 49 | 74 | 122.910435(21) | 6.17(5) s | β− | 123mSn | 9/2+ | ||||||||||||
123m1In | 327.21(4) keV | 47.4(4) s | β− | 123Sn | 1/2− | ||||||||||||||
123m2In | 2078.1(6) keV | 1.4(2) μs | IT | 123In | (17/2−) | ||||||||||||||
123m3In | 2103(14)# keV | >100 μs | IT | 123In | (21/2−) | ||||||||||||||
124In | 49 | 75 | 123.913185(33) | 3.12(9) s | β− | 124Sn | 3+ | ||||||||||||
124mIn[n 9] | −20(60) keV | 3.67(03) s | β− | 124Sn | 8− | ||||||||||||||
IT? | 124In | ||||||||||||||||||
125In | 49 | 76 | 124.9136738(19) | 2.36(4) s | β− | 125mSn | 9/2+ | ||||||||||||
125m1In | 352(12) keV | 12.2(2) s | β− | 125Sn | 1/2− | ||||||||||||||
125m2In | 2009.4(7) keV | 9.4(6) μs | IT | 125In | (19/2+) | ||||||||||||||
125m3In | 2161.2(9) keV | 5.0(15) ms | IT | 125In | (23/2−) | ||||||||||||||
126In | 49 | 77 | 125.9164682(45) | 1.53(1) s | β− | 126Sn | 3+ | ||||||||||||
126m1In | 90(7) keV | 1.64(5) s | β− | 126Sn | 8− | ||||||||||||||
126m2In | 243.3(2) keV | 22(2) μs | IT | 126In | 1− | ||||||||||||||
127In | 49 | 78 | 126.9174539(14)[7] | 1.086(7) s | β− (>99.97%) | 127mSn | 9/2+ | ||||||||||||
β−, n (<0.03%) | 126Sn | ||||||||||||||||||
127m1In | 407.9(50) keV[7] | 3.618(21) s | β− (99.30%) | 127mSn | 1/2−# | ||||||||||||||
β−, n (0.70%) | 126Sn | ||||||||||||||||||
127m2In | 1728.7(12) keV[7] | 1.04(10) s | β− | 127mSn | (21/2−) | ||||||||||||||
β−, n? | 126Sn | ||||||||||||||||||
127m3In | 2364.7(9) keV | 9(2) μs | IT | 127In | (29/2+) | ||||||||||||||
128In | 49 | 79 | 127.9203536(14) | 816(27) ms | β− (99.96%) | 128Sn | (3)+ | ||||||||||||
β−, n (0.038%) | 127Sn | ||||||||||||||||||
128m1In | 247.87(10) keV | 23(2) μs | IT | 128In | (1)− | ||||||||||||||
128m2In | 285.1(22) keV | 720(100) ms | β− | 128Sn | (8−) | ||||||||||||||
IT? | 128In | ||||||||||||||||||
β−, n? | 127Sn | ||||||||||||||||||
128m3In | 1797.6(16) keV | >0.3 s | β− | 128Sn | (16+) | ||||||||||||||
IT? | 128In | ||||||||||||||||||
β−, n? | 127Sn | ||||||||||||||||||
129In | 49 | 80 | 128.9218085(21) | 570(10) ms | β− (99.77%) | 129Sn | 9/2+ | ||||||||||||
β−, n (0.23%) | 128Sn | ||||||||||||||||||
129m1In | 449.1(59) keV[7] | 1.23(3) s | β− (96.2%) | 129Sn | 1/2− | ||||||||||||||
β−, n (3.6%) | 128Sn | ||||||||||||||||||
IT? | 129In | ||||||||||||||||||
129m2In | 1646.6(33) keV[7] | 670(100) ms | β− | 129Sn | (23/2−) | ||||||||||||||
IT? | 129In | ||||||||||||||||||
129m3In | 1687.97(25) keV | 11.2(2) μs | IT | 129In | (17/2−) | ||||||||||||||
129m4In | 1927.6(33) keV[7] | 110(15) ms | IT | 129In | (29/2+) | ||||||||||||||
β−? | 129Sn | ||||||||||||||||||
130In | 49 | 81 | 129.9249523(19) | 273(5) ms | β− (99.07%) | 130Sn | 1(−) | ||||||||||||
β−, n (0.93%) | 129Sn | ||||||||||||||||||
130m1In[n 9] | 66.5(27) keV | 540(10) ms | β− (98.20%) | 130Sn | (10-) | ||||||||||||||
β−, n (1.80%) | 129Sn | ||||||||||||||||||
130m2In | 385.4(26) keV | 540(10) ms | β− (98.20%) | 130Sn | (5+) | ||||||||||||||
β−, n (1.80%) | 129Sn | ||||||||||||||||||
130m3In | 388.3(2) keV | 4.6(2) μs | IT | 130In | (3+) | ||||||||||||||
131In | 49 | 82 | 130.9269728(24) | 261.5(28) ms | β− (97.75%) | 131Sn | 9/2+ | ||||||||||||
β−, n (2.25%) | 130Sn | ||||||||||||||||||
131m1In | 376(3) keV | 328(15) ms | β− (97.75%) | 131Sn | 1/2− | ||||||||||||||
β−, n (2.25%) | 130Sn | ||||||||||||||||||
IT? | 131In | ||||||||||||||||||
131m2In | 3750(90) keV | 322(41) ms | β− (88%) | 131Sn | (21/2+) | ||||||||||||||
β−, n (12%) | 130Sn | ||||||||||||||||||
IT? | 129Sn | ||||||||||||||||||
131m3In | 3783.6(5) keV | 669(34) ns | IT | 131In | (17/2+) | ||||||||||||||
132In | 49 | 83 | 131.932998(64) | 202.2(2) ms | β− (87.7%) | 132Sn | (7−) | ||||||||||||
β−, n (12.3%) | 131Sn | ||||||||||||||||||
β−, 2n? | 130Sn | ||||||||||||||||||
133In | 49 | 84 | 132.93807(22)# | 163.0(16) ms | β−, n (85%) | 132Sn | (9/2+) | ||||||||||||
β− (15%) | 133Sn | ||||||||||||||||||
β−, 2n? | 131Sn | ||||||||||||||||||
133mIn | 330(40)# keV | 167(11) ms | β−, n (93%) | 132Sn | (1/2−) | ||||||||||||||
β− (7%) | 133Sn | ||||||||||||||||||
134In | 49 | 85 | 133.94421(22)# | 140(4) ms | β−, n (65%) | 133Sn | 7−# | ||||||||||||
β−? | 134Sn | ||||||||||||||||||
β−, 2n (<4%) | 132Sn | ||||||||||||||||||
134mIn | 56.7(1) keV | 3.5(4) μs | IT | 134In | (5−) | ||||||||||||||
135In | 49 | 86 | 134.94943(32)# | 103(3) ms | β− | 135Sn | 9/2+# | ||||||||||||
β−, n? | 134Sn | ||||||||||||||||||
β−, 2n? | 133Sn | ||||||||||||||||||
136In | 49 | 87 | 135.95602(32)# | 86(9) ms | β− | 136Sn | 7−# | ||||||||||||
β−, n? | 135Sn | ||||||||||||||||||
β−, 2n? | 134Sn | ||||||||||||||||||
137In | 49 | 88 | 136.96154(43)# | 70(40) ms | β− | 137Sn | 9/2+# | ||||||||||||
β−, n? | 136Sn | ||||||||||||||||||
β−, 2n? | 135Sn | ||||||||||||||||||
This table header & footer: |
- ^ mIn – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ a b c # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^
Modes of decay:
EC: Electron capture IT: Isomeric transition n: Neutron emission p: Proton emission - ^ Bold italics symbol as daughter – Daughter product is nearly stable.
- ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ a b c d e f g Order of ground state and isomer is uncertain.
- ^ Used in medical applications
- ^ a b Fission product
- ^ Primordial radionuclide
References
edit- ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ "Standard Atomic Weights: Indium". CIAAW. 2011.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ "Octreoscan review". Medscape.
- ^ "Precision mass measurements of indium isotopes allow conclusions on the mass of the doubly-magic atomic nucleus of tin-100". GSI. 13 June 2012. Retrieved 2023-09-10.
- ^ "Tin 100 probed by studying its neighboring isotopes, indium 99 and 101 – IJCLab". Retrieved 2023-09-10.
- ^ a b c d e f Jaries, A.; Stryjczyk, M.; Kankainen, A.; Ayoubi, L. Al; Beliuskina, O.; Canete, L.; de Groote, R. P.; Delafosse, C.; Delahaye, P.; Eronen, T.; Flayol, M.; Ge, Z.; Geldhof, S.; Gins, W.; Hukkanen, M.; Imgram, P.; Kahl, D.; Kostensalo, J.; Kujanpää, S.; Kumar, D.; Moore, I. D.; Mougeot, M.; Nesterenko, D. A.; Nikas, S.; Patel, D.; Penttilä, H.; Pitman-Weymouth, D.; Pohjalainen, I.; Raggio, A.; Ramalho, M.; Reponen, M.; Rinta-Antila, S.; de Roubin, A.; Ruotsalainen, J.; Srivastava, P. C.; Suhonen, J.; Vilen, M.; Virtanen, V.; Zadvornaya, A. "Physical Review C - Accepted Paper: Isomeric states of fission fragments explored via Penning trap mass spectrometry at IGISOL". journals.aps.org. arXiv:2403.04710.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
- "News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.