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A fire retardant is a substance that reduces flammability of fuels or delays their combustion. This includes chemical agents, but may also include substances that work by physical action, such as cooling the fuels, such as fire-fighting foams and fire-retardant gels. Fire retardants may also be coatings applied to an object, such as a spray retardant to prevent Christmas trees from burning. Fire retardants are commonly used in fire fighting.
Principles of operationEdit
In general, fire retardants reduce the flammability of materials by either blocking the fire physically or by initiating a chemical reaction that stops the fire.
There are several ways in which the combustion process can be retarded by physical action:
- By cooling: Some chemical reactions actually cool the material down.
- By forming a protective layer that prevents the underlying material from igniting.
- By dilution: Some retardants release water and/or carbon dioxide while burning. This may dilute the radicals in the flame enough for it to go out.
Commonly used fire retardant additives include mixtures of huntite and hydromagnesite, aluminium hydroxide, and magnesium hydroxide. When heated, aluminium hydroxide dehydrates to form aluminum oxide (alumina, Al2O3), releasing water vapor in the process. This reaction absorbs a great deal of heat, cooling the material into which it is incorporated. Additionally, the residue of alumina forms a protective layer on the material's surface. Mixtures of huntite and hydromagnesite work in a similar manner. They endothermically decompose releasing both water and carbon dioxide, giving fire retardant properties to the materials in which they are incorporated.
- Reactions in the gas phase: chemical reactions in the flame (i.e. gas phase) can be interrupted by fire retardants. Generally, these retardants are organic halides (haloalkanes) such as Halon and PhostrEx. The chemicals used in these types of retardants are often toxic.
- Reaction in the solid phase: some retardants break down polymers so they melt and flow away from the flame. Although this allows some materials to pass certain flammability tests[which?], it is not known whether fire safety is truly improved by the production of flammable plastic droplets.
- Char Formation: For carbon-based fuels, solid phase flame retardants cause a layer of carbonaceous char to form on the fuel surface. This char layer is much harder to burn and prevents further burning.
- Intumescents: These types of retardant materials incorporate chemicals which cause swelling behind the protective char layer, providing much better insulation. They are available as plastic addatives, and as paints for protecting wooden buildings or steel structures.
Class A foam is used as a fire retardant in 2.5 gallon [APW] and [CAFS] extinguishers to contain incipient brush fires and grass fires by creating a fire break. Other chemical retardants are capable of rendering class A material and Class B fuels non-flammable and extinguishing class A, class B, and some class D fires. Fire retardant slurries dropped from aircraft are normally applied ahead of a wildfire to prevent ignition, while fire suppression agents are used to extinguish fires.
Objects may be coated with fire retardants. For example, Christmas trees are sprayed with retardants. As a tree dries out it becomes very flammable and a fire-hazard.
Large sky-scrapers use a coating around main structural elements to prevent catastrophic weakening during a fire.
Dormitories in the US are also considering using these products. Since 2000, 109 people have died in fires in dormitories or off-campus student housing across the nation, according to Campus Firewatch, an online newsletter.[when?] Campus Firewatch's publisher, Ed Comeau, said a January 2000 fire at Seton Hall University in New Jersey drew attention to the perils of fire on campus. A common area in a Seton Hall dorm caught fire after two students ignited a banner from a bulletin board. The fire quickly spread to furniture and killed three students and injured 58 others.
Generally, fire retardants are dropped from aircraft or applied by ground crews around a wildfire's edges in an effort to contain its spread. This allows ground crews time to work to extinguish the fire. However, when needed, retardant can also be dropped directly onto flames to cool the fire and reduce flame length.
Aerial firefighting is a method to combat wildfires using aircraft. The types of aircraft used include fixed-wing aircraft and helicopters. Smokejumpers and rappellers are also classified as aerial firefighters, being delivered by parachute from a variety of fixed-wing aircraft, or rappelling from helicopters. Chemicals used to fight fires may include water, water enhancers, or specially-formulated fire retardants.
Most clothing intended for children in the United States is required to pass fire-retardant tests for safety reasons.
In many locations mattresses are now treated with fire retardant or built with fire-resistant material. Many new foams self-extinguish. This is the most common use of chemical fire retardancy.
Fire retardants applied to wildfires are usually a mixture of water and chemicals designed to wet the area as well as chemically retard a fire's progression through vegetation. Typically it is colored so that the application area can be seen from the air. New[when?] gel-based retardants which meet NFPA Standard 1150 are being introduced into use. These are dyed other colors to differentiate them from the traditional red retardant. The gels and their dyes are designed to biodegrade naturally. Phos-Chek is a brand of long-term retardant currently approved for wildland fire use.
Some fire retardants contain chemicals that are potentially dangerous to the environment, such as PBDEs. Fire retardants used in airplanes and fire resistant objects such as carpets accumulate in humans. (see PBDE#Health concerns).
Forest fire retardants that are used are generally considered non-toxic, but even less-toxic compounds carry some risk when organisms are exposed to large amounts. Fire retardants used in firefighting can be toxic to fish and wildlife as well as firefighters by releasing dioxins and furans when halogenated fire retardants are burned during fires, and drops within 300 feet of bodies of water are generally prohibited unless lives or property are directly threatened. The US Forest Service is the governing agency that conducts research and monitors the effect of fire retardants on wildland systems in the US.
A study published in June 2014 found that marine bacteria have the ability to manufacture a non-synthetic source of chemically identical PBDEs. These chemicals are used as flame retardant, but are known to be toxic to the environment.
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