An excimer laser, sometimes more correctly called an exciplex laser, is a form of ultraviolet laser which is commonly used in the production of microelectronic devices, semiconductor based integrated circuits or "chips", eye surgery, and micromachining.
The term excimer is short for 'excited dimer', while exciplex is short for 'excited complex'. Most excimer lasers are of the noble gas halide type, for which the term excimer is strictly speaking a misnomer (since less commonly used name for such is exciplex laser).
The excimer laser was invented in 1970 by Nikolai Basov, V. A. Danilychev and Yu. M. Popov, at the Lebedev Physical Institute in Moscow, using a xenon dimer (Xe2) excited by an electron beam to give stimulated emission at 172 nm wavelength. A later improvement, developed by many groups in 1975 was the use of noble gas halides (originally XeBr). These groups include the Avco Everett Research Laboratory, Sandia Laboratories, the Northrop Research and Technology Center, and the United States Government's Naval Research Laboratory who also developed a XeCl Laser that was excited using a microwave discharge.
An excimer laser typically uses a combination of a noble gas (argon, krypton, or xenon) and a reactive gas (fluorine or chlorine). Under the appropriate conditions of electrical stimulation and high pressure, a pseudo-molecule called an excimer (or in the case of noble gas halides, exciplex) is created, which can only exist in an energized state and can give rise to laser light in the ultraviolet range.
Laser action in an excimer molecule occurs because it has a bound (associative) excited state, but a repulsive (dissociative) ground state. Noble gases such as xenon and krypton are highly inert and do not usually form chemical compounds. However, when in an excited state (induced by electrical discharge or high-energy electron beams), they can form temporarily bound molecules with themselves (excimer) or with halogens (exciplex) such as fluorine and chlorine. The excited compound can release its excess energy by undergoing spontaneous or stimulated emission, resulting in a strongly repulsive ground state molecule which very quickly (on the order of a picosecond) dissociates back into two unbound atoms. This forms a population inversion.
The wavelength of an excimer laser depends on the molecules used, and is usually in the ultraviolet:
|Xe2*||172 & 175 nm|
Excimer lasers, such as XeF and KrF, can also be made slightly tunable using a variety of prism and grating intracavity arrangements.
Discharge-pumped excimer lasers are usually operated with a pulse repetition rate of around 100 Hz and a pulse duration of ~10 ns, although some operate at pulse repetition rates as high as 8 kHz and some have pulse length as large as 30 ns. For electron-beam pumped lasers typical pulse length can be as large as 100 ns and a repetition rate usually limited to a single shot within several minutes, although some operate at pulse repetition rates as high as 10 Hz.
Excimer lasers are widely used in high-resolution photolithography machines, one of the critical technologies required for microelectronic chip manufacturing. Current state-of-the-art lithography tools use deep ultraviolet (DUV) light from the KrF and ArF excimer lasers with wavelengths of 248 and 193 nanometers (the dominant lithography technology today is thus also called "excimer laser lithography"), which has enabled transistor feature sizes to shrink below 45 nanometers. Excimer laser lithography has thus played a critical role in the continued advance of the so-called Moore's law for the last 20 years.
The most widespread industrial application of excimer lasers has been in deep-ultraviolet photolithography, a critical technology used in the manufacturing of microelectronic devices (i.e., semiconductor integrated circuits or "chips"). Historically, from the early 1960s through the mid-1980s, mercury-xenon lamps had been used in lithography for their spectral lines at 436, 405 and 365 nm wavelengths. However, with the semiconductor industry's need for both higher resolution (to produce denser and faster chips) and higher throughput (for lower costs), the lamp-based lithography tools were no longer able to meet the industry's requirements. This challenge was overcome when in a pioneering development in 1982, deep-UV excimer laser lithography was proposed and demonstrated at IBM by Kanti Jain. With phenomenal advances made in equipment technology in the last two decades, and today microelectronic devices fabricated using excimer laser lithography totaling $400 billion in annual production, it is the semiconductor industry view that excimer laser lithography has been a crucial factor in the continued advance of Moore's law, enabling minimum features sizes in chip manufacturing to shrink from 800 nanometers in 1990 to 10 nanometers in 2016. From an even broader scientific and technological perspective, since the invention of the laser in 1960, the development of excimer laser lithography has been highlighted as one of the major milestones in the 50-year history of the laser.
The ultraviolet light from an excimer laser is well absorbed by biological matter and organic compounds. Rather than burning or cutting material, the excimer laser adds enough energy to disrupt the molecular bonds of the surface tissue, which effectively disintegrates into the air in a tightly controlled manner through ablation rather than burning. Thus excimer lasers have the useful property that they can remove exceptionally fine layers of surface material with almost no heating or change to the remainder of the material which is left intact. These properties make excimer lasers well suited to precision micromachining organic material (including certain polymers and plastics), or delicate surgeries such as eye surgery LASIK. In 1980–1983, Rangaswamy Srinivasan, Samuel Blum and James J. Wynne at IBM's T. J. Watson Research Center observed the effect of the ultraviolet excimer laser on biological materials. Intrigued, they investigated further, finding that the laser made clean, precise cuts that would be ideal for delicate surgeries. This resulted in a fundamental patent and Srinivasan, Blum and Wynne were elected to the National Inventors Hall of Fame in 2002. In 2012, the team members were honored with National Medal of Technology and Innovation by the President of The United States Barack Obama for their work related to the excimer laser. Subsequent work introduced the excimer laser for use in angioplasty. Xenon chloride (308 nm) excimer lasers can also treat a variety of dermatological conditions including psoriasis, vitiligo, atopic dermatitis, alopecia areata and leukoderma.
As light sources, excimer lasers are generally large in size, which is a disadvantage in their medical applications, although their sizes are rapidly decreasing with ongoing development.
Research is being conducted to compare differences in safety and effectiveness outcomes between conventional excimer laser refractive surgery and wavefront-guided or wavefront-optimized refractive surgery, as wavefront methods may better correct for higher-order aberrations.
Excimer lasers are also widely used in numerous fields of scientific research, both as primary sources and, particularly the XeCl laser, as pump sources for tunable dye lasers, mainly to excite laser dyes emitting in the blue-green region of the spectrum. These lasers are also commonly used in Pulsed laser deposition systems, where their large fluence, short wavelength and non-continuous beam properties make them ideal for the ablation of a wide range of materials.
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