Copper(II) oxide or cupric oxide is the inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.
3D model (JSmol)
CompTox Dashboard (EPA)
|Molar mass||79.545 g/mol|
|Appearance||black to brown powder|
|Melting point||1,326 °C (2,419 °F; 1,599 K)|
|Boiling point||2,000 °C (3,630 °F; 2,270 K)|
|Solubility||soluble in ammonium chloride, potassium cyanide |
insoluble in alcohol, ammonium carbonate
|Band gap||1.2 eV|
Refractive index (nD)
a = 4.6837, b = 3.4226, c = 5.1288
α = 90°, β = 99.54°, γ = 90°
Std enthalpy of
|Safety data sheet||Fisher Scientific|
|GHS Signal word||Warning|
|P273, P391, P501|
|NFPA 704 (fire diamond)|
|NIOSH (US health exposure limits):|
|TWA 1 mg/m3 (as Cu)|
|TWA 1 mg/m3 (as Cu)|
IDLH (Immediate danger)
|TWA 100 mg/m3 (as Cu)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO.
It can be formed by heating copper in air at around 300–800°C:
- 2 Cu + O2 → 2 CuO
- 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) + O2(g) (180°C)
- CuCO3(s) → CuO(s) + CO2(g)
- Cu(OH)2(s) → CuO(s) + H2O(g) 
- CuO + 2 HNO3 → Cu(NO3)2 + H2O
- CuO + 2 HCl → CuCl2 + H2O
- CuO + H2SO4 → CuSO4 + H2O
It reacts with concentrated alkali to form the corresponding cuprate salts:
- 2 MOH + CuO + H2O → M2[Cu(OH)4]
- CuO + H2 → Cu + H2O
- CuO + CO → Cu + CO2
- 2 CuO + C → 2Cu + CO2
When cupric oxide is substituted for iron oxide in thermite the resulting mixture is a low explosive, not an incendiary.
Structure and physical propertiesEdit
As a significant product of copper mining, copper(II) oxide is the starting point for the production of other copper salts. For example, many wood preservatives are produced from copper oxide.
Cupric oxide is used as a pigment in ceramics to produce blue, red, and green, and sometimes gray, pink, or black glazes.
Pyrotechnic and FireworksEdit
Used as moderate blue coloring agent in blue flame compositions with additional chlorine donors and oxidizers such as chlorates and perchlorates. Providing oxygen it can be used as flash powder oxidizer with metal fuels such as magnesium, aluminium, or magnalium powder. Sometimes it is used in strobe effects and thermite compositions as crackling stars effect.
- The effect of hydrostatic pressure on the ambient temperature structure of CuO, Forsyth J.B., Hull S., J. Phys.: Condens. Matter 3 (1991) 5257-5261 , doi:10.1088/0953-8984/3/28/001. Crystallographic point group: 2/m or C2h. Space group: C2/c. Lattice parameters: a = 4.6837(5), b = 3.4226(5), c = 5.1288(6), α = 90°, β = 99.54(1)°, γ = 90°.
- NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).
- Richardson, H. Wayne (2002). "Copper Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a07_567.
- O. Glemser and H. Sauer (1963). "Copper, Silver, Gold". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. 1. NY,NY: Academic Press.
- Cudennec, Yannick; Lecerf, André (November 2003). "The transformation of Cu(OH)2 into CuO, revisited". Solid State Sciences. 5 (11–12): 1471–1474. doi:10.1016/j.solidstatesciences.2003.09.009.
- F. P. Koffyberg and F. A. Benko (1982). "A photoelectrochemical determination of the position of the conduction and valence band edges of p-type CuO". J. Appl. Phys. 53 (2): 1173. doi:10.1063/1.330567.
- "Uses of Copper Compounds: Other Copper Compounds". Copper Development Association. 2007. Retrieved 2007-01-27.
- Cupric Oxide Should Not Be Used As a Copper Supplement for Either Animals or Humans, Baker, D. H., J. Nutr. 129, 12 (1999) 2278-2279
- "Cupric Oxide Data Sheet". Hummel Croton Inc. 2006-04-21. Retrieved 2007-02-01.
|Wikimedia Commons has media related to Copper(II) oxide.|