Collision frequency describes the rate of collisions between two atomic or molecular species in a given volume, per unit time. In an ideal gas, assuming that the species behave like hard spheres, the collision frequency between A and B is:
SI unit of Z is number of collision per time .
- is the number of A molecules in the gas,
- is the number of B molecules in the gas,
- is the collision cross section (unit ), the area when two molecules collide with each other, simplified to , where the radius of A and the radius of B.
- is the Boltzmann's constant (unit ,
- is the temperature (unit ),
- is the reduced mass of the reactants A and B, (unit )
Collision in diluted solutionEdit
Collision in diluted gas or liquid solution is regulated by diffusion instead of direct collisions, which can be calculated from Fick's laws of diffusion.
In the case of equal-size particles at a concentration in a solution of viscosity , an expression for collision frequency where is the volume in question, and is the number of collisions per second, can be written as :
Here the frequency is independent of particle size, a result noted as counter-intuitive. For particles of different size, more elaborate expressions can be derived for estimating .