Chemical clock

A chemical clock (or clock reaction) is a complex mixture of reacting chemical compounds in which the onset of an observable property occurs after a predictable induction time.[1] In cases where one of the reagents has a visible color, crossing a concentration threshold can lead to an abrupt color change after a reproducible time lapse.

In an iodine clock reaction, colour changes after a time delay.

TypesEdit

Clock reactions may be classified into three or four types:[2]

  • substrate-depletive clock reaction
  • autocatalysis-driven clock reaction
  • pseudoclock behavior
  • crazy clock reaction

One reaction may fall into more than one classification above depending on the circumstance. For example, iodate−arsenous acid reaction can be substrate-depletive clock reaction, autocatalysis-driven clock reaction and crazy clock reaction.

ExamplesEdit

One class of example is the iodine clock reactions, in which an iodine species is mixed with redox reagents in the presence of starch. After a delay, a dark blue color suddenly appears due to the formation of a triiodide-starch complex.

Additional reagents can be added to some chemical clocks to build a chemical oscillator. For example, the Briggs–Rauscher reaction is derived from an iodine clock reaction by adding perchloric acid, malonic acid and manganese sulfate.[3]

See alsoEdit

ReferencesEdit

  1. ^ Wright, Stephen W. (2002-01-01). "Tick Tock, a Vitamin C Clock". Journal of Chemical Education. 79 (1): 40A. doi:10.1021/ed079p40. CS1 maint: discouraged parameter (link)
  2. ^ Horváth, Attila K.; Nagypál, István (23 February 2015). "Classification of Clock Reactions". ChemPhysChem. 16 (3): 588–594. doi:10.1002/cphc.201402806.
  3. ^ Briggs, Thomas S.; Rauscher, Warren C. (1973-07-01). "An oscillating iodine clock". Journal of Chemical Education. 50 (7): 496. Bibcode:1973JChEd..50..496B. doi:10.1021/ed050p496. ISSN 0021-9584.