Caesium hexafluorocobaltate(IV) is a salt with the chemical formula Cs
2CoF
6. It can be synthesized by the reaction of Cs
3[(CoCl
4)Cl] and fluorine.[1] The salt contains rare example of cobalt(IV) complex, i.e. [CoF6]2-.
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| Identifiers | |
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3D model (JSmol)
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| Properties | |
| CoCs2F6 | |
| Molar mass | 438.734517 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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It has cubic K2PtCl6 structure, with the lattice constant a = 8.91 Å, and the length of Co-F bond is 1.73 Å.[1] The complex is ferromagnetic and the ground state of Co(IV) is T2g3Eg2.[2]
See also edit
References edit
- ^ a b Quail, J. W.; Rivett, G. A. (1 August 1972). "Complex Fluorides of Tetravalent Cobalt". Canadian Journal of Chemistry. 50 (15): 2447–2450. doi:10.1139/v72-394.
- ^ Allen, Geoffrey Charles; Warren, Keith D. (1 September 1969). "Electronic spectrum of the hexafluorocobaltate(IV) anion". Inorganic Chemistry. 8 (9): 1902–1904. doi:10.1021/ic50079a019.
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