Barium ruthenate is an inorganic compound, with the chemical formula of BaRuO3. It can be obtained from the stoichiometric reaction of barium oxide and ruthenium(IV) oxide at temperatures below 1200 °C,[3] or from the thermal decomposition of Ba[Ru(NO)(NO2)4(OH)]·xH2O.[4] It reacts with ruthenium and ruthenium(IV) oxide at 1250 °C to obtain black needle-like crystal BaRu6O12.[5] Hydrogen or zirconium can reduce it when heated to produce metal ruthenium.[1]
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3D model (JSmol)
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CompTox Dashboard (EPA)
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| BaO3Ru | |
| Molar mass | 286.39 g·mol−1 |
| Appearance | black solid[1] |
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| H302, H332 | |
| P261, P264, P270, P271, P301+P317, P304+P340, P317, P330, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References
edit- ^ a b John B. Wiley; Kenneth R. Poeppelmeier (1991-11-01). "Reduction chemistry of platinum group metal perovskites". Materials Research Bulletin. 26 (11): 1201–1210. doi:10.1016/0025-5408(91)90127-8. Archived from the original on 2018-06-30. Retrieved 2022-08-31.
- ^ "Barium ruthenium trioxide". pubchem.ncbi.nlm.nih.gov.
- ^ Popova, T. L.; Kisel, N. G.; Krivobok, V. I.; Karlov, V. P. Reactions in the barium oxide-ruthenium(IV) oxide system(in Russian). Ukrainskii Khimicheskii Zhurnal (Russian Edition), 1982. 48 (5): 457-460. ISSN 0041-6045.
- ^ Sinitsyn, N. M.; Kokunova, V. N. Preparation of double ruthenium oxides from coordination compounds(in Russian). Zhurnal Neorganicheskoi Khimii, 1990. 35 (12): 3120-3123. ISSN 0044-457X.
- ^ C.C. Torardi (1985-06-01). "Synthesis and crystal structure of BaRu6O12: An ordered stoichiometric hollandite". Materials Research Bulletin. 20 (6): 705–713. doi:10.1016/0025-5408(85)90149-7. Archived from the original on 2018-06-04. Retrieved 2022-08-31.
External reading
edit- Darriet, J.; Dussarrat, C.; Weill, F.; Darriet, B.; Bontchev, R. (1993). "The system BaRuO3-BaBiO3 I Crystal structures of Ba3Ru2BiO9 and Ba2RuxBi2-xO6 (0". European Journal of Solid State and Inorganic Chemistry. 30 (3): 273–286.