Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.
![](http://upload.wikimedia.org/wikipedia/commons/thumb/b/be/Mg3AsN-ejic201900756-fig-0002-m.jpg/220px-Mg3AsN-ejic201900756-fig-0002-m.jpg)
Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.
List
editname | formula | crystal
system |
space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|---|
Mg3AsN | cubic | Pm3m | a =4.2148 Z=1 | 74.88 | 3.589 | orange | [2] | |
Ca3AsN | orthorhombic | Pbnm | a=6.725 b=6.7198 c=9.5335 Z=4 | 430.8 | 3.237 | red; moisture sensitive | [3] | |
Ca14As6C0.445N1.135H4.915 | P4/mbm | a = 15.749 c = 9.1062 | red; band gap 1.6 eV | [4] | ||||
Cr3AsN | tetragonal | I4/mcm | a=5.360 c=8.066 | [5][6] | ||||
gallium arsenide nitride | Ga(As,N) | |||||||
indium gallium arsenide nitride | (In,Ga)(As,N) | |||||||
aluminium gallium arsenide nitride | (Al,Ga)(As,N) | |||||||
Sr3AsN | orthorhombic | Pbnm | a=7.1856 b=10.1446 c=7.1464 Z=4 | 520.93 | 4.486 | dark grey | [2] | |
Ba3AsN | orthorhombic | Pbnm | a=7.6741 b=10.7573 c=7.5387 Z=4 | 622.33 | 5.347 | black | [2] | |
LaFe2AsN | orthorhombic | Cmcm | a =3.79932 b =11.11461 c =7.18656 | 303.474 | [7] | |||
LaCo2AsN | orthorhombic | Cmcm | a =3.75993 b =11.1674 c =7.0185 | 294699 | [7] | |||
LaNi2AsN | orthorhombic | Cmcm | a =3.71584 b =11.4147 c =6.9786 | 296.004 | [7] | |||
Th2ONAs | P3m1 | a=4.041 c=6.979 | [8] | |||||
ThCrAsN | metallic | [9] | ||||||
ThMnAsN | tetragonal | P4/nmm | a =4.0818 b =4.0818 c =8.947 | metallic | [10] | |||
ThFeAsN | tetragonal | P4/nmm | a = 4.0367 c = 8.5262 | superconductor Tc 30 K | [11] | |||
ThFe1-xCoxAsN | superconductivity lost for x>0.05 | [12] | ||||||
ThNiAsN | tetragonal | P4/nmm | a=4,0804 c=7.9888 | superconductor at 4.3K | [13] | |||
BaTh2Fe4As4(N0.7O0.3)2 | a=3.9886 c=29.853 | Tc 22K | [14] | |||||
U2N2As | P3m1 | a=3.833 c=6.737 | [8] |
References
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- ^ a b c Stoiber, Dominik; Niewa, Rainer (2019-02-15). "Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba)". Zeitschrift für anorganische und allgemeine Chemie. 645 (3): 329–334. doi:10.1002/zaac.201800295. S2CID 219878132.
- ^ Chern, Ming Y.; Disalvo, F.J.; Parise, J.B.; Goldstone, Joyce A. (February 1992). "The structural distortion of the anti-perovskite nitride Ca3AsN". Journal of Solid State Chemistry. 96 (2): 426–435. Bibcode:1992JSSCh..96..426C. doi:10.1016/S0022-4596(05)80277-4.
- ^ Blankenship, Trevor V.; Wang, Xiaoping; Hoffmann, Christina; Latturner, Susan E. (2014-10-06). "LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux". Inorganic Chemistry. 53 (19): 10620–10626. doi:10.1021/ic501722d. ISSN 0020-1669. PMID 25222291.
- ^ Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu; Ohta, Hiroto; Yajima, Takeshi; Hiroi, Zenji; Nakamura, Hiroyuki (15 October 2017). "Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan. 86 (10): 104706. Bibcode:2017JPSJ...86j4706W. doi:10.7566/JPSJ.86.104706.
- ^ Boller, H. (1968). "Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ". Monatshefte für Chemie. 99 (6): 2444–2449. doi:10.1007/BF01154362. S2CID 97266394.
- ^ a b c Jeong, Sehoon; Matsuishi, Satoru; Bang, Joonho; Hosono, Hideo (2015-04-01). "Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN ( TM = Fe, Co, and Ni)". APL Materials. 3 (4): 041509. Bibcode:2015APLM....3d1509J. doi:10.1063/1.4913395. ISSN 2166-532X.
- ^ a b Benz, R.; Zachariasen, W. H. (1969-02-15). "Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 25 (2): 294–296. doi:10.1107/S0567740869002135.
- ^ Wang, Zhi-Cheng; Shao, Ye-Ting; Lin, Yi-Qiang; Song, Shi-Jie; Li, Bai-Zhuo; Cheng, Er-Jian; Li, Shi-Yan; Zhu, Qin-Qing; Ren, Zhi; Cao, Guang-Han (2023-08-09). "Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x". Physical Review B. 108 (6): 064503. arXiv:2308.05267. Bibcode:2023PhRvB.108f4503W. doi:10.1103/PhysRevB.108.064503. ISSN 2469-9950. S2CID 260775924.
- ^ Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong; Mao, Huican; Xia, Yuanhua; Hu, Bingfeng; Liu, Zichen; Wang, Zhicheng; Shao, Yeting; Feng, Zhifa; Tan, Shugang; Sun, Yuping; Ren, Zhi; Jing, Qiang; Liu, Bo (2020-03-02). "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects". Inorganic Chemistry. 59 (5): 2937–2944. doi:10.1021/acs.inorgchem.9b03294. ISSN 0020-1669. PMID 32064866. S2CID 211133783.
- ^ Wang, Cao; Wang, Zhi-Cheng; Mei, Yu-Xue; Li, Yu-Ke; Li, Lin; Tang, Zhang-Tu; Liu, Yi; Zhang, Pan; Zhai, Hui-Fei; Xu, Zhu-An; Cao, Guang-Han (2016-02-24). "A New ZrCuSiAs-Type Superconductor: ThFeAsN". Journal of the American Chemical Society. 138 (7): 2170–2173. arXiv:1603.01501. doi:10.1021/jacs.6b00236. ISSN 0002-7863. PMID 26853632. S2CID 5393656.
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