Zirconium monophosphide

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Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP.[1][2][3]

Zirconium phosphide
Names
IUPAC name
Phosphinidinzirconium
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 234-866-8
  • InChI=1S/P.Zr
    Key: VQYKQHDWCVUGBB-UHFFFAOYSA-N
  • P#[Zr]
Properties
PZr
Molar mass 122.198 g·mol−1
Appearance solid
Hazards
GHS labelling:
GHS09: Environmental hazardGHS05: CorrosiveGHS06: Toxic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Preparation

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Zirconium monophosphide can be prepared from direct reaction of zirconium powders with red phosphorus:[4]

4 Zr + P4 → 4 ZrP

Physical properties

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The α-form of zirconium monophosphide has a NaCl crystal structure.[5] The β-form structure is hexagonal. The α-form is a superconductor if cooled below 5K.[6]

References

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  1. ^ "Zirconium Phosphide". American Elements. Retrieved 7 March 2024.
  2. ^ Irani, K. S.; Gingerich, K. A. (1 October 1963). "Structural transformation of zirconium phosphide". Journal of Physics and Chemistry of Solids. 24 (10): 1153–1158. doi:10.1016/0022-3697(63)90231-2. ISSN 0022-3697. Retrieved 7 March 2024.
  3. ^ O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 283. ISBN 978-1-4613-2655-7. Retrieved 7 March 2024.
  4. ^ Li, Zhen; Chen, Ning; Wang, Jigang; Li, Peishen; Guo, Ming; Wang, Qiang; Li, Chunhong; Wang, Changzheng; Guo, Tao; Chen, Shaowei (12 October 2017). "Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method" (PDF). Scientific Reports. 7 (1): 13044. doi:10.1038/s41598-017-13616-5. PMC 5638856. PMID 29026175.
  5. ^ Swanson, Howard Eugene (1962). Standard X-ray Diffraction Powder Patterns: Data for 46 substances. National Bureau of Standards. p. 75. Retrieved 7 March 2024.
  6. ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3769. ISBN 978-0-412-30120-9. Retrieved 7 March 2024.