User:Graeme Bartlett/formate chloride

Formate chlorides are mixed anion compounds containing formate and chloride anions.

formula	system	space group	unit cell	volume	density	comment	references
NH₄Cu(HCOO)Cl₂						yellowish green	^[1]
KCu(HCOO)Cl₂						yellowish green	^[1]
Zn(L)(HCOO)Cl L=1,3-bis(5,6-dimethylbenzimidazole-1-ylmethyl)benzene							^[2]
[Zn₂(L)₂(OH)(HCOO)Cl]·I
CsCu(HCOO)₂Cl							^[3]
KCs₂Pb₂(HCOO)₂Cl₅	orthorhombic	Amm2	a=5.8603 b=20.2300 c=7.3561 Z=2	872.09	3.757	transparent 0.43–1.87 μm; band gap 3.52 eV SHG 4.2×KDP	^[4]

formula	system	space group	unit cell	volume	density	comment	references
KCs₂[Pb₂Br₅(HCOO)₂]	orthorhombic	Amm2	a=6.066 b=20.646 c=7.605 Z=2	952.4	4.215	colourless; transparent 0.43 - 1.30 μm; SHG 6.5 × KDP	^[5]^[6]

References edit

^ ^a ^b Emori, Shuji; Muto, Yoneichiro (January 1984). "The Magnetic Properties of Cu(CH 3 COO) 2 ·2NH 4 Cl and NH 4 Cu(HCOO)Cl 2". Bulletin of the Chemical Society of Japan. 57 (1): 291–292. doi:10.1246/bcsj.57.291. ISSN 0009-2673.
^ Xiao, Shu Lin; Zhao, Yan Qin; He, Cui Hong; Cui, Guang Hua (2013-01-01). "Synthesis, crystal structures, and fluorescence properties of two 1-D zinc(II) coordination polymers constructed from a bis(benzimidazole) ligand". Journal of Coordination Chemistry. 66 (1): 89–97. doi:10.1080/00958972.2012.748190. ISSN 0095-8972.
^ Zhou, Junyan; Jin, Shifeng; Sun, Ruijin; Chai, Congcong; Hao, Munan; Zhong, Xin; Chen, Xiaolong (14 July 2021). "Above-room-temperature coupling between ferroelastic domains and magnetism in an organic-inorganic hybrid: CsCu ( HCOO ) 2 Cl". Physical Review Materials. 5 (7): 074405. doi:10.1103/PhysRevMaterials.5.074405.
^ Zhou, Ziqi; Fu, Ruibiao; Shui, Qirui; Tang, Hongxin; Bao, Wenxiu; Ma, Zuju; Wu, Xintao (29 December 2021). [10.1021/acs.inorgchem.1c03320 "KCs 2 Pb 2 (HCOO) 2 Cl 5 : A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution"]. Inorganic Chemistry. pp. acs.inorgchem.1c03320. doi:10.1021/acs.inorgchem.1c03320. {{cite web}}: Check |url= value (help)
^ Zhou, Ziqi; Fu, Ruibiao; Shui, Qirui; Tang, Hongxin; Bao, Wenxiu; Ma, Zuju; Wu, Xintao (29 December 2021). [10.1021/acs.inorgchem.1c03320 "KCs 2 Pb 2 (HCOO) 2 Cl 5 : A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution"]. Inorganic Chemistry. pp. acs.inorgchem.1c03320. doi:10.1021/acs.inorgchem.1c03320. {{cite web}}: Check |url= value (help)
^ Zhou, Zi‐Qi; Shui, Qi‐Rui; Fu, Rui‐Biao; Fang, Yuan‐Bin; Ma, Zu‐Ju; Wu, Xin‐Tao (9 September 2021). "KCs 2 [Pb 2 Br 5 (HCOO) 2 ]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response". Chemistry – A European Journal. 27 (51): 12976–12980. doi:10.1002/chem.202102332.

[:0-1] Emori, Shuji; Muto, Yoneichiro (January 1984). "The Magnetic Properties of Cu(CH 3 COO) 2 ·2NH 4 Cl and NH 4 Cu(HCOO)Cl 2". Bulletin of the Chemical Society of Japan. 57 (1): 291–292. doi:10.1246/bcsj.57.291. ISSN 0009-2673.

[2] Xiao, Shu Lin; Zhao, Yan Qin; He, Cui Hong; Cui, Guang Hua (2013-01-01). "Synthesis, crystal structures, and fluorescence properties of two 1-D zinc(II) coordination polymers constructed from a bis(benzimidazole) ligand". Journal of Coordination Chemistry. 66 (1): 89–97. doi:10.1080/00958972.2012.748190. ISSN 0095-8972.

[3] Zhou, Junyan; Jin, Shifeng; Sun, Ruijin; Chai, Congcong; Hao, Munan; Zhong, Xin; Chen, Xiaolong (14 July 2021). "Above-room-temperature coupling between ferroelastic domains and magnetism in an organic-inorganic hybrid: CsCu ( HCOO ) 2 Cl". Physical Review Materials. 5 (7): 074405. doi:10.1103/PhysRevMaterials.5.074405.

[4] Zhou, Ziqi; Fu, Ruibiao; Shui, Qirui; Tang, Hongxin; Bao, Wenxiu; Ma, Zuju; Wu, Xintao (29 December 2021). [10.1021/acs.inorgchem.1c03320 "KCs 2 Pb 2 (HCOO) 2 Cl 5 : A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution"]. Inorganic Chemistry. pp. acs.inorgchem.1c03320. doi:10.1021/acs.inorgchem.1c03320. {{cite web}}: Check |url= value (help)

[5] Zhou, Ziqi; Fu, Ruibiao; Shui, Qirui; Tang, Hongxin; Bao, Wenxiu; Ma, Zuju; Wu, Xintao (29 December 2021). [10.1021/acs.inorgchem.1c03320 "KCs 2 Pb 2 (HCOO) 2 Cl 5 : A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution"]. Inorganic Chemistry. pp. acs.inorgchem.1c03320. doi:10.1021/acs.inorgchem.1c03320. {{cite web}}: Check |url= value (help)

[6] Zhou, Zi‐Qi; Shui, Qi‐Rui; Fu, Rui‐Biao; Fang, Yuan‐Bin; Ma, Zu‐Ju; Wu, Xin‐Tao (9 September 2021). "KCs 2 [Pb 2 Br 5 (HCOO) 2 ]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response". Chemistry – A European Journal. 27 (51): 12976–12980. doi:10.1002/chem.202102332.

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