Borate tellurates are chemical mixed anion compounds that contain any kind of borate and tellurate ions. They are distinct from borotellurates where borate and tellurate are linked via oxygen; and telluroborates in which tellurium atoms replace oxygen in borates. There are also analogous borate selenates,and borate sulfates with selenium or sulfur atoms instead of tellurium.
List edit
| name | chem | mw | crystal system | space group | unit cell | volume | density | comments | references |
|---|---|---|---|---|---|---|---|---|---|
| Gd3S3BO3 | 626.74 | triclinic | P1 | a=3.9725 b=7.5945 c=11.182 α=91.402 β=91.093 γ=90.206 Z=2 | 337.30 | 6.173 | pale yellow; band gap 2.65 eV | [1] | |
| Bi3TeBO9 | Hexagonal | P63 | a=8.7337 c =5.8903 | transparent from 0.35 to 7.10 μm; SHG 1.6×KDP | [2] | ||||
| Bi3(TeO6)(BO3) | 909.35 | hexagonal | P63 | a=8.745, c=5.891, Z=2 | 390.20 | 7.740 | pale yellow; decompose 825 °C | [3] |
References edit
- ^ Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01). "Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)". New Journal of Chemistry. 40 (8): 6720–6727. doi:10.1039/C6NJ00549G. ISSN 1369-9261.
- ^ Dong, Weimin; Sun, Yingjie; Wang, Biao; Zhu, Mengqi; Li, Jing; Xu, Xinguang; Wang, Jiyang (2022-06-13). "Bi 3 TeBO 9 : A Promising Mid-Infrared Nonlinear Optical Crystal with a Large Laser Damage Threshold". Inorganic Chemistry. 61 (23): 8870–8878. doi:10.1021/acs.inorgchem.2c00924. ISSN 0020-1669.
- ^ Daub, Michael; Krummer, Michael; Hoffmann, Anke; Bayarjargal, Lkhamsuren; Hillebrecht, Harald (2017-01-26). "Synthesis, Crystal Structure, and Properties of Bi 3 TeBO 9 or Bi 3 (TeO 6 )(BO 3 ): A Non-Centrosymmetric Borate-Tellurate(VI) of Bismuth". Chemistry - A European Journal. 23 (6): 1331–1337. doi:10.1002/chem.201602480.
Category:Borates Category:Tellurates Category:Mixed anion compounds