Antimonide chlorides or chloride antimonides are compounds containing anions composed of chloride (Cl−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide bromides, antimonide iodides, phosphide bromides, and arsenide bromides.
List edit
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| R3c | |||||||
| SbHg2AlCl4 | orthorhombic | Pbcn | a = 11.9771, b = 8.7826, c = 17.5237, Z=8 | 1843.3 | red; room temp; air sensitive | [1] | |
| SbHg2AlCl4 | orthorhombic | Pna21 | a = 11.9529, b = 8.7536, c = 17.4532, Z=8 | 1826.1 | red; low temp | [1] | |
| [SbHg2]GaCl4 | orthorhombic | Pbcn | a = 12.0023, b = 8.7615, c = 17.5083, Z = 8 | >277K | [2] | ||
| [SbHg2]GaCl4 | orthorhombic | Pna21 | a = 17.4330, b = 8.7436, c = 11.9692, Z=8 | <277 | [2] | ||
| (Sb2Te2)[AlCl4] | triclinic | P1 | a = 9.4930, b = 13.4824, c = 18.0497, α = 78.983, β = 88.060, γ = 88.444°, Z = 8 | 2239.65 | red | [3] | |
Thioantimonate chlorides edit
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
Selenoantimonate chlorides edit
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
References edit
- ^ a b Schlirf, Jens; Deiseroth, Hans-Jörg (December 2007). "Crystal structures of α- and β-antimony dimercury tetrachloroaluminate, SbHg2AlCl4". Zeitschrift für Kristallographie - New Crystal Structures. 222 (4): 367–368. doi:10.1524/ncrs.2007.0156. ISSN 2197-4578.
- ^ a b Schlirf, J.; Deiseroth, H. J. (July 2007). "The Network Structure [SbHg2]GaCl4: An X-Ray Study of a Temperature Driven Phase Transition". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (8): 1154–1158. doi:10.1002/zaac.200700087.
- ^ Beck, Johannes; Schlüter, Stefan (February 2005). "Synthesis and Crystal Structure of (Sb2Te2)[AlCl4], a Compound Containing a Heteroatomic Polymeric Cation (Sb2Te2+)n". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (2–3): 569–574. doi:10.1002/zaac.200400427. ISSN 0044-2313.