Keatite is a silicate mineral with the chemical formula SiO2 (silicon dioxide) that was discovered in nature in 2013. It is a tetragonal polymorph of silica first known as a synthetic phase.[1] It was reported as minute inclusions within clinopyroxene (diopside) crystals in an ultra high pressure garnet pyroxenite body. The host rock is part of the Kokchetav Massif in Kazakhstan.[2]

Keatite
Crystal structure
General
CategorySilicate mineral
Formula
(repeating unit)
SiO2
Strunz classification4.DA.45
Crystal systemTetragonal
Identification
Crystal habitMicroscopic inclusions

Keatite was synthesized in 1954 and named for Paul P. Keat who discovered it while studying the role of soda in the crystallization of amorphous silica.[3] Keatite was well known before 1970 as evidenced in few studies from that era.[4][5]

References edit

  1. ^ Ralph, Jolyon, and Ida Ralph. "Keatite: Keatite Mineral Information and Data." MinDat. 2013. Aug. 2013
  2. ^ Abstract Hill, Tina R., Hiromi Konishi, and Huifang Xu, Natural occurrence of keatite precipitates in UHP clinopyroxene from the Kokchetav Massif: A TEM investigation, American Mineralogist, Volume 98, pages 187–196, 2013
  3. ^ Science 120 (27 Aug1954) pp 328-330 with the title "A new crystalline silica.
  4. ^ Li, C. T. (1971). "Transformation mechanism between high-quartz and keatite phases of LiAlSi2O6 composition". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 27 (6): 1132–1140. doi:10.1107/S0567740871003649.
  5. ^ Martin, Brigitte (December 1995). "Keatite; II, Hydrothermal synthesis from silica-glass". European Journal of Mineralogy. 7 (6): 1389–1397. Bibcode:1995EJMin...7.1389M. doi:10.1127/ejm/7/6/1389.