Zinc phosphide (Zn3P2) is an inorganic chemical compound. It is a grey solid, although commercial samples are often dark or even black. It is used as a rodenticide. Zn3P2 is a semiconductor with a direct band gap of 1.5 eV and may have applications in photovoltaic cells. A second zinc phosphide is known, with the stoichiometry ZnP2.
3D model (JSmol)
|Molar mass||258.12 g/mol|
|Appearance||gray tetragonal crystals|
|Melting point||1,160 °C (2,120 °F; 1,430 K)|
|Solubility||insoluble in ethanol, soluble in benzene, reacts with acids|
|P42/nmc, No. 137|
|GHS signal word||Danger|
|P223, P231+232, P264, P270, P280, P301+310, P321, P330, P335+334, P370+378, P402+404, P405, P501|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis and reactionsEdit
- 3 Zn + 2 P → Zn3P2
- Zn3P2 + 6 H2O → 2 PH3 + 3 Zn(OH)2
Zn3P2 has a room-temperature tetragonal form that converts to a cubic form at around 845 °C. In the room-temperature form there are discrete P atoms, zinc atoms are tetrahedrally coordinated and phosphorus six coordinate, with zinc atoms at 6 of the vertices of a distorted cube. ZnP2 also has two forms, a lower-temperature red tetragonal form and a black monoclinic form. In both of these there are chains of P atoms, helical in the tetragonal, semi-spiral in the monoclinic.
Thin film photovoltaic applicationsEdit
Zinc phosphide is an ideal candidate for thin film photovoltaic applications, for it has strong optical absorption and an almost ideal band gap (1.5eV). In addition to this, both zinc and phosphorus are found abundantly in the earth’s crust, meaning that material extraction cost is low compared with that of other thin film photovoltaics. Both zinc and phosphorus are also nontoxic, which is not the case for other common commercial thin film photovoltaics, like cadmium telluride.
Researchers at the University of Alberta were the first to successfully synthesize colloidal zinc phosphide. Before this, researchers were able to create efficient solar cells from bulk zinc phosphide, but their fabrication required temperatures greater than 850°C or complicated vacuum deposition methods. By contrast, colloidal zinc phosphide nanoparticles, contained in a zinc phosphide “ink”, allows for inexpensive, easy large-scale production, by means of slot-die coating or spray coating.
The testing and development of these zinc phosphide thin films is still in its early stages, but early results have been positive. Prototype heterojunction devices fabricated from zinc phosphide nanoparticle ink exhibited a rectification ratio of 600 and photosensitivity with an on/off ratio near 100. These are both acceptable suitability benchmarks for solar cells. Development still needs to be made on optimizing the nanoparticle ink formation and device architecture before commercialization is possible, but commercial spray-on zinc phosphide solar cells may be possible within ten years.
Metal phosphides have been used as rodenticides. A mixture of food and zinc phosphide is left where the rodents can eat it. The acid in the digestive system of the rodent reacts with the phosphide to generate toxic phosphine gas. This method of vermin control has possible use in places where rodents are immune to other common poisons. Other pesticides similar to zinc phosphide are aluminium phosphide and calcium phosphide.
Zinc phosphide is typically added to rodent baits in amount of around 0.75-2%. Such baits have a strong, pungent garlic-like odor characteristic of phosphine liberated by hydrolysis. The odor attracts rodents, but has a repulsive effect on other animals; However, birds, notably wild turkeys, are not sensitive to the smell. The baits have to contain sufficient amount of zinc phosphide in sufficiently attractive food in order to kill rodents in a single serving; a sublethal dose may cause aversion towards zinc phosphide baits encountered by surviving rodents in the future.
Rodenticide-grade zinc phosphide usually comes as a black powder containing 75% of zinc phosphide and 25% of antimony potassium tartrate, an emetic to cause vomiting if the material is accidentally ingested by humans or domestic animals. However, it is still effective against rats, mice, guinea pigs and rabbits, none of which have a vomiting reflex.
Zinc phosphide use in New ZealandEdit
The New Zealand Environmental Protection Authority has approved the import and manufacture of Microencapsulated Zinc Phosphide (MZP Paste) for the ground control of possums. The application was made by Pest Tech Limited, with support from Connovation Ltd, Lincoln University and the Animal Health Board. It will be used as an additional vertebrate poison in certain situations. Unlike 1080 poison, it cannot be used for aerial application.
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- Toxicity label
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- EPA Proposed Risk Mitigation Decision for Nine Rodenticides
- Zinc phosphide in the Pesticide Properties DataBase (PPDB)
- Zinc phosphide properties and use in Michigan
- MD0173 - Pesticides in the military