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Urea-formaldehyde (UF), also known as urea-methanal, so named for its common synthesis pathway and overall structure,[1] is a non-transparent thermosetting resin or polymer. It is produced from urea and formaldehyde. These resins are used in adhesives, finishes, particle board, medium-density fibreboard (MDF), and molded objects.

UF and related amino resins are a class of thermosetting resins of which urea-formaldehyde resins make up 80% produced globally. Examples of amino resins use include in automobile tires to improve the bonding of rubber to tire cord, in paper for improving tear strength, in molding electrical devices, jar caps, etc.[2]



Urea-formaldehyde resin's attributes include high tensile strength, flexural modulus, and a high heat distortion temperature, low water absorption, mould shrinkage, high surface hardness, elongation at break, and volume resistance. It has a refractive index of 1.55.[3]

Chemical structureEdit

The chemical structure of UF polymer consists of [(O)CNHCH2NH]n repeat units. In contrast melamine-formaldehyde resins feature NCH2OCH2N repeat units. Depending on the polymerization conditions, some branching can occur. Early stages in the reaction of formaldehyde and urea produce bis(hydroxymethyl)urea.

Two steps in formation of urea-formaldehyde resin


Approximately 1 million metric tons of urea-formaldehyde are produced annually. Over 70% of this production is then put into use by the forest products industry for bonding particleboard (61%), medium density fiberboard (27%), hardwood plywood (5%), and laminating adhesive (7%).

General usesEdit

A range of objects made from urea formaldehyde

Urea-formaldehyde is pervasive. Examples include decorative laminates, textiles, paper, foundry sand molds, wrinkle resistant fabrics, cotton blends, rayon, corduroy, etc. It is also used to glue wood together. Urea formaldehyde was commonly used when producing electrical appliances casing (e.g. desk lamps). Foams have been used as artificial snow in movies.

Agricultural useEdit

Urea formaldehyde is also used in agriculture as a slow release source of nitrogen fertilizer. Urea formaldehyde's rate of decomposition into CO
and NH
is determined by the action of microbes found naturally in most soils.[4] The activity of these microbes, and, therefore, the rate of nitrogen release, is temperature dependent. The optimum temperature for microbe activity is approximately 70-90 °F (approx 20-30 °C).[citation needed]

Foam insulationEdit

Urea-formaldehyde insulation

Urea-formaldehyde foam insulation (UFFI) dates to the 1930s and made a synthetic insulation with R-values near 5.0 per inch. It is a foam, like shaving cream, that is easily injected or pumped into walls. It is made by using a pump set and hose with a mixing gun to mix the foaming agent, resin and compressed air. The fully expanded foam is pumped into areas in need of insulation. It becomes firm within minutes but cures within a week. UFFI is generally found in homes built before the 1970s, often in basements, crawl spaces, attics, and unfinished attics. Visually it looks like oozing liquid that has been hardened. Over time, it tends to vary in shades of butterscotch but new UFFI is a light yellow color. Early forms of UFFI tended to shrink significantly. Modern UF insulation with updated catalysts and foaming technology have reduced shrinkage to minimal levels (between 2-4%). The foam dries with a dull matte color with no shine. When cured, it often has a dry and crumbly texture.

Health concernsEdit

Health effects occur when urea-formaldehyde based materials and products release formaldehyde into the air. Generally there are no observable health effects from formaldehyde when air concentrations are below 1.0 ppm. The onset of respiratory irritation and other health effects, and even increased cancer risk begins when air concentrations exceed 3.0-5.0 ppm. This triggers watery eyes, nose irritations, wheezing and coughing, fatigue, skin rash, severe allergic reactions, burning sensations in the eyes and throat, nausea, and difficulty in breathing in some humans (usually > 1.0 ppm).[5][6] Occupants of UFFI insulated homes with elevated formaldehyde levels experienced systemic symptoms such as headache, malaise, insomnia, anorexia, and loss of libido.[citation needed] Irritation of the mucous membranes (specifically the eyes, nose, and throat) was a common upper respiratory tract symptom related to formaldehyde exposure. However, when compared to control groups, the frequency of symptoms did not exceed the controls except when it came to wheezing, difficult breathing, and a burning skin sensation. Controlled studies have suggested that tolerance to formaldehyde's odor and irritating effects can occur over a prolonged exposure.[citation needed]


It was first synthesized in 1884 by Hölzer, who was working with Bernhard Tollens.[7] In 1919, Hanns John (1891–1942) of Prague, Czechoslovakia obtained the first patent for urea-formaldehyde resin.[8]

Urea-formaldehyde was object matter of judgment via the European Court of Justice (now CJEU) of 5 February 1963, Case 26-62 Van Gend & Loos v Netherlands Inland Revenue Administration.[9]

See alsoEdit


  1. ^ Uses Of Formaldehyde
  2. ^ H. Deim, G. Matthias, R. A. Wagner "Amino Resins" in Ullmann's Encyclopedia of Industrial Chemistry,2012, Wiley-VCH, Weinheim. no doi:10.1002/14356007.a02_115.pub2
  3. ^ Brady, George S.; Clauser, Henry R.; Vaccari, A. John (1997). Materials Handbook (14th ed.). New York, NY: McGraw-Hill. ISBN 978-0-07-007084-4.
  4. ^ Hayatsu, M (2014). "A novel function of controlled-release nitrogen fertilizers". Microbes and Environments. 29 (2): 121–2. doi:10.1264/jsme2.me2902rh. PMC 4103517. PMID 25047661.
  5. ^ "Press Release N° 153".
  6. ^ Krief, P.; Coutrot, D.; Conso, F. (2008). "Occupational-toxicological risk related to the exposure to MDF wood dust". Archives des Maladies Professionnelles et de l'Environnement. 69 (5–6): 655–666. doi:10.1016/j.admp.2008.09.007.
  7. ^ See:
    • Tollens, B. (1884) "Ueber einige Derivate des Formaldehyds" (On some derivatives of formaldehyde), Berichte der Deutschen Chemischen Gesellschaft, 17 : 653-659. On page 659, Tollens mentions in passing: "… , aus Harnstoff und Formaldehyd hat dagegen Dr. Hölzer ein festes, schwer lösliches Derivat erhalten." (… from urea and formaldehyde, on the other hand, Dr. Hölzer obtained a solid, almost insoluble derivative.)
    • B. Tollens (1896) "Ueber den Methylen-Harnstoff" (On methylene-urea), Berichte der deutschen chemischen Gesellschaft, 29 (3) : 2751-2752. Neither Hölzer nor Tollens realized that the urea and formaldehyde were polymerizing.
    In 1896, Carl Goldschmidt investigated the reaction further. He also obtained an amorphous, almost insoluble precipitate; however, he didn't realize that polymerization was occurring: he thought that two molecules of urea were combining with three molecules of formaldehyde:
    • Goldschmidt, Carl (1896) "Ueber die Einwirkung von Formaldehyd auf Harnstoff" (On the effect of formaldehyde on urea), Berichte der Deutschen Chemischen Gesellschaft, 29 (3) : 2438-2439.
    • Goldschmidt, C. (1897) "Ueber die Einwirkung von Formaldehyd auf Harnstoff," Chemiker-Zeitung, 21 (46) : 460.
    Goldschmidt had suggested that the reaction might be used to measure urea, so in 1897, Hermann Thoms (1859-1931) of Berlin investigated the reaction further: H. Thoms (1897) "Über Harnstoffbestimmung mittelst Formaldehyds" (On the determination of urea via formaldehyde), Berichte der Deutschen Pharmaceutischen Gesellschaft, 7 : 161-168. On page 168, Thoms suggested that urea and formaldehyde might be forming a polymer: "(vielleicht auch ein Polymeres dieser Zusammensetzung)" (perhaps also a polymer of this composition).
  8. ^ See:
    • H. John "Verfahren zur Herstellung von Kondensationsprodukten aus Formaldehyd und Harnstoff bzw. Thioharnstoff oder anderen Harnstoffderivaten" (Process for the production of condensation products from formaldehyde and urea or thiourea or other urea derivatives), Austrian Patent 78,251, October 9, 1919.
    • H. John, "Process for the manufacture of condensation products of formaldehyde and carbamide or carbamide derivatives," Great Britain Patent 151,016, January 16, 1922.
    • Hanns John, "Manufacture of aldehyde condensation product capable of technical utilization," U.S. Patent 1,355,834, October 19, 1920.
  9. ^ Van Gend & Loos v Netherlands Inland Revenue Administration

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