Equivalent concentration

In chemistry, the equivalent concentration or normality (N) of a solution is defined as the molar concentration ci divided by an equivalence factor feq:

Normality = ci/feq

DefinitionEdit

Normality is defined as the number of gramme or mole equivalents of solute present in one litre of solution. The SI unit of normality is Eq/L.

Normality formulaEdit

Normality (N) = Mass of Solute (in gm) / (Equivalent Weight of Solute × Volume of the Solution (in liters))

UsageEdit

There are three common types of chemical reaction where normality is used as a measure of reactive species in solution:

  • In acid-base chemistry, normality is used to express the concentration of hydronium ions (H3O+) or hydroxide ions (OH) in a solution. Here, 1/feq is an integer value. Each solute can produce one or more equivalents of reactive species when dissolved.
  • In redox reactions, the equivalence factor describes the number of electrons that an oxidizing or reducing agent can accept or donate. Here, 1/feq can have a fractional (non-integer) value.
  • In precipitation reactions, the equivalence factor measures the number of ions which will precipitate in a given reaction. Here, 1/feq is an integer value.

Normal concentration of an ionic solution is also related to conductivity (electrolytic) through the use of equivalent conductivity.

MedicalEdit

Although losing favor in the medical industry, reporting of serum concentrations in units of "eq/L" (= 1 N) or "meq/L" (= 0.001 N) still occurs.

ExamplesEdit

Normality can be used for acid-base titrations. For example, sulfuric acid (H2SO4) is a diprotic acid. Since only 0.5 mol of H2SO4 are needed to neutralize 1 mol of OH, the equivalence factor is:

feq(H2SO4) = 0.5

If the concentration of a sulfuric acid solution is c(H2SO4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.

Similarly, for a solution with c(H3PO4) = 1 mol/L, the normality is 3 N because phosphoric acid contains 3 acidic H atoms.

Criticism of the term "normality"Edit

Normality is an ambiguous measure of the concentration of a given reagent in solution. It needs a definition of the equivalence factor, which depends on the definition of the reaction unit (and therefore equivalents). The same solution can possess different normalities for different reactions. The definition of the equivalence factor varies depending on the type of chemical reaction that is discussed: It may refer to equations, bases, redox species, precipitating ions, or isotopes. Since a reagent solution with a definite concentration may have different normality depending on which reaction is considered, IUPAC and NIST discourage the use of the terms "normality" and "normal solution".[1]

See alsoEdit

ReferencesEdit

  1. ^ International Union of Pure and Applied Chemistry (1998). Compendium of Analytical Nomenclature (definitive rules 1997, 3rd. ed.). Oxford: Blackwell Science. ISBN 0-86542-6155. section 6.3. "Archived copy" (PDF). Archived from the original (PDF) on July 26, 2011. Retrieved 2009-05-10.{{cite web}}: CS1 maint: archived copy as title (link)

External LinksEdit