Ammonium cerium(IV) sulfate

Ammonium cerium(IV) sulfate
Identifiers
CAS Number	10378-47-9 ;
3D model (JSmol)	Interactive image;
ChemSpider	17339565 ;
ECHA InfoCard	100.206.470
PubChem CID	71308344;
CompTox Dashboard (EPA)	DTXSID30897728 ;
	InChI InChI=1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;41-5(2,3)4;;/h;41H3;4(H2,1,2,3,4);21H2/q+4;;;;;;;;;;/p-4 Key: VCNAMBGKEDPVGQ-UHFFFAOYSA-J;
	SMILES [Ce+4].[O-]S(=O)(=O)[O-].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.O.O.[NH4+].[NH4+].[NH4+].[NH4+];
Properties
Chemical formula	H20N4S4O18Ce
Molar mass	632.55 g/mol
Appearance	Orange-colored solid
Melting point	130 °C (266 °F; 403 K)
Solubility in water	soluble in water
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	Irritant
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P262, P264, P280, P302+P352, P305+P351+P338, P314, P332+P313, P337+P313, P362
NFPA 704 (fire diamond)	2 1 OX
Related compounds
Related compounds	Cerium(IV) sulfate, Ceric ammonium nitrate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Ammonium cerium(IV) sulfate is an inorganic compound with the formula (NH₄)₄Ce(SO₄)₄·2H₂O. It is an orange-colored solid. It is a strong oxidant, the potential for reduction is about +1.44V. Cerium(IV) sulfate is a related compound.

Structure edit

A crystallographic study shows that the compound contains the Ce₂(SO₄)₈⁸⁻ anion, where the cerium atoms are 9 coordinated by oxygen atoms belonging to sulfate groups, in a distorted tricapped trigonal prism. The compound is thus sometimes formulated as (NH₄)₈[Ce₂(SO₄)₈]·4H₂O.^[2]

References edit

^ "Cerium(IV) Ammonium Sulfate Dihydrate". American Elements. Archived from the original on September 14, 2018. Retrieved September 13, 2018.
^ Shan, Y.; Huang, S. D. (1998). "(NH₄)₈[Ce₂(SO₄)₈]•4H₂O". Acta Crystallographica Section C. 54 (12): 1744–1745. Bibcode:1998AcCrC..54.1744S. doi:10.1107/S0108270198007057. ISSN 0108-2701. PMID 9921692.

[sds-1] "Cerium(IV) Ammonium Sulfate Dihydrate". American Elements. Archived from the original on September 14, 2018. Retrieved September 13, 2018.

[ShanHuang1998-2] Shan, Y.; Huang, S. D. (1998). "(NH₄)₈[Ce₂(SO₄)₈]•4H₂O". Acta Crystallographica Section C. 54 (12): 1744–1745. Bibcode:1998AcCrC..54.1744S. doi:10.1107/S0108270198007057. ISSN 0108-2701. PMID 9921692.

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[2]

Identifiers

CAS Number	10378-47-9^Y
3D model (JSmol)	Interactive image
ChemSpider	17339565^N
ECHA InfoCard	100.206.470
PubChem CID	71308344
CompTox Dashboard (EPA)	DTXSID30897728
InChI InChI=1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;41-5(2,3)4;;/h;41H3;4(H2,1,2,3,4);21H2/q+4;;;;;;;;;;/p-4 Key: VCNAMBGKEDPVGQ-UHFFFAOYSA-J
SMILES [Ce+4].[O-]S(=O)(=O)[O-].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.O.O.[NH4+].[NH4+].[NH4+].[NH4+]
Properties
Chemical formula	H₂₀N₄S₄O₁₈Ce
Molar mass	632.55 g/mol
Appearance	Orange-colored solid
Melting point	130 °C (266 °F; 403 K)
Solubility in water	soluble in water
Hazards
Occupational safety and health (OHS/OSH):
Main hazards	Irritant
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P262, P264, P280, P302+P352, P305+P351+P338, P314, P332+P313, P337+P313, P362^[1]
NFPA 704 (fire diamond)	2 1 OX
Related compounds
Related compounds	Cerium(IV) sulfate, Ceric ammonium nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references