Tetrabutyltin is the organotin compound with the molecular formula Sn(CH2CH2CH2CH3)4 or SnBu4, where Bu is butyl −CH2CH2CH2CH3. Sometimes abbreviated TTBT, it is a colorless, lipophilic oil.[3]
| |
| |
| Names | |
|---|---|
| Preferred IUPAC name
Tetrabutylstannane | |
| Other names
Tetra-n-butyltin
Tetra-n-butylstannane | |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.014.510 |
PubChem CID
|
|
| UNII | |
CompTox Dashboard (EPA)
|
|
| |
| |
| Properties | |
| Sn(CH2CH2CH2CH3)4 | |
| Molar mass | 347.174 g·mol−1 |
| Appearance | Colourless liquid |
| Density | 1.054 g/cm3 |
| Melting point | −97 °C (−143 °F; 176 K) |
| Boiling point | 245 °C (473 °F; 518 K) |
| insoluble | |
| Solubility | non-polar solvents such as benzene, ether, or THF[1] |
| Hazards | |
| GHS labelling: | |
  
| |
| Danger | |
| H301, H312, H315, H319, H410 | |
| P273, P280, P301+P310+P330, P302+P352+P312, P305+P351+P338, P314[2] | |
| Flash point | 107 °C (225 °F; 380 K) |
| Safety data sheet (SDS) | Tetrabutyltin |
| Related compounds | |
Related tetraalkylstannanes
|
|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Tetrabutyltin is a precursor to tributyltin and dibutyltin compounds. By the redistribution reaction with tin(IV) chloride it forms tributyltin chloride and dibutyltin chloride. These compounds are starting materials for a wide range of organotin compounds used as stabilizers for PVC and as biocides, fungicides, wood preservatives, and (historically) marine anti-biofouling agents.[4]
References edit
- ^ "13Tin - Gelest, Inc" (PDF).
- ^ Sigma-Aldrich Co., Tetrabutyltin. Retrieved on 2020-06-28.
- ^ Graf, Günter G. (2000). "Tin, Tin Alloys, and Tin Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a27_049. ISBN 978-3527306732.
- ^ Hoch, M. (2001). "Organotin compounds in the environment — an overview". Applied Geochemistry. 16 (s 7–8): 719–743. Bibcode:2001ApGC...16..719H. doi:10.1016/S0883-2927(00)00067-6.