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Summary
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English: Preparation of isovelleral via Swern oxidation. Note that the acid-sensitive cyclopropanemethanol moiety does not undergo ring opening. Taken from (a) Thompson SK, Heathcock CH. "Total synthesis of some marasmane and lactarane sesquiterpenes", Journal of Organic Chemistry, 1992, 57 (22), 5979–5989. doi:10.1021/jo00048a036 (b) Bell RPL, Wijnberg JPBA, de Groot A. "A Novel Route to the Marasmane Skeleton via a Tandem Rearrangement-Cyclopropanation Reaction. Total Synthesis of (+)-Isovelleral", Journal of Organic Chemistry 2001, 66, 2350-2357. doi:10.1021/jo0015568 |
| Date | |
| Source | Own work |
| Author | Walkerma |
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I, the copyright holder of this work, release this work into the public domain. This applies worldwide. In some countries this may not be legally possible; if so: I grant anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law. |
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| Date/Time | Thumbnail | Dimensions | User | Comment | |
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| current | 05:22, 3 January 2010 | | 1,518 × 356 (23 KB) | Walkerma | {{Information |Description={{en|1=Preparation of isovelleral via Swern oxidation. Note that the acid-sensitive cyclopropanemethanol moiety does not undergo ring opening. Taken from (a) Thompson SK, Heathcock CH. "Total synthesis of some marasmane and l |
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