Dichlorodifluoroethylene

Dichlorodifluoroethylene
	; 1,1-Dichloro-2,2-difluoroethylene
cis-1,2-Dichloro-1,2-difluoroethylene	trans-1,2-Dichloro-1,2-difluoroethylene
Names
	IUPAC names 1,1-Dichloro-2,2-difluoroethene; (Z)-1,2-Dichloro-1,2-difluoroethene; (E)-1,2-Dichloro-1,2-difluoroethene
Identifiers
CAS Number	79-35-6 ; 311-81-9 (cis) ; 381-71-5 (trans) ;
3D model (JSmol)	Interactive image; Interactive image; Interactive image;
ChemSpider	21106435 ; 2018468 ; 2297331 ;
ECHA InfoCard	100.001.090
PubChem CID	6592; 2736814; 3032334;
UNII	WC503FP86Y ;
CompTox Dashboard (EPA)	DTXSID6073150 ;
	InChI InChI=1S/C2Cl2F2/c3-1(4)2(5)6 Key: QDGONURINHVBEW-UHFFFAOYSA-N ; InChI=1S/C2Cl2F2/c3-1(5)2(4)6/b2-1- Key: UPVJEODAZWTJKZ-UPHRSURJSA-N; InChI=1S/C2Cl2F2/c3-1(5)2(4)6/b2-1+ Key: UPVJEODAZWTJKZ-OWOJBTEDSA-N;
	SMILES ClC(Cl)=C(F)F; Cl/C(F)=C(\Cl)F; Cl/C(F)=C(/Cl)F;
Properties
Chemical formula	C2Cl2F2
Molar mass	132.92 g·mol−1
Magnetic susceptibility (χ)	-60.0·10−6 cm3/mol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

A dichlorodifluoroethylene (systematically named dichlorodifluoroethene) is one of three compounds with the chemical formula C
₂Cl
₂F
₂. Dichlorodifluoroethylenes are colourless gases, and are some of the simplest chlorodifluoroalkenes.

The structural isomers are used as intermediates or precursors in the production of other industrial chemicals.^[1]^[2]

1,1-Dichloro-2,2-difluoroethylene edit

1,1-Dichloro-2,2-difluoroethylene is a low-boiling liquid that is used a refrigerant.^[3] It may also be used as a solvent, but has practical limitations as such, because of its low boiling point (commercial listings, 19 °C; lit. 17 °C).^[4]

It is regarded as a hazardous chemical for being toxic by inhalation (see MSDS), and a low-boiling liquid, and it causes irritation when it comes into contact with the skin and mucous membranes. Its ASHRAE number is R-1112a, and its CAS number is 79-35-6. Concentrated 1,1-dichloro-2,2-difluoroethylene can be ignited with ease in the laboratory.

cis- And trans-1,2-dichloro-1,2-difluoroethylene edit

The diastereomers were co-isolated first in 1965, by using a combination of fractional melting and fractional distillation.^[5] The cis isomer's ASHRAE number is R-1112c, and its CAS number is 311-81-9. Its melting point is −119.6 °C (−183.3 °F).^[5] The trans isomer's ASHRAE number is R-1112t, and its CAS number is 381-71-5. Its melting point is −93.3 °C (−135.9 °F).^[5] The diastereomers are commercially only available as a mixtures of varying proportions.

References edit

^ "1,1-Dichlorodifluoroethylene | 79-35-6 suppliers - BuyersGuideChem". www.buyersguidechem.com. Retrieved 26 December 2013.
^ "Process for the preparation of 1,2-difluoro-ethylene and 1-chloro-1,2-difluoro-ethylene". www.google.nl. Retrieved 26 December 2013.
^ "Refrigeration Technologies: Knowledge Center: Toxic Info: Refrigerant Safety Profile". Archived from the original on 2013-12-24. Retrieved 2013-12-05.
^ "Organic Syntheses Procedure".
^ ^a ^b ^c Craig, Norman C.; Evans, David A. (5 October 1965). "Infrared and Raman spectra of cis- and trans-1,2-dichloro-1,2-difluoroethylene". Journal of the American Chemical Society. 87 (19). ACS Publications: 4223–4230. doi:10.1021/ja00947a001.

External links edit

MSDS

[sup11-1] "1,1-Dichlorodifluoroethylene | 79-35-6 suppliers - BuyersGuideChem". www.buyersguidechem.com. Retrieved 26 December 2013.

[pat12-2] "Process for the preparation of 1,2-difluoro-ethylene and 1-chloro-1,2-difluoro-ethylene". www.google.nl. Retrieved 26 December 2013.

[3] "Refrigeration Technologies: Knowledge Center: Toxic Info: Refrigerant Safety Profile". Archived from the original on 2013-12-24. Retrieved 2013-12-05.

[4] "Organic Syntheses Procedure".

[Craig1965-5] Craig, Norman C.; Evans, David A. (5 October 1965). "Infrared and Raman spectra of cis- and trans-1,2-dichloro-1,2-difluoroethylene". Journal of the American Chemical Society. 87 (19). ACS Publications: 4223–4230. doi:10.1021/ja00947a001.

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